Kinetics of carbamide-formaldehyde interaction under different conditions with different concentration of chlorides and sulfates in the solution

Authors

  • Олена Анатоліївна Храброва Sevastopol national university of nuclear energy and industry St. of Kurchatova, 7, Sevastopol, 99033, Ukraine
  • Юлія Аркадіївна Омельчук Sevastopol national university of nuclear energy and industry St. of Kurchatova, 7, Sevastopol, 99033, Ukraine
  • Микола Дмитрович Гомеля National technical university of Ukraine «Kyiv polytechnic institute» pr. Pobedu, 37, Kiev, 03056, Ukraine

DOI:

https://doi.org/10.15587/1729-4061.2012.5570

Keywords:

Kinetics, formaldehyde, chlorides, sulphates

Abstract

Waste water generating in the production of ion exchange resins contains formaldehyde, chlorides and sulfates in its composition, exceeding the maximum allowable concentration, so there was a need to study various conditions of chlorides and sulfates content on the extraction of formaldehyde  from them. The existing thermal methods of sterilization of waste water during the production of ion exchange resins are not profitable  from an economic point of view, as there is the consumption of large quantities of natural gas, and formation of significant amount of highly mineralized concentrates. Thus, the development of water treatment method from formaldehyde,  based on chemical and physicochemical methods is an important issue. The article represents the results of studies of kinetic regularities of the interaction of carbamide with formaldehyde  in different ratios with different amounts of chlorides and sulfates, at different pH and temperature of solutions, generating during the production of ion exchange resins. The results can be used to assess the efficiency of waste water treatment from formaldehyde

Author Biographies

Олена Анатоліївна Храброва, Sevastopol national university of nuclear energy and industry St. of Kurchatova, 7, Sevastopol, 99033

Lector

Chair of Chemical Technological of nuclear power plants

Юлія Аркадіївна Омельчук, Sevastopol national university of nuclear energy and industry St. of Kurchatova, 7, Sevastopol, 99033

PhD in Chemistry, Assistant of professor, leader of  the institute|institution| of Ecological and informative safety|crashworthiness|

Микола Дмитрович Гомеля, National technical university of Ukraine «Kyiv polytechnic institute» pr. Pobedu, 37, Kiev, 03056

