Analysis of properties of modified kaolins and water-dispersion paints developed on their base

Authors

DOI:

https://doi.org/10.15587/1729-4061.2016.79358

Keywords:

water­dispersion paint, kaolin, modification, styrene­acrylic film former, 3­aminopropyltriethoxysilane

Abstract

Analysis of the effect of modified kaolins on the formation of properties of water­dispersed paints was conducted.

It was determined that, as a result of the kaolin modification by 3­aminopropyltriethoxysilane, their adsorption and physical and chemical properties (wettability and specific effective surface by water and benzene) were changed. Specific effective surface of kaolin from Glukhovetskiy deposit was increased by benzene by 26.47 %, from Prosianivskiy deposit – by 5.9 %. The same indicator by water was decreased by 26.1 % for the kaolin from Glukhovetskiy deposits and 3.4 % for the kaolin from Prosianivskiy deposit. The adsorption of acrylic­styrene polymer by respective kaolins was increased by 32.1 % and 23.8 %.

The processes of interaction of kaolins with a modifier and styrene­acrylic film former were studied; the parameters of the main characteristic bands responsible for valence fluctuations of reactive capable groups of kaolins and film former were analyzed. The results of the study demonstrated that, due to the modification of kaolins by 3­aminopropyltriethoxysilane, their polymeric philicity was increased.

The pre­modified kaolins, characterized by the most complete interaction with styrene­acrylic film former, are proposed to use as fillers for water­dispersion paints. This will ensure the higher performance properties of paints and  coatings: elasticity at the level of 2–4 mm, the edge angle of wetting at the level of 89–95 degrees, tensile strength in the range of 5.53–6.81 MPa, which is by 18–51 % larger than when using non­modified fillers. It was determined that improving the compatibility of kaolins with the film former of water­dispersion paints allow forming coatings more resistant to corrosive liquids, with low water absorption at the level of 8.1–9.7 % mass %, i. e., by 17.9 % – 10.4 lower than when adding non­modified kaolins.

Author Biographies

Nina Merezhko, Kyiv National University of Trade and Economics Kyoto str., 19, Kyiv, Ukraine, 02156

Doctor of Technical Science, Professor, Head of Department

Department of Commodity science and customs affairs

Svitlana Sirenko, Vinnitsa Trade and Economic Institute of Kyiv National University of Trade and Economics Soborna str., 87, Vinnytsia, Ukraine, 21050

PhD, аssociate professor

Department of Commodity, examination and Commercial Activities

Olga Shulga, Kyiv National University of Trade and Economics Kyoto str., 19, Kyiv, Ukraine, 02156

