Investigation of interaction of aminoethylethylenediamine with sunflower oil

Authors

  • Анатолий Павлович Мельник UkrNDIgas Research Studies Institute 20 Chervonoshkilna nab, Kharkiv, Ukraine, 61010, Ukraine https://orcid.org/0000-0002-7088-1929
  • Ольга Петровна Чумак National Technical University “Kharkiv Polytechnic Institute” 21 Frunze str., Kharkiv, Ukraine, 61002, Ukraine
  • Сергей Григорьевич Малик UkrNDIgas Research Studies Institute 20 Chervonoshkilna nab., Kharkiv, Ukraine, 61010, Ukraine https://orcid.org/0000-0002-6683-7183
  • Алишер Евадиллович Хусанов M. Auezov South-Kazakhstan State University 5 Tauke Khan ave., Shymkent, Republic Kazakhstan, 160012, Kazakhstan

DOI:

https://doi.org/10.15587/1729-4061.2015.47732

Keywords:

sunflower oil, amidation, hydroxyethylethylenediamine, composition, kinetics, model, adequacy

Abstract

The interaction reaction of sunflower oil with hydroxyethylethylenediamine at molar ratios of reactants of from 1: 1 to 1: 3, and temperatures of 393 K – 433 K by changes in the amine concentration over time was investigated, based on which the rate constants, activation energy and entropy were calculated. Using a kinetic first-order reaction model, the estimated thermodynamic parameters, changes in the amine concentration over time were calculated and compared with the experimental values. Analysis of variance between concentrations indicates that the amine concentration can be used for the sunflower oil amidation reaction control only at the initial stage. This is caused by the fact that both nitrogen and oxygen-containing products that also react with amine are formed in the oil amidation.

Author Biographies

Анатолий Павлович Мельник, UkrNDIgas Research Studies Institute 20 Chervonoshkilna nab, Kharkiv, Ukraine, 61010

Doctor of Technicsl Science, Professor

Ольга Петровна Чумак, National Technical University “Kharkiv Polytechnic Institute” 21 Frunze str., Kharkiv, Ukraine, 61002

PhD

Department of technology of fats and fermentation products

Сергей Григорьевич Малик, UkrNDIgas Research Studies Institute 20 Chervonoshkilna nab., Kharkiv, Ukraine, 61010

Candidate of technical sciences

Department of physical and chemical research and processing of natural gas, condensate an oil

Алишер Евадиллович Хусанов, M. Auezov South-Kazakhstan State University 5 Tauke Khan ave., Shymkent, Republic Kazakhstan, 160012

Candidate of technical sciences

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Published

2015-08-18

How to Cite

Мельник, А. П., Чумак, О. П., Малик, С. Г., & Хусанов, А. Е. (2015). Investigation of interaction of aminoethylethylenediamine with sunflower oil. Eastern-European Journal of Enterprise Technologies, 4(6(76), 44–49. https://doi.org/10.15587/1729-4061.2015.47732

Issue

Section

Technology organic and inorganic substances