The research of the kinetics of sunflower cake extraction by ethyl alcohol

Authors

  • Павло Федорович Петік Ukrainian scientific-research Institute of fats and oils NAAN 61019, Kharkov, etc. Dziuba 2, Ukraine https://orcid.org/0000-0002-1618-3986
  • Валерій Васильович Гірман Ukrainian scientific-research Institute of fats and oils NAAN 61019, Kharkov, etc. Dziuba 2, Ukraine https://orcid.org/0000-0003-4298-2201
  • Олена Валеріївна Мазур Ukrainian scientific-research Institute of fats and oils NAAN 61019, Kharkov, etc. Dziuba 2, Ukraine

DOI:

https://doi.org/10.15587/1729-4061.2014.30426

Keywords:

ethanolic extraction, sunflower cake, kinetics, internal diffusion, oil content, miscella concentration

Abstract

The present paper deals with theoretical and experimental substantiation of the basic process laws of the sunflower cake extraction by unconventional solvent - ethyl alcohol. Industrial samples of sunflower cake in the form of granules and grits, for which the porosity parameters (porosity and filtration ratios) were defined, were subjected to the test. Physical model of the 8-step extractor, operating by the countercurrent irrigation principle was developed using a specially designed laboratory setup. The influence of some technological factors (duty of water, extraction time and oilseed material structure) on the sunflower oil extraction kinetics (original cake oil content variation in time) and miscella concentration at each extraction stage was experimentally found. Based on the experimental results, internal diffusion coefficient for ethanolic extraction of sunflower cake, depending on the porosity and filtration indicators was calculated using MathCad and MicrosoftExsel application package. It was shown that improved ethyl alcohol percolation in the granule is confirmed by the higher value of the coefficient of internal diffusion in the granule. The latter is about 2 times higher than that for the hexane extraction. New scientific data for the formulation of the values of process parameters for future technology were obtained.

Author Biographies

Павло Федорович Петік, Ukrainian scientific-research Institute of fats and oils NAAN 61019, Kharkov, etc. Dziuba 2

Candidate of technical Sciences, Director

Валерій Васильович Гірман, Ukrainian scientific-research Institute of fats and oils NAAN 61019, Kharkov, etc. Dziuba 2

Head of department

Department of research technology oil-extraction production

Олена Валеріївна Мазур, Ukrainian scientific-research Institute of fats and oils NAAN 61019, Kharkov, etc. Dziuba 2

