Environmentally friendly epoxyamine filled compositions curing under the low temperatures

Authors

  • Юлія Михайлівна Данченко Kharkiv National University of Civil Engineering and Architecture Sumskaya 40, Kharkov, Ukraine, 61002, Ukraine
  • Роман Олександрович Биков Kharkiv National University of Civil Engineering and Architecture Sumskaya 40, Kharkov, Ukraine, 61002, Ukraine
  • Марія Павлівна Качоманова Kharkiv National University of Civil Engineering and Architecture Sumskaya 40, Kharkov, Ukraine, 61002, Ukraine
  • Тетяна Миколаївна Обіженко Kharkiv National University of Civil Engineering and Architecture Sumskaya 40, Kharkov, Ukraine, 61002, Ukraine
  • Наталія Геннадіївна Білоус Kharkiv National University of Civil Engineering and Architecture Sumskaya 40, Kharkov, Ukraine, 61002, Ukraine
  • Антін Віталійович Антонов Kharkiv National University of Civil Engineering and Architecture Sumskaya 40, Kharkov, Ukraine, 61002, Ukraine

DOI:

https://doi.org/10.15587/1729-4061.2013.19165

Keywords:

epoxy-amine compositions, disperse mineral fillers, catalytic effect, E-factor, atom efficiency

Abstract

 It is established that in comparison with other polymeric bind­ers, the processes of obtaining the epoxy-amine compositions, used in construction, meet 8 of 12 principles of “green” chemistry. It is shown that the use of low-molecular weight substances as acid catalysts of the curing reaction reduces the value of E-factor by one order and the value of atom efficiency of the process by two orders. It is experimentally proved that the disperse mineral fillers, which have hydroxyl groups with various functions of acidity on the surface, can be used for the acceleration of reaction of cross-linking in the production of polymeric construction materials based on the epoxy-amine compositions. This will allow to improve the environmental safety of the preparation, application, use and utilization of these materials by the exclusion of toxic and environmentally hazardous to humans and biosphere low-molecular weight substances.

Author Biographies

Юлія Михайлівна Данченко, Kharkiv National University of Civil Engineering and Architecture Sumskaya 40, Kharkov, Ukraine, 61002

Candidate of engineering sciences, associate professor, managing a department

Department of General Chemistry

Роман Олександрович Биков, Kharkiv National University of Civil Engineering and Architecture Sumskaya 40, Kharkov, Ukraine, 61002

Candidate of engineering sciences, associate professor

Department of General Chemistry

Марія Павлівна Качоманова, Kharkiv National University of Civil Engineering and Architecture Sumskaya 40, Kharkov, Ukraine, 61002

Candidate of engineering sciences, junior scientist

Department of General Chemistry

Тетяна Миколаївна Обіженко, Kharkiv National University of Civil Engineering and Architecture Sumskaya 40, Kharkov, Ukraine, 61002

Candidate of engineering sciences, associate professor

Department of General Chemistry

Наталія Геннадіївна Білоус, Kharkiv National University of Civil Engineering and Architecture Sumskaya 40, Kharkov, Ukraine, 61002

Master's degree

Антін Віталійович Антонов, Kharkiv National University of Civil Engineering and Architecture Sumskaya 40, Kharkov, Ukraine, 61002

Student

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Published

2013-12-11

How to Cite

Данченко, Ю. М., Биков, Р. О., Качоманова, М. П., Обіженко, Т. М., Білоус, Н. Г., & Антонов, А. В. (2013). Environmentally friendly epoxyamine filled compositions curing under the low temperatures. Eastern-European Journal of Enterprise Technologies, 6(10(66), 9–12. https://doi.org/10.15587/1729-4061.2013.19165

Issue

Vol. 6 No. 10(66) (2013): Ecology. Materials science

Section

Ecology

License

Copyright (c) 2014 Юлія Михайлівна Данченко, Роман Олександрович Биков, Марія Павлівна Качоманова, Тетяна Миколаївна Обіженко, Наталія Геннадіївна Білоус, Антін Віталійович Антонов

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