Non-emulsion copolymerization in obtaining silicone-acrylic surfactant

Authors

  • Олеся Владимировна Рубан Institute of Chemical Technology Volodymyr Dahl East Ukrainian University st. Lenin, 31, Rubizhne, Lugansk region, Ukraine, 93009, Ukraine https://orcid.org/0000-0002-0044-1215
  • Екатерина Валерьевна Киселёва-Логинова Institute of Chemical Technology Volodymyr Dahl East Ukrainian University st. Lenin, 31, Rubizhne, Lugansk region, Ukraine, 93009, Ukraine https://orcid.org/0000-0003-0826-9285
  • Евгений Вадимович Попов Institute of Chemical Technology Volodymyr Dahl East Ukrainian University st. Lenin, 31, Rubizhne, Lugansk region, Ukraine, 93009, Ukraine https://orcid.org/0000-0001-7941-5134

DOI:

https://doi.org/10.15587/1729-4061.2014.33109

Keywords:

silicone acrylic polymer, polydimethylsiloxane, acrylic acid, non-emulsion copolymerization, surfactants

Abstract

The experiment-based paper presents non-emulsion hybride copolymerization of acrylic acid and polydimethylsiloxane in making the most pure silicone acrylic polymeric surfactant. We have determined optimal conditions for the synthesis. The study of copolymerization kinetics by means of identifying the acid number has determined the best reasonable time and temperature for the reaction—2 hours and 120  respectively, since after 2 hours the acid conversion makes up 78%, whereas polymer yield is 66%.

The synthesized silicone acrylic polymeric surfactant is a viscous transparent liquid that has no pungent smell and dissolves in organic solvents. We have identified and characterized the properties—molecular mass, viscosity and surface tension—of the obtained silicone acrylic polymer. The polymeric surfactant can be used as surface modifier in lacquer and paint products.

Author Biographies

Олеся Владимировна Рубан, Institute of Chemical Technology Volodymyr Dahl East Ukrainian University st. Lenin, 31, Rubizhne, Lugansk region, Ukraine, 93009

Postgraduate

Department of ecology

Екатерина Валерьевна Киселёва-Логинова, Institute of Chemical Technology Volodymyr Dahl East Ukrainian University st. Lenin, 31, Rubizhne, Lugansk region, Ukraine, 93009

Candidate of Technical Sciences

Department of ecology

Евгений Вадимович Попов, Institute of Chemical Technology Volodymyr Dahl East Ukrainian University st. Lenin, 31, Rubizhne, Lugansk region, Ukraine, 93009

Professor

Department of ecology

References

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Published

2014-12-11

How to Cite

Рубан, О. В., Киселёва-Логинова, Е. В., & Попов, Е. В. (2014). Non-emulsion copolymerization in obtaining silicone-acrylic surfactant. Eastern-European Journal of Enterprise Technologies, 6(6(72), 24–28. https://doi.org/10.15587/1729-4061.2014.33109

Issue

Vol. 6 No. 6(72) (2014): Technology organic and inorganic substances

Section

Technology organic and inorganic substances

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Copyright (c) 2014 Олеся Владимировна Рубан, Екатерина Валерьевна Киселёва-Логинова, Евгений Вадимович Попов

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