Candidate of technical Sciences, head sector

Sector of research technologies oil-extraction production

References

  1. Mkhtyriants, L. A., Kornena, E. P., Martovshchuk, E. V., Mustafaev, S. K. (2009). Tekhnologyia otrasly (Proyzvodstvo rastytelnykh masel). SPb : HYORD, 352.
  2. Оseiko, M. I. (2006). Теkhnologiya roslynnykh olii. Кiev: Vаrtа, 280.
  3. GRAS Notification for Ethanol. (2004).United Statesfood and drug administration, Frito Lay, Inc. Washington : FDA, № 151. Available at: http://www.accessdata.fda.gov/scripts/fen/gras_notice/grn0151.pdf
  4. Ostroushko, V. L., Papchenko, V. Yu. (2012). Теkhnologichni aspekty protsesu еkstraktsii roslynnykh olii, Visnyk Natsionalnoho tekhnichnoho universitetu «KhPI», 34, 117–120.
  5. Petik, P. F. (2014). Vykorystannia alternatyvnykh rozchynnykiv dlia ekstraktsii roslynnykh olii, Intehrovani tekhnologii ta energozberezhennia, 2, 77–85.
  6. Prohramma razvytyia spyrtovoi, lykero-vodochnoi y vynodelcheskoi otrasley na 2003–2007 h.h., zatv. Postanovou Kabminu Ukrainy vid 01 kvitnia 2013 h., 451.
  7. Demydov, Y. N. (2008). Novye tekhnologycheskye protsessy v maslozhyrovoi promyshlennosty, Zbirtyk prats UkrNDIOZh UААN, 2, 14–17.
  8. Hron, R., Koltun, S., Cruci, A. (1982). Bio-Renewable Solvents for Vegetable Oil Extraction, Journal of the American Oil Chemists Society, 59 (9), 674–678. doi: 10.1007/bf02636034
  9. Regitanodarce, M. A. B.,Lima,U.D.(1986). Sunflower-seed oil extraction with ethanol, Journal of the American Oil Chemists Society, 63 (4), 428–430.
  10. Sinciro, F., Domingner, H., Nunez, M. F., Lema, F. M. (1998). Ethanol extraction of sunflower oil in a pulsing extractor, Journal of the American Oil Chemists Society, 75 (6), 753–754. doi: 10.1007/s11746-998-0220-7
  11. Маtiuhov, D. V. (2013). Rafynatsyonnyi effect etylovoho sryrta v dobyvaniyy y pererabotke podsolnechnoho masla, Sbornyk nauchnykh trudov SWorld. Materyaly mezhdynarodnoi nauchno-praktycheskoi konferentsyy «Sovremennye napravlenyia teoretycheskykh y prykladnykh yssledovanyi 2013», 1 (4), 63–68.
  12. Маtiuhov, D. V. (2013).Vlyianye pryrody rastvorytelia na protsess ekstraktsyy zhmykhov podsolnechnyka. Sbornyk nauchnykh trudov SWorld. Materyaly mezhdynarodnoi nauchno-praktycheskoi konferentsyy «Sovremennye napravlenyia teoretycheskykh y prykladnykh yssledovanyi 2013», 1 (4), 18–24.
  13. Маtiuhov, D. V. (2013). Кіnetyka ekstrahuvannia etanol rozchynnykh rechovyn makykhovoi krypky soniashnyku, Visnyk Natsionalnoho tekhnichnoho universitetu «KhPI», 55, 11–21.
  14. Маtiuhov, D. V., Hladkyi, F. F. (2013). Vplyv tekhnologichnykh parametriv na rezultat ekstraktsii makuhy soniashnyku etylovym spyrtom, Prohresyvni tekhnika ta takhnologii kharchovykh vyrobnytstv restorannoho hospodarstva i torhivli, 2 (18), 132–138.
  15. Маtiuhov, D. V. (2013). Vplyv umov etanolnoi ekstraktsii rechovyn makukhy soniashnyku na dunamiku protsessu. Sbornyk nauchnykh trudov SWorld. Materyaly mezhdynarodnoi nauchno-praktycheskoi konferentsyy «Sovremennye napravlenyia teoretycheskykh y prykladnykh yssledovanyi 2014», 1 (11), 51–55.
  16. Маtiuhov, D. V. (2013). Poshuk ta vykorystannia matematychnoi modeli rozchunnosti soniashnykovoi olii v etylovomu srurti, Visnyk Natsionalnoho tekhnichnoho universitetu «KhPI», 38, 152–155.
  17. Spyrt etylovyi rektyfikovanyi. Теkhnichni umovy. (2007). DSTU 4221 [Chynnyi vid 2003-10-14]. Кyiv: Derzhspozhyvstandart Ukrainy, 47.
  18. Zhmykhy y shroty. Оpredelenye vlahy, zhyra y proteyna metodom spektroskopyy v blyzhnei ynfrakrasnoi oblasty (1996). :HOST 30131 [Chynnyi vid 1997-01-01]. Мynsk : Standartynform, 19.
  19. Rzhekhyn, V. P., Serheev, A. H. (1964). Rukovodstvo po metodam yssledovanyia, takhnokhymycheskomu kontrolu y uchetu proyzvodstva v maslozhyrovoi promyshlennosty. Lviv: NPO «Maslozhyrprom», 2, 408.
  20. Mazur, O. V., Evtushenko, S. L., Katasonova, N. H., Lytvynenko, O. A. (2013). Меtodyka opredelenyia porystosty y udelnoi poverkhnosry zhmykha maslychnykh kultur, Visnyk Natsionalnoho tekhnichnoho universitetu «KhPI», 16 (989), 146–150.
  21. Belobrodov, V. V. (1966). Оsnovnye protsessy proyzvodstva rastytelnykh masel. Мoscow: Pushchevaia promyshlennost, 478.
  22. Lysnianskyi, V. M., Akselryd H. A. (1974). Ekstrahyrovanye v systeme tverdoe telo-zhydkost. Lviv: Khymyia, 256.
  23. Lykov, A. V., Mykhailov Yu. A. (1959). Теоryia perenosa enerhyy y vashestva. Мynsk : Yzd-vо АNBSSR, 330.
  24. Mazur, O. V. (2013). Udoskonalennia tekhnologii pidhotovky soniashnykovoi makukh do vydobuvannia olii. Tekhnologiia zhyriv, efirnukh masel y parfumerno-kosmetychnykh produktiv, 160

Published

2014-12-11

How to Cite

Петік, П. Ф., Гірман, В. В., & Мазур, О. В. (2014). The research of the kinetics of sunflower cake extraction by ethyl alcohol. Eastern-European Journal of Enterprise Technologies, 6(6(72), 13–18. https://doi.org/10.15587/1729-4061.2014.30426

Issue

Section

Technology organic and inorganic substances