Study of thickeners synthesized on the basis of polyethoxylate modified with diisocyanates

Authors

  • Анна Геннадиевна Глухова Kherson National Technical University Berislavsky Highway 24, Kherson, 73008, Ukraine

DOI:

https://doi.org/10.15587/1729-4061.2013.14777

Keywords:

urethane thickener, fabric, quality, printing, solvent, rheology

Abstract

The article studies the new synthetic thickeners of urethane type in pigment printing of fabrics with compositions prepared on the basis of urethane resins. The article presents the influence of the urethane thickeners and the system of solvents used in the preparation on pigment printing quality compared with the standard thickeners. It also presents the influence of organic solvents on the rheological behavior of thickeners based on the urethane thickeners.

For the study two different thickeners were prepared using a strong base of the polymer synthesized from polyethoxylate, modified with diisocyanate and two different solvent system for dissolving the solid base and form a solution of thickener. From a solution of the thickener by deterioration of the solvent we obtained a thickener. It was found that the thickener prepared with propylene glycol provides a higher color intensity compared to those the solid base of which was dissolved with ethylene glycol. It was shown that the solvent also affects the stability of the colors to washing and friction, affects the viscosity of the system, the clarity of the contour and painting of underside of the fabric.

Effect of thickeners on printing results is explained by their different rheological behavior.

Author Biography

Анна Геннадиевна Глухова, Kherson National Technical University Berislavsky Highway 24, Kherson, 73008

Candidate sensible science. Docent

Department of Chemistry and Ecology

References

  1. Волхонская, Н. С. Синтетический загуститель Сопан для печати кубовыми красителями [Текст] / Н.С. Волхонская, М.З. Казарян, А.В. Сенахов, Ф.И. Садов // Журн. крашение и отделка тканей. 1972. №1. – С. 6 12.
  2. Кричевский, Г. Е. Химическая технология волокнистых материалов [Текст]: учеб./ Г.Е. Кричевский, М.В. Корчагин, А.В. Сенахов. - М.: Легпромбытиздат, 1985. – 610с.
  3. Советская энциклопедия [Текст]. Т.3 Энциклопедия полимеров: /под ред. В.А. Каргина. – М. : 1972. – С.43.
  4. Олигомерный загуститель для водных систем [Текст] / Антоненко Т.А. Лапрол Д3 // Информационный листок №116. серия Р.61.65.09. – Владимир: ЦНТИ, 1993, - 2с.
  5. Применеие упронила в качестве загустителя пигментных печатних красок [Текст]: сб. науч. тр. / Мищенко, А.В., Яновская, О.В; Ресурсосберегающие технологии. – Киев, 1993. – С. 37 – 38.
  6. Мищенко, А. В. Структура и механизм реологического поведения полиуритановых гелей [Текст] / Мищенко А.В., Костыря Н.И., Антоненко Т.А. // Украинский химический журнал – 2000. Т.66. - №2, С.120 - 123.
  7. Кирилов, E.A. Цветоведение [Текст] : учеб, пособие / Е.А. Кирилов. – M.: Legprombutisdat, 1987. – 128с.
  8. Cross, M.M. Rheology of non – Newtonian f-luids: A new flow eguation for pseudoplastic systems [Текст] / I. Colloid Sci/ - 1965, V.20, С. 417 – 437.
  9. Nakajima, N. Academic rheology and industrial rheology – a ptrsonal reflection (to the years 1960 – 1970) [Текст]. Appl. Rheol. V. 9(3). 1999, C.116 – 125.
  10. Cheung, C.V. Cebon, D. Experimental study of pure ditumens in tension, compression and shear [Текст] // Jeurnal of Rheology. – 1997. V. 41(1). C. 45 – 73.
  11. Volkhonsky, N.S., Kazaryan, M.Z., Senachov, A.V., Sadov, F.I. (1972). Sintetichesky zagustitel sopan dlya pechati kubovymi krasitelyami. Krashenie i otdelka tkany, №1, 6-12.
  12. Krichevskii, G.E., Korchagin, M.V., Senachov, A.V. (1985). Khimisheskay tekhnologiy voloknistykh materialov. Moscow, USSR: Lenprombytizdate, 610.
  13. Kargina, V.A. (1972). Sovetskya intsklopediy, Intsklopediy polimerov. Moscow, USSR: 3, 43.
  14. Antonenko, T.A., Laprol, D.Z. (1993).Oligomerny zagustitel dly vodnykh system. Informatsione listok №116, seriy R.61.65.09.Vladimir TSNTI, 2.
  15. Mishchenko, A.V., Yanovskaya, O.V. (1993). Primenenie
  16. upronila v kachestve zagustitelya pigmentnykh pechatnykh krasok. Kiev, Ukrain: resursosberegayushchie tehnologii, 37 – 38.
  17. Mishchenko, A.V., Kostyrya, A.V., Antonenko, T.A. (2000). Struktura i mikhanizm reologicheskogo povedeniy poliuritanovykh geley. Ukrainsky khimichesky zhurnal, 66, №2, 120 – 123.
  18. Kirillov, E.A. Zwetovedenie (1987). Moscow, USSR: Legprombutisdat, 128.
  19. Cross, M.M. (1965). Rheology of non – Newtonian f-luids: A new flow eguation for pseudoplastic systems , I. Colloid Sci, 20, 417 – 437.
  20. Nakajima, N. (1999). Academic rheology and industrial rheology – a ptrsonal reflection (to the years 1960 – 1970). Appl. Rheol, 9(3), 116 – 125.
  21. Cheung, C.V., Cebon, D. (1997). Experimental study of pure ditumens in tension, compression and shear. Jeurnal of Rheology, 41(1), 45 – 73.

Published

2013-06-19

How to Cite

Глухова, А. Г. (2013). Study of thickeners synthesized on the basis of polyethoxylate modified with diisocyanates. Eastern-European Journal of Enterprise Technologies, 3(6(63), 8–11. https://doi.org/10.15587/1729-4061.2013.14777

Issue

Section

Technology organic and inorganic substances