Research of consumer properties of leather filled with the use of electroactivated water reagent solutions

Authors

DOI:

https://doi.org/10.15587/1729-4061.2016.73337

Keywords:

semi­finished leather, filling, activated water, xanthan acrylamide, porosity, hydrophilic ability, elasticity

Abstract

Consumer properties of the filled macroporous chrome­tanned semi­finished leather obtained by the developed technology using electrochemically activated aqueous solutions of the composition comprising xanthan acrylamide were studied. Sorption­desorption properties of different sections of the filled material during its interaction with water, relaxation and deformation characteristics, differential moisture content on a thermo­gravi­calorie­metric installation, volume yield were determined.

It was found that the leather material obtained by the developed technology has higher elastic and plastic strain components by 1.7 and 1.3 times respectively compared with the current technology; porosity, volume yield and hygroscopic ability of obtained samples exceed those of the samples of the experimental technology by 4.5; 19.0; and 9.8–11.3 % respectively. The technology of filling of chrome­tanned leather material from pig skin is implemented by diffusion of the composition ingredients in the anolyte solution at pH 4.2–4.4 with the reduction of surface tension, the formation of mostly hydrogen bonds between the elements of the modified structure of collagen and the filler reagents. The interaction with water results in partial destruction of bonds that are restored after moisture removal. Optimum consumer properties are achieved at a certain ratio of the hydrophilic ability and the differential porosity type of the leather material.

The use of the filling composition involving xanthan acrylamide in the anolyte provides effective alignment of porosity in different sections of the semi­finished product due to preferred filling of large pores and increase in the specific volume of smaller pores with the composition. The resulting fine­pored leather material with the split fibrillar structure causes a smaller loss of its area by 0.3 % after moisturizing and drying processes compared with the current technology.

The leather material formed using the developed technology due to the complex of consumer properties is recommended for making the insides of shoes – insoles and lining and moisture removal material in the mechanical surface cleaning of products and structures.

Author Biographies

Anatoliy Danylkovych, Kyiv National University of Technologies and Design Nemirovich-Danchenko str., 2, Kyiv, Ukraine, 01011

Doctor of Technical Sciences, Professor

Department of Biotechnology, leather and fur

 

Oksana Romanyuk, Kyiv National University of Technologies and Design, Nemirovich-Danchenko str., 2, Kyiv, Ukraine, 01011

Associate professor

Department Technological safety and heat-mass Exchange processes

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Published

2016-08-24

How to Cite

Danylkovych, A., & Romanyuk, O. (2016). Research of consumer properties of leather filled with the use of electroactivated water reagent solutions. Eastern-European Journal of Enterprise Technologies, 4(6(82), 23–28. https://doi.org/10.15587/1729-4061.2016.73337

Issue

Vol. 4 No. 6(82) (2016): Technology organic and inorganic substances

Section

Technology organic and inorganic substances

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Copyright (c) 2016 Anatoliy Danylkovych, Oksana Romanyuk

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