Assistant

Department of Commodity science and customs affairs

References

  1. Eller, K. (2013). The Role of Sustainability in the EU Paint Industry. Shanghai. Available at: http://bayferrox.com/uploads/tx_lxsmatrix/08_Karsten_Eller_final_presentation_en.pdf
  2. LeRoux, G. (2014). Sustainability: Impacts and Challenges in the Coatings. Industry. CFCM Trade Magazine. Available at: http://static1.1.sqspcdn.com/static/f/1493895/24315095/1391441907517/CFCM.Final.Jan17.2014.pdf?token=%2Fz%2FJS1qm%2BEB7Fho5ZOyelx4LSwQ%3D.3
  3. Komakha, V. O., Sviderskyj, V. A. (2014). Stan ta perspektyvy rozvytku vitchyznyanogo rynku bilyx mineralnyx napovnyuvachiv dlya lakofarbovyx materialiv. Visnyk Lvivskoyi komercijnoyi akademiyi (Seriya tovaroznavcha), 14, 27–33.
  4. Tracton, A. A. (2006). Coating technology handbook. New York: CRC Press, 936.
  5. Stoye, D., Freitag, W. (1998). Paints, coatings and solvents. New York: Wiley–VCH, 413.
  6. Sviderskyi, V., Merezhko, N., Komakha, V., Shulga O. (2015). Prospects of using modified kaolin and carbonates as fillers for paints. In Proc. of the13th International Commodity Science Conference, 66.
  7. Komakha, V. O., Sviderskyj, V. A. (2015). Purposeful modification of carbonate fillers for waterborne paints. Technology audit and production reserves, 2 (4 (22)), 12–16. doi: 10.15587/2312-8372.2015.40242
  8. Balczár, I., Korim, T., Kovács, A., Makó, É. (2016). Mechanochemical and thermal activation of kaolin for manufacturing geopolymer mortars – Comparative study. Ceramics International, 42 (14), 15367–15375. doi: 10.1016/j.ceramint.2016.06.182
  9. Zykova, J., Kalendova, A., Matějka, V., Zadrapa, P., Malač, J. (2010). Influence of kaolinite modification on the PVC composites properties (3rd WSEAS International Conference on Materials Science). Portugal. Available at: http://www.wseas.us/e-library/conferences/2010/Faro/MATSE/MATSE-05.pdf
  10. Wu, W., Tian, L. (2013). Formulation and morphology of kaolin-filled rubber composites. Applied Clay Science, 80-81, 93–97. doi: 10.1016/j.clay.2013.06.025
  11. Zhang, Y., Liu, Q., Zhang, S., Zhang, Y., Zhang, Y., Liang, P. (2016). Characterization of kaolinite/styrene butadiene rubber composite: Mechanical properties and thermal stability. Applied Clay Science, 124-125, 167–174. doi: 10.1016/j.clay.2016.02.002
  12. Salnik, V. G., Sviderskyj, V. A., Chernyak, L. P. (2010). Zastosuvannya modifikovanogo kaolinu dlya regulyuvannya vlastivostey vodnih dispersnih sistem. Naukovi visti NTUU «KPI», 3, 133–137.
  13. Qiu, X., Lei, X., Alshameri, A., Wang, H., Yan, C. (2014). Comparison of the physicochemical properties and mineralogy of Chinese (Beihai) and Brazilian kaolin. Ceramics International, 40 (4), 5397–5405. doi: 10.1016/j.ceramint.2013.10.121
  14. Prado, A. G. S., Airoldi, C. (2001). Adsorption, preconcentration and separation of cations on silica gel chemically modified with the herbicide 2,4-dichlorophenoxyacetic acid. Analytica Chimica Acta, 432 (2), 201–211. doi: 10.1016/s0003-2670(00)01372-6
  15. Mikanovic, N., Jolicoeur, C., Page, M. (2006). Influence of Surfactant Chemical Admixtures on the Stability and Rheological Properties of Calcium Carbonate and Cement Pastes. In Proc. of Conference “Recent developments in superplasticizers”, 321–344.
  16. Malicka-Soczka, A., Domka, L., Kozak, A. (2010). Kaolin modified with silane compounds as a filler used in rubber industry. Physicochemical Problems of Mineral Processing, 44, 151–156.
  17. Domka, L., Malicka, A., Stachowiak, N. (2008). The effect of kaolin modification of silane coupling agents on the properties of the polyethylene composites. Polish Journal of Chemical Technology, 10 (2), 5–10. doi: 10.2478/v10026-008-0020-8
  18. Avila, L. R., de Faria, E. H., Ciuffi, K. J., Nassar, E. J., Calefi, P. S., Vicente, M. A., & Trujillano, R. (2010). New synthesis strategies for effective functionalization of kaolinite and saponite with silylating agents. Journal of Colloid and Interface Science, 341 (1), 186–193. doi: 10.1016/j.jcis.2009.08.041
  19. Sviderskiy, V. A., Sikorskiy, A S., Mironyuk, A. V. (2013). Rheological behavor of kaoline water suspensions in presence of surfactants. Technology audit and production reserves, 2 (1 (10)), 45–48. Available at: http://journals.uran.ua/tarp/article/view/12959/10849
  20. Merezhko, N. V., Komakha, V. O. (2015). Tovaroznavcha otsInka Interrnih vodno-dispersnih farb na osnovi modifIkovanih karbonatnih napovnyuvachiv. In Proc. of Conference Suchasne materialoznavstvo ta tovaroznavstvo: teoriya, praktika, osvita, 200–202.
  21. Karavaev, T. A. (2014). Gidrofobnist pokrittiv z vodno–dispersiynih farb ta sposobi yiyi pidvischennya. Visnik Cherkaskogo derzhavnogo tehnologichnogo universitetu. Seriya: tehnichni nauki, 2, 106–112.
  22. Domka, L., Malicka, A., Stachowiak, N. (2008). Production and Structural Investigation of Polyethylene Composites with Modified Kaolin. Acta Physica Polonica A, 114 (2), 413–421. doi: 10.12693/aphyspola.114.413
  23. Rissa, K., Lepistö, T., Yrjölä, K. (2006). Effect of kaolin content on structure and functional properties of water-based coatings. Progress in Organic Coatings, 55 (2), 137–141. doi: 10.1016/j.porgcoat.2005.09.009
  24. Zolotov, M. S., Lyubchenko, M. A., Volyuvach, S. V. (2010). Modifitsirovanyie zaschitno–dekorativnyie pokryitiya na osnove akrilovyih polimerov. In Proc. of Unitech Proceedings, 475–479.
  25. Zolotov, M. S., Lyubchenko, M. A. (2013). Povyishenie adgezionnoy prochnosti i dolgovechnosti modifitsirovannyih zaschitno-dekorativnyih akrilovyih pokryitiy. Zbirnik naukovih prats Poltavskogo natsionalnogo tehnichnogo universitetu im. Yu. Kondratyuka. Ser.: Galuzeve mashinobuduvannya, budivnitstvo, 4 (1), 123–131.
  26. Selyaev, V. P. (2010). Polimernyie pokryitiya dlya betonnyih i zhelezobetonnyih konstruktsiy. Saransk: Izd-vo SVMO, 224.
  27. Kazakova, E. E. (2003). Vodno-dispersionnyie akrilovyie lakokrasochnyie materialyi stroitelnogo naznacheniya. Moscow: Izd-vo OOO «Peynt–Media», 136.

