Weste products of steel galvanizing processes for obtaining technology of colored glazes

Authors

  • Орест Миронович Вахула Lviv Polytechnic National University Bandery 13, Lviv, 79013, Ukraine
  • Ігор Вікторович Позняк LLC "Fakro Orbita" Sahaidachnoho 48, Shklo, Lviv region, 81050, Ukraine
  • Іван Володимирович Солоха Lviv Polytechnic National University Bandery 13, Lviv, 79013, Ukraine
  • Мирон Григорович Пона Lviv Polytechnic National University Bandery 13, Lviv, 79013, Ukraine
  • Зенон Іванович Боровець Lviv Polytechnic National University Bandery 13, Lviv, 79013, Ukraine

DOI:

https://doi.org/10.15587/1729-4061.2013.14808

Keywords:

waste products galvanizing process, electrolyte, crystal phases, milling, glaze, firing

Abstract

The subject of this research is glass-forming compounds pegmatite-slag of thermal pover plants-waste products of galvanizing processes based on frits.

The subject of this research is colored low-melt glazes.

The objective of the work is elaboration of compounds and technology obtaining colored glazes using waste products of steel galvanizing processes.

Up-to-date methods of investigation (X-ray phase analysis, differential thermal analysis, flame photometry and optical electroscopy) have been used in this work. Peculiarities of the formation of slimes of steel parts galvanizing and their properties have been investigated. The processes of gas formation in the process of thermal treatment of slimes have been studied in the range of temperatures 293…1773 K. Regularities of crystallization of coloring crystal phases α-Fe2o3, ZnO•Fe2o3 and  Feo•Fe2o3 that ensure obtaining colored glazes have been established.

Technology of obtaining low-melt glazes of brown and cherry-brown colors based on low-melt frit without adding additional ceramic pigments with firing temperature 1343…1373 K has been elaborated. It was established, that with the increase of slime content from 10 to 30 weight % in the composition of glazes the color of coating changes from brown to cherry-brown and the purity of color increases from 31 % to 47 %.

The obtained compositions of such glazes were successfully tested under the manufacturing conditions and confirmed the possibility of producing decorative oven ceramic tiles with improved decorative and maintenance properties.

Author Biographies

Орест Миронович Вахула, Lviv Polytechnic National University Bandery 13, Lviv, 79013

Ph.D., teacher

Department of Life Safety

Ігор Вікторович Позняк, LLC "Fakro Orbita" Sahaidachnoho 48, Shklo, Lviv region, 81050

Ph.D.

The head of galvanizing plant

Іван Володимирович Солоха, Lviv Polytechnic National University Bandery 13, Lviv, 79013

Ph.D., Assoc. Prof.

Department of Silicate Engineering

Мирон Григорович Пона, Lviv Polytechnic National University Bandery 13, Lviv, 79013

Ph.D., Assoc. Prof.

Department of Silicate Engineering

Зенон Іванович Боровець, Lviv Polytechnic National University Bandery 13, Lviv, 79013

Ph.D., Assoc. Prof.

Department of Silicate Engineering

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Published

2013-06-19

How to Cite

Вахула, О. М., Позняк, І. В., Солоха, І. В., Пона, М. Г., & Боровець, З. І. (2013). Weste products of steel galvanizing processes for obtaining technology of colored glazes. Eastern-European Journal of Enterprise Technologies, 3(6(63), 45–48. https://doi.org/10.15587/1729-4061.2013.14808

Issue

Section

Technology organic and inorganic substances