Change of montmorilonite surfaсe structure with cationic surfactants adsorption

Authors

  • Антон Олегович Голембіовський National Technical University of Ukraine “Kyiv Polytechnic Institute” Peremogy ave., 37, Kyiv, Ukraine, 03056, Ukraine https://orcid.org/0000-0002-0838-3718
  • Анна Миколаївна Брезіцька National Technical University of Ukraine “Kyiv Polytechnic Institute” Peremogy ave., 37, Kyiv, Ukraine, 03056, Ukraine
  • Лариса Миколаївна Спасьонова National Technical University of Ukraine “Kyiv Polytechnic Institute” Peremogy ave., 37, Kyiv, Ukraine, 03056, Ukraine https://orcid.org/0000-0002-7562-7241

DOI:

https://doi.org/10.15587/1729-4061.2014.26043

Keywords:

surface adsorption, montmorillonite, quaternary alkylammonium salts, sedimentation, macroelectrophoresis, chromium, cobalt

Abstract

This paper shows the influence of cationic surface-active agents (SAA) with a different structure of the hydrophobic chain on the modification of the surface structure of silicate mineral montmorillonite and adsorptive properties of the resultant sorbent for extracting ions of chromium (VI) and cobalt (II) from aqueous media. Macroelectrophoresis and sorption methods for designating the selected samples were used in the research. It was proved that increasing the amount of surfactants added to a dispersed system, long-chain surfactants tend to form more stable hemicellar structure on the clay surface and more fully recharge it. It was found that the increasing the number of the hydrocarbon chain links from 1 to 16 the physicochemical characteristics of the obtained materials are changed dramatically: the adsorption of chromium increases to about 45 mg/g, while the adsorption of cobalt falls to zero in the full range of the surface-active agents concentrations. The research results will be useful and important in obtaining sorbents for extracting chromium (VI) ions from aqueous media.

Author Biographies

Антон Олегович Голембіовський, National Technical University of Ukraine “Kyiv Polytechnic Institute” Peremogy ave., 37, Kyiv, Ukraine, 03056

Ph.D. student

Chemical Technology of Ceramics and Glass Department

Анна Миколаївна Брезіцька, National Technical University of Ukraine “Kyiv Polytechnic Institute” Peremogy ave., 37, Kyiv, Ukraine, 03056

Student

Chemical Technology of Ceramics and Glass Department

Лариса Миколаївна Спасьонова, National Technical University of Ukraine “Kyiv Polytechnic Institute” Peremogy ave., 37, Kyiv, Ukraine, 03056

Ph.D. in Chemistry, professor assistant

Chemical Technology of Ceramics and Glass Department

References

  1. Kornilovych, B. Yu., Andrievska, O. R., Plemiannikov, M. M., Spasonova L. M. (2013). Physical chemistry of silica and nanodisperse silicates. Kyiv, Ukraine: Osvita Ukrainy, 178.
  2. Bergaya, F., Theng, B. K. G., Lagaly, G. (2006). Developments in clay science. Handbook of clay science. Amsterdam, Kingdom of the Netherlands: Elsevier, 1224.
  3. Yariv, S. (2002). Organo–clay complexes and interactions. New York, USA: Marcel Dekker, 688.
  4. De Paiva, L. B., Morales, A. R., Valenzuela Díaz, F. R. (2008). Organoclays: Properties, preparation and applications. Applied Clay Science, 42 (1-2), 8–24. doi:10.1016/j.clay.2008.02.006
  5. Lagaly, G. (1981). Characterization of Clays by Organic Compounds. Clay Minerals, 16 (1), 1–21. doi:10.1180/claymin.1981.016.1.01
  6. Mittal, V., Herle, V. (2008). Physical adsorption of organic molecules on the surface of layered silicate clay platelets: A thermogravimetric study. Journal of Colloid and Interface Science, 327 (2), 295–301. doi:10.1016/j.jcis.2008.08.036
  7. Hu, Z., He, G., Liu, Y. et al. (2013). Effects of surfactant concentration on alkyl chain arrangements in dry and swollen organic montmorillonite. Applied Clay Science, 75-76, 134–140, doi: 10.1016/j.clay.2013.03.004
  8. Kajino, M., Saito, T., Okamoto M. (2010). Nonisothermal order–disorder phase transition of alkylammonium ions in nanoconfined space. Applied Clay Science, 48 (1-2), 73–80, doi: 10.1016/j.clay.2009.11.025
  9. Tarasevich, Yu. I. (1981). Natural sorbents in water treatment processes. Kyiv, Ukraine: Naukova Dumka, 208.
  10. Golembiovskyi, A. O. (2014). Physical and chemical organoclay synthesis features for adsorption of chromium. Eastern–European Journal of Enterprise Technologies, 6 (67), 4–7.
  11. Jiang, N., Li, P., Wang, Y. (2005). Aggregation behavior of hexadecyltrimethylammonium surfactants with various counterions in aqueous solution. Journal of Colloid and Interface Science, 286 (2), 755–760, doi: 10.1016/j.jcis.2005.01.064
  12. Mukerjee, P., Mysels, K. J. (1971). Critical Micelle Concentrations of Aqueous Surfactant Systems. Washington D.C., U.S.: NBS, 222.
  13. Rubingh, D. N., Holland, P. M. (1991). Cationic Surfactants: Physical Chemistry. Boca Raton, U.S. (Florida): CRC Press, 544.
  14. Penner, D., Lagaly, G. (2000). Influence of organic and inorganic salts on the coagulation of montmorillonite dispersions. Clays and Clay Minerals, 48 (2), 246–255, doi: 10.1346/ccmn.2000.0480211
  15. Tarasevich, Yu. I., Ovcharenko, F. D. (1975). Adorption on clay minerals. Kyiv, Ukraine: Naukova Dumka, 351.
  16. Koyuncua, H., Yildiz, N., Salgin U. (2011). Adsorption of o–, m– and p–nitrophenols onto organically modified bentonites. Journal of Hazardous Materials, 185 (2-3), 1332–1339, doi: 10.1016/j.jhazmat.2010.10.050
  17. Hu, B., Luo, H. (2010). Adsorption of hexavalent chromium onto montmorillonite modified with hydroxyaluminum and cetyltrimethylammonium bromide. Applied Surface Science, 257 (3), 769–775, doi: 10.1016/j.apsusc.2010.07.062

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Published

2014-08-08

How to Cite

Голембіовський, А. О., Брезіцька, А. М., & Спасьонова, Л. М. (2014). Change of montmorilonite surfaсe structure with cationic surfactants adsorption. Eastern-European Journal of Enterprise Technologies, 4(6(70), 53–57. https://doi.org/10.15587/1729-4061.2014.26043

Issue

Vol. 4 No. 6(70) (2014): Technology organic and inorganic substances

Section

Technology organic and inorganic substances

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Copyright (c) 2014 Антон Олегович Голембіовський, Анна Миколаївна Брезіцька, Лариса Миколаївна Спасьонова

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