Establishing regularities of temperature conductivity reduction when protecting fabric against fire by intumescent coating

Authors

DOI:

https://doi.org/10.15587/1729-4061.2022.254546

Keywords:

protective means, textile material, combustion, weight loss, fabric surface treatment, swelling

Abstract

This paper has analyzed materials for fire protection of textile products; it was found that there are not enough data to explain and describe the process of fire protection. Neglecting modern coatings leads to the ignition of fabric structures under the action of flame. Devising reliable methods for studying the conditions of fabric fire protection leads to the design of new types of fireproof materials. Therefore, there is a need to determine the conditions that form a barrier to high fabric temperature and to establish a mechanism for inhibiting heat transfer to the material. In this regard, the thermal conductivity process was simulated on the fabric surface using an intumescent coating, which makes it possible to estimate the coefficient of thermal conductivity at high temperatures. Based on the experimental data and theoretical dependences, the thermal conductivity coefficient of the fire-retardant layer of coked foam was calculated, which is 8.9×10-6 m2/s, due to the formation of a heat-insulating layer. The study results proved that the process of thermal insulation of textile material involves not only the decomposition of flame retardants with the formation of inert gases that interact with the flame on the sample surface but also the inhibition of heat transfer to the material treated with an intumescent coating that forms a thermally-insulating layer of coked foam on the fabric surface. The maximum possible penetration of temperature was estimated, namely generating a temperature on the sample's surface that significantly exceeds the ignition temperature of the fabric, and does not exceed 215 °C on the unheated surface. Thus, there is reason to argue about the possibility of targeted adjustment of the processes of fabric fire protection by applying coatings capable of forming a protective layer on the surface of the material, which inhibits the rate of heat transfer

Author Biographies

Yuriy Tsapko, National University of Life and Environmental Sciences of Ukraine; Kyiv National University of Construction and Architecture

Doctor of Technical Sciences, Professor

Department of Technology and Design of Wood Products

V. D. Glukhovsky Scientific Research Institute for Binders and Materials

Аleksii Tsapko, Ukrainian State Research Institute "Resource"; Kyiv National University of Construction and Architecture

PhD, Senior Researcher

Department of Research of Quality and Conditions of Storage of oil Products and Industrial Group of Goods

V. D. Glukhovsky Scientific Research Institute for Binders and Materials

Nataliia Buiskykh, National University of Life and Environmental Sciences of Ukraine

PhD

Department of Technology and Design of Wood Products

Oleksandra Horbachova, National University of Life and Environmental Sciences of Ukraine

PhD, Associate Professor

Department of Technology and Design of Wood Products

Serhii Mazurchuk, National University of Life and Environmental Sciences of Ukraine

