Study of interaction of fatty acid salts with calcium hydroxide in cavitation fields

Authors

  • Зеновій Орестович Знак National University Lviv Polytechnik St. Bandera, 12, Lviv, 79013, Ukraine, Ukraine
  • Роман Володимирович Мних National University Lviv Polytechnik St. Bandera, 12, Lviv, 79013, Ukraine, Ukraine

DOI:

https://doi.org/10.15587/1729-4061.2013.9183

Keywords:

cavitation, cavitator, calcium hydroxide, activation, fatty acids salts, stearate, potentiometry, flotation.

Abstract

The article represents the results of the study of the interaction of fatty acids salts as components of wastewater with calcium hydroxide in the cavitation fields which were excited in the hydrodynamic cavitator of fluid type. The potentiometry method revealed that in the cavitation fields the fullness of usage of calcium hydroxide has been much higher than at the mechanical mixing of the reaction system. The method of infrared spectrographic analysis of the products of interaction of calcium hydroxide with sodium stearate at different hydrodynamic conditions confirmed almost complete conversion of Ca (OH)2 in the cavitation fields. The article analyses the system of interconnected physical and chemical processes during the interaction of calcium hydroxide with sodium stearate in the cavitation fields, and the cause-and-effect relations between them. The role of the cumulative effect, caused by the cavitation was noted in the intensification of the interaction between these reagents. The effect of flotation of the poorly soluble calcium stearate was revealed after the treatment of the reaction system in the hydrodynamic cavitator.

Author Biographies

Зеновій Орестович Знак, National University Lviv Polytechnik St. Bandera, 12, Lviv, 79013, Ukraine

Doctor of technical sciences, Professor

Department of chemistry and technology of inorganic substances

Роман Володимирович Мних, National University Lviv Polytechnik St. Bandera, 12, Lviv, 79013, Ukraine

PhD Student

Department of chemistry and technology of inorganic substances

References

  1. Ультразвуковое оборудование [Електронний ресурс] / ПКФ ООО „Сапфир”. – Режим доступу: http: //www.sapphire.ru/ — Загол. з екрану.
  2. Хмелев, Н.Н. Ультразвуковые многофункциональные и специализированные аппараты для интенсификации технологических процессов в промышленности, сельском и домашнем хозяйстве [Текст] / В.Н. Хмелев, Г.В. Леонов, Р.В. Барсуков. – Бийск: Изд-во Алт. гос. техн. ун-та. – 2007. – 400 с.
  3. Кудимов, Ю.Н. Электроразрядные процессы в жидкости и кинетика экстрагирования биологически активных компонентов. Часть 1. Ударные волны и кавитация [Текст] / Ю.Н. Кудимов, В.Т. Казуб, Е.В. Голов // Вестн. Тамб. гос. техн. ун-та. – 2002. – Т. 8, №2. – С. 253-264.
  4. Ивченко, В.М. Кавитационная технология [Текст] /В.М. Ивченко, В.А. Кулагин, А.Ф. Немчин; под ред. акад. Г.В. Логвиновича; – Красноярск: Изд-во КГУ, 1990. – 200 с.
  5. Балабышко, А.М. Гидромеханическое диспергирование [Текст] /А.М. Балабышко, А.И. Зимин, В.П. Ружицкий. – М.: Наука, 1998.– 330 с.

Published

2013-02-05

How to Cite

Знак, З. О., & Мних, Р. В. (2013). Study of interaction of fatty acid salts with calcium hydroxide in cavitation fields. Eastern-European Journal of Enterprise Technologies, 1(6(61), 7–10. https://doi.org/10.15587/1729-4061.2013.9183

Issue

Section

Technology organic and inorganic substances