Dr. Sci. in Engineering., Professor, Head of the Department

Department of Ecology and Plant Polymers

References

  1. Система стандартов безопасности труда. Вредные вещества. Классификация и общие требования безопасности: ГОСТ 12.1.007-76. – [Действующий вид 01.01.1977]. – М.: Стандартинформ, 2007. – 7 с. – (Межгосударственный стандарт).
  2. Сальникова Е.О. Очистка сточных вод от сульфат ионов с помощью извести и оксосульфата алюминия / Е.О. Сальникова, И.Ф. Гофенберг, Е.Н. Тураника и др. // Химия и технология воды. – 1992. – 14, № 2. – С. 152 – 157.
  3. Омельчук Ю.А. Очистка шахтных вод от урана коагуляцией /
  4. Ю.А. Омельчук, Е.В. Рудковская, Н.Д. Гомеля // Энерготехнологии и ресурсосбережение: науч.-техн. журн. – 2011. – № 5. – С. 36 – 40.
  5. Кучерик Г.В. Использование электролиза для выделения хлоридов и сульфатов из щелочных регенерационных растворов / Г.В. Кучерик,
  6. Ю.А. Омельчук, Н.Д. Гомеля // Экологическая безопасность. – 2012. – Вып. 1/2012(13). – С. 68 – 72.
  7. Кучерик Г.В. Ионообменное выделение хлоридов и сульфатов из воды / Г.В. Кучерик, Ю.А. Омельчук, Н.Д. Гомеля // Сборник науч. трудов СНУЯЭиП. – 2010. – Вып. 3(35). – С. 129 – 136.
  8. Голтвяницька О.В. Видалення та розділення хлоридів і сульфатів при іонообмінному знесоленні води / О.В. Голтвяницька, Т.О. Шаблій, М.Д. Гомеля, С.С. Ставська // Східно-Європейський журнал передових технологій. – 2012. – № 1/6 (55). – С. 40 – 44.
  9. Chen Yu. Study on the treatment of formaldehyde wastewater by addition reaction: Challenges in Environmental Science and Computer Engineering (CESCE), International Conference: 6 – 7 March 2010 / Yu. Chen, Shun-sheng Yang, Zheng-jun Gong, Dong-mei Wang. – Wuhan, China, 2010, – Vol. 2. – Р. 293 – 296.
  10. Hesham R. Lotfy. A method for treating wastewater containing formaldehyde
  11. / Hesham R. Lotfy, I.G. Rashed // Water Research. – Elsevier Science Ltd. – 2002. – No. 36. – Р. 633 – 637.
  12. Jarusutthirak C. Treatment of formaldehyde-containing wastewater using membrane bioreactor / [C. Jarusutthirak, K. Sangsawang, S.Mattaraj,
  13. R. Jiraratananon] // Journal of environmental engineering. – American Society of Civil Engineers. – Vol. 138, No. 3. – Р. 265 – 271.
  14. Eiroa M. Biological treatment of industrial wastewater containing formaldehyde and formic acid / [M. Eiroa, A. Vilar, C. Kennes, MC. Veiga] // Water SA. – Association of Crop Science: Uganda, 2005. – Vol. 32, No 1. – Р. 115 – 118.
  15. Vossoughi M. Combined chemical and biological processes for the treatment of industrial wastewater containing formaldehyde / [M. Vossoughi, M Borgheai,
  16. H. Salehi, I. Alemzadeh] // Scientia Iranica. – Sharif University of Technology, 2001. – Vol. 8, No. 3. – Р. 223 – 227.
  17. Moussavi G. The removal of formaldehyde from concentrated synthetic wastewater using O3/MgO/H2O2 process integrated with the biological treatment /
  18. G. Moussavi, A. Yazdanbakhsh, M. Heidarizad // Journal of Hazardous Materials. – Elsevier B.V., 2009. – No. 171. – Р. 907 – 913.
  19. Conner A.H. Urea-formaldehyde adhesive resins / A.H. Conner // In: Joseph C, Salamone J.C, Demby A, Aller M. Encyclopedia of Polymeric Materials,
  20. CRC Press Inc., Boca Raton, Florida, USA. – 1996. – Vol. 2. – Р. 8495 – 8500.
  21. Bednarik V. Removal of formaldehyde from acrylic acid production wastewater / V. Bednarik, M. Vondruska // Environmental Engineering Science, 2003. – No. 20(6). – Р. 703 – 707.
  22. Masaya Okano. Kinetics of the condensation of melamine with formaldehyde / Masaya Okano, Yoshiro Ogata // J. Am. Chem. Soc., 1952. – Vol. 74 (22). – Р. 5728 – 5731.
  23. Liang Jiantao. Kinetics and reaction mechanism for formaldehyde wastewater using uv-fenton oxidation: Bioinformatics and Biomedical Engineering (iCBBE), 4th International Conference: 18 – 20 June 2010 / Liang Jiantao, Liu Xiangxuan, Zhang Zeyang. – Chengdu, China. – 2010. – 5 р.
  24. Smets G. Réactions de condensation de formaldéhyde et d’urée / G. Smets et A. Bofuee // Journal of polymer science. – 1951. – Vol. VIII, No. 4. – P. 371 – 394.
  25. Храброва Е.А. Исследования кинетики взаимодействия карбамида с формальдегидом сточных вод предприятий по производству ионообменных смол / Е.А. Храброва, Ю.А. Омельчук, Н.Д. Гомеля // Сборник науч. трудов СНУЯЭиП. – 2011. – Вып. 4(40). – С. 171 – 179.

Downloads

Published

2012-12-12

How to Cite

Храброва, О. А., Омельчук, Ю. А., & Гомеля, М. Д. (2012). Kinetics of carbamide-formaldehyde interaction under different conditions with different concentration of chlorides and sulfates in the solution. Eastern-European Journal of Enterprise Technologies, 6(6(60), 57–62. https://doi.org/10.15587/1729-4061.2012.5570

Issue

Vol. 6 No. 6(60) (2012): Technology organic and inorganic substances

Section

Technology organic and inorganic substances

License

Copyright (c) 2014 Олена Анатоліївна Храброва, Юлія Аркадіївна Омельчук, Микола Дмитрович Гомеля

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

The consolidation and conditions for the transfer of copyright (identification of authorship) is carried out in the License Agreement. In particular, the authors reserve the right to the authorship of their manuscript and transfer the first publication of this work to the journal under the terms of the Creative Commons CC BY license. At the same time, they have the right to conclude on their own additional agreements concerning the non-exclusive distribution of the work in the form in which it was published by this journal, but provided that the link to the first publication of the article in this journal is preserved.

A license agreement is a document in which the author warrants that he/she owns all copyright for the work (manuscript, article, etc.).
The authors, signing the License Agreement with TECHNOLOGY CENTER PC, have all rights to the further use of their work, provided that they link to our edition in which the work was published.
According to the terms of the License Agreement, the Publisher TECHNOLOGY CENTER PC does not take away your copyrights and receives permission from the authors to use and dissemination of the publication through the world's scientific resources (own electronic resources, scientometric databases, repositories, libraries, etc.).
In the absence of a signed License Agreement or in the absence of this agreement of identifiers allowing to identify the identity of the author, the editors have no right to work with the manuscript.
It is important to remember that there is another type of agreement between authors and publishers – when copyright is transferred from the authors to the publisher. In this case, the authors lose ownership of their work and may not use it in any way.