Research into surface properties of disperse fillers based on plant raw materials

Authors

DOI:

https://doi.org/10.15587/1729-4061.2017.111350

Keywords:

disperse filler, plant raw materials, composite material, surface active centre, acid­base properties

Abstract

The properties of the dispersed fillers are investigated based on the agricultural and wood industry wastes: buckwheat and oats husk, wood and pine­needle flour. We experimentally determined structural­rheological characteristics, morphology and acid­base properties of the surface. By applying a potentiometric determining of hydrogen indicator of aqueous suspensions рНsusp., we studied the qualitative and quantitative characteristics of acid­base active centers on the surface of the particles of fillers. It was revealed that the surface of buckwheat husk is dominated by two types of active centers: weakly­acidic (рKа≈5.53–5.83) and close to neutral (рKа≈6.16–6.30). The surfaces of wood flour and pine­needle flour are characterized as the weakly­acidic with centers рKа≈5.29–5.52 and рKа≈5.02–5.36, respectively. Based on sources from the scientific literature, we compiled a comparative characteristic of the chemical composition of the examined fillers. A correlation is established between chemical composition, physical­chemical and surface properties. It is shown that the total mass content of cellulose and lignin can be one of the criteria for evaluating resistance of the fillers to high temperatures and acidic­base properties. A decrease in the sum of mass content of cellulose and lignin in the composition of fillers results in the improved thermal resistance while the surface acidity decreases. The results obtained allow us to predict behaviour of the fillers in compositions and control performance characteristics of composite materials.

Author Biographies

Yuliya Danchenko, Kharkiv National University of Civil Engineering and Architecture Sumska str., 40, Kharkiv, Ukraine, 61002

PhD, Associate Professor

Department of General Chemistry

 

Vladimir Andronov, National University of Civil Protection of Ukraine Chernyshevska str., 94, Kharkiv, Ukraine, 61023

Doctor of Technical Sciences, Professor

Research Center

Artem Kariev, Kharkiv National University of Civil Engineering and Architecture Sumska str., 40, Kharkiv, Ukraine, 61002

Postgraduate student

Department of General Chemistry

Vladimir Lebedev, National Technical University "Kharkiv Polytechnic Institute" Kyrpychova str., 2, Kharkiv, Ukraine, 61002

PhD, Associate Professor

Department of Technology of Plastics and biological active polymer

Evgeniy Rybka, National University of Civil Protection of Ukraine Chernyshevska str., 94, Kharkiv, Ukraine, 61023

PhD

Research Center

Ruslan Meleshchenko, National University of Civil Protection of Ukraine Chernyshevska str., 94, Kharkiv, Ukraine, 61023

PhD

Department of fire and rescue training

Dayana Yavorska, V. N. Karazin Kharkiv National University Svobody sq., 4, Kharkiv, Ukraine, 61022

Department of Ecological Safety and Environmental Education

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Published

2017-10-31

How to Cite

Danchenko, Y., Andronov, V., Kariev, A., Lebedev, V., Rybka, E., Meleshchenko, R., & Yavorska, D. (2017). Research into surface properties of disperse fillers based on plant raw materials. Eastern-European Journal of Enterprise Technologies, 5(12 (89), 20–26. https://doi.org/10.15587/1729-4061.2017.111350

Issue

Vol. 5 No. 12 (89) (2017): MATERIALS SCIENCE

Section

Materials Science

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Copyright (c) 2017 Yuliya Danchenko, Vladimir Andronov, Artem Kariev, Vladimir Lebedev, Evgeniy Rybka, Ruslan Meleshchenko, Dayana Yavors'ka

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