Downloads

Published

2016-10-30

How to Cite

Merezhko, N., Sirenko, S., & Shulga, O. (2016). Analysis of properties of modified kaolins and water-dispersion paints developed on their base. Eastern-European Journal of Enterprise Technologies, 5(6 (83), 11–16. https://doi.org/10.15587/1729-4061.2016.79358

Issue

Vol. 5 No. 6 (83) (2016): Technology organic and inorganic substances

Section

Technology organic and inorganic substances

License

Copyright (c) 2016 Nina Merezhko, Svitlana Sirenko, Olga Shulga

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

The consolidation and conditions for the transfer of copyright (identification of authorship) is carried out in the License Agreement. In particular, the authors reserve the right to the authorship of their manuscript and transfer the first publication of this work to the journal under the terms of the Creative Commons CC BY license. At the same time, they have the right to conclude on their own additional agreements concerning the non-exclusive distribution of the work in the form in which it was published by this journal, but provided that the link to the first publication of the article in this journal is preserved.

A license agreement is a document in which the author warrants that he/she owns all copyright for the work (manuscript, article, etc.).
The authors, signing the License Agreement with TECHNOLOGY CENTER PC, have all rights to the further use of their work, provided that they link to our edition in which the work was published.
According to the terms of the License Agreement, the Publisher TECHNOLOGY CENTER PC does not take away your copyrights and receives permission from the authors to use and dissemination of the publication through the world's scientific resources (own electronic resources, scientometric databases, repositories, libraries, etc.).
In the absence of a signed License Agreement or in the absence of this agreement of identifiers allowing to identify the identity of the author, the editors have no right to work with the manuscript.
It is important to remember that there is another type of agreement between authors and publishers – when copyright is transferred from the authors to the publisher. In this case, the authors lose ownership of their work and may not use it in any way.