PhD, Associate Professor

Department of Technology and Design of Wood Products

Andrii Matviichuk, V. I. Vernadsky National Library of Ukraine

PhD

Yuriy Sarapin, Fire Safety Department of the Armed Forces of Ukraine

Specialist

References

  1. Horrocks, A. R. (2014). High performance textiles for heat and fire protection. High Performance Textiles and Their Applications, 144–175. doi: https://doi.org/10.1533/9780857099075.144
  2. Ahmed, M. T., Morshed, M. N., Farjana, S., An, S. K. (2020). Fabrication of new multifunctional cotton–modal–recycled aramid blended protective textiles through deposition of a 3D-polymer coating: high fire retardant, water repellent and antibacterial properties. New Journal of Chemistry, 44 (28), 12122–12133. doi: https://doi.org/10.1039/d0nj02142c
  3. Dolez, P. I., Tomer, N. S., Malajati, Y. (2018). A quantitative method to compare the effect of thermal aging on the mechanical performance of fire protective fabrics. Journal of Applied Polymer Science, 136 (6), 47045. doi: https://doi.org/10.1002/app.47045
  4. Chan, S. Y., Si, L., Lee, K. I., Ng, P. F., Chen, L., Yu, B. et. al. (2017). A novel boron–nitrogen intumescent flame retardant coating on cotton with improved washing durability. Cellulose, 25 (1), 843–857. doi: https://doi.org/10.1007/s10570-017-1577-2
  5. Fire safety requirements on textile membranes in temporary building structures (2013). SP Technical research Institute of Sweden. Available at: https://www.diva-portal.org/smash/get/diva2:962753/FULLTEXT01.pdf
  6. Mandal, S., Song, G., Rossi, R. M., Grover, I. B. (2021). Characterization and modeling of thermal protective fabrics under Molotov cocktail exposure. Journal of Industrial Textiles, 152808372098497. doi: https://doi.org/10.1177/1528083720984973
  7. Zhu, H., Kannan, K. (2020). Determination of melamine and its derivatives in textiles and infant clothing purchased in the United States. Science of The Total Environment, 710, 136396. doi: https://doi.org/10.1016/j.scitotenv.2019.136396
  8. Ackerman, M., Batcheller, J., Paskaluk, S. (2015). Off Gas Measurements from FR Materials Exposed to a Flash Fire. AATCC Journal of Research, 2 (2), 1–12. doi: https://doi.org/10.14504/ajr.2.2.1
  9. Magovac, E., Vončina, B., Jordanov, I., Grunlan, J. C., Bischof, S. (2022). Layer-by-Layer Deposition: A Promising Environmentally Benign Flame-Retardant Treatment for Cotton, Polyester, Polyamide and Blended Textiles. Materials, 15 (2), 432. doi: https://doi.org/10.3390/ma15020432
  10. Kozlowski, R., Muzyczek, M., Mieleniak, B. (2004). Upholstery Fire Barriers Based on Natural Fibers. Journal of Natural Fibers, 1 (1), 85–95. doi: https://doi.org/10.1300/j395v01n01_06
  11. Skorodumova, O., Tarakhno, O., Chebotaryova, O., Hapon, Y., Emen, F. M. (2020). Formation of Fire Retardant Properties in Elastic Silica Coatings for Textile Materials. Materials Science Forum, 1006, 25–31. doi: https://doi.org/10.4028/www.scientific.net/msf.1006.25
  12. Tsapko, Y., Tsapko, A., Bondarenko, O. P. (2020). Research of Conditions of Removal of Fire Protection from Building Construction. Key Engineering Materials, 864, 141–148. doi: https://doi.org/10.4028/www.scientific.net/kem.864.141
  13. Tsapko, Y., Tsapko, О., Bondarenko, O. (2020). Determination of the laws of thermal resistance of wood in application of fire-retardant fabric coatings. Eastern-European Journal of Enterprise Technologies, 2 (10 (104)), 13–18. doi: https://doi.org/10.15587/1729-4061.2020.200467
  14. Tsapko, Y., Rogovskii, I., Titova, L., Bilko, T., Tsapko, А., Bondarenko, O., Mazurchuk, S. (2020). Establishing regularities in the insulating capacity of a foaming agent for localizing flammable liquids. Eastern-European Journal of Enterprise Technologies, 5 (10 (107)), 51–57. doi: https://doi.org/10.15587/1729-4061.2020.215130
  15. Potter, M. C. (2019). Engineering analysis. Springer, 434. doi: https://doi.org/10.1007/978-3-319-91683-5
  16. Janna, W. S. (2010). Engineering Heat Transfer. CRC Press, 692.
  17. Tsapko, Y., Tsapko, А., Bondarenko, O., Chudovska, V. (2021). Thermophysical characteristics of the formed layer of foam coke when protecting fabric from fire by a formulation based on modified phosphorus-ammonium compounds. Eastern-European Journal of Enterprise Technologies, 3 (10 (111)), 34–41. doi: https://doi.org/10.15587/1729-4061.2021.233479
  18. Tsapko, Y., Tsapko, А., Bondarenko, O. (2021). Defining patterns of heat transfer through the fire-protected fabric to wood. Eastern-European Journal of Enterprise Technologies, 6 (10 (114)), 49–56. doi: https://doi.org/10.15587/1729-4061.2021.245713

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Published

2022-04-30

How to Cite

Tsapko, Y., Tsapko А., Buiskykh, N., Horbachova, O., Mazurchuk, S., Matviichuk, A., & Sarapin, Y. (2022). Establishing regularities of temperature conductivity reduction when protecting fabric against fire by intumescent coating . Eastern-European Journal of Enterprise Technologies, 2(10 (116), 74–80. https://doi.org/10.15587/1729-4061.2022.254546