Analysis of the behavior of low-molecular cationic and high-molecular anionic surfactants on the interface of phases «binary aqueous solution – air»

Authors

DOI:

https://doi.org/10.15587/2313-8416.2017.97643

Keywords:

surface properties, binary solutions, hexadecylpyridinium bromide, carboxymethylcellulose sodium salt

Abstract

Specific features of the behavior of hexadecylpyridinium bromide and sodium carboxymethyl cellulose at the interface between solution-air phases at different weight ratios of components in solutions, pH of the medium at a constant concentration of cationic surfactant are studied. The composition of adsorption layers and the parameter of intermolecular interaction of surfactants in them are calculated. Optimal conditions for surface concentration of cationic surfactants are proposed

Author Biographies

Olga Voliuvach, I. I. Mechnykov Odessa National University Dvoryanska str., 2, Odessa, Ukraine, 65082

PhD, Senior researcher

Department of Microbiology, Virology and Biotechnology

Yuriy Ishkov, I. I. Mechnykov Odessa National University Dvoryanska str., 2, Odessa, Ukraine, 65082

Doctor of Chemical Sciences, Professor

Department of Organic Chemistry

References

Holmberg, K., Jonsson, B., Kronberg, B., Lindman, B. (2007). Surfactants and Polymer in Aqueous Solution. Moscow: BEAN. Laboratory knowledge, 528.

Kochkodan, O. D., Karmazin, T. V. (2014). The thermodynamic characteristics of micelle formation as a measure of interaction between the molecules of water and surfactant. SWorld, 30 (4), 91–96.

Voliuvach, O. V., Streltsova, O. О. (2011). Adsorption of dodecylpyridinium chloride from solutions containing Tweens (Tween-40, Tween-60). Ukrainian Chemical Journal, 77 (3), 21–25.

Voliuvach, O. V. (2013). Quantitative and thermodynamic assessment of the interaction of iodide hexadecylpyridinium and Tween-20 in mixed aqueous solutions and adsorption layers. Herald of the National University "Lviv Polytechnic". Series: Chemistry, materials technology and their applications, 761, 64–70.

Streltsova, E. A., Voliuvach, O. V. (2009). Analysis of adsorption hexadecylpyridinium bromide and sodium alkylsulfate on the binary surfactant solution – air phase interface. Bulletin of the Odessa National University. Series: Chemistry, 14 (12), 114–120.

Voliuvach, O. V., Menchuk, V. V., Dragunovskaya, O. I. (2012). Pat. No. 70434 UA. Detergent based on a synergistic combination of cationic and non-ionic surfactants. MPK C11D 1/72. No. u201114074; declareted: 29.11.2011; published: 11.06.2012, Bul. No. 11.

Voliuvach, O. V. (2006). Colloidal-Сhemical Regularities of Isolation of Hexadecylpyridinium Salts from Aqueous Solutions. Kyiv, 135.

Voliuvach, O. V. (2011). Intensification of process flotational isolation sodium dodecylsulfate from aqueous solutions at the presence of Tweens. Questions of chemistry and chemical technology, 6, 194–199.

Langevin, D. (2009). Complexation of oppositely charged polyelectrolytes and surfactants in aqueous solutions. Advances in Colloid and Interface Science, 147-148, 170–177. doi: 10.1016/j.cis.2008.08.013

Llamas, S., Guzman, E., Ortega, F., Baghdadli, N., Cazeneuve, C., Rubio, R. G., Luengo, G. S. (2015). Adsorption of polyelectrolytes and polyelectrolytes-surfactant mixtures at surfaces: a physico-chemical approach to a cosmetic challenge. Advances in Colloid and Interface Science, 222, 461–487. doi: 10.1016/j.cis.2014.05.007

Zhilyakova, E. T., Popov, N. N., Novikov, M. Yu., Novikov, O. О., Khalikov, M. A., Kazakov, V. S. (2011). Study of physico-chemical and technological characteristics of the sodium carboxymethylcellulose to create long-acting dosage form with a liquid dispersion medium. Scientific statements Belgorod State University. Series: Medicine. Pharmacy, 13-2 (4 (99)), 146–153.

Ivankin, A. N., Panferov, V. I., Fahretdinov, H. A., Vostrikova, N. I., Golovanova, P. M. (2015). Nanomicrocomposite wound coverings on the basis of collagen and carboxymethylcellulose. Forest Gazette. Rational use of forest resources and wood products, 19 (1), 41–45.

Dhar, N., Au, D., Berry, R. C., Tam, K. C. (2012). Interactions of nanocrystalline cellulose with an oppositely charged surfactant in aqueous medium. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 415, 310–319. doi: 10.1016/j.colsurfa.2012.09.010

Mata, J., Patel, J., Jain, N., Ghosh, G., Bahadur, P. (2006). Interaction of cationic surfactants with carboxymethylcellulose in aqueous media. Journal of Colloid and Interface Science, 297 (2), 797–804. doi: 10.1016/j.jcis.2005.11.022

Liu, J., Zheng, L., Sun, D., Wei, X. (2010). Salt effect on the complex formation between 1-dodecyl-3-methylimidazolium bromide and sodium carboxymethylcellulose in aqueous solution. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 358 (1-3), 93–100. doi: 10.1016/j.colsurfa.2010.01.034

Wu, Q., Du, M., Shangguan, Y., Zhou, J., Zheng, Q. (2009). Investigation on the interaction between C16TAB and NaCMC in semidilute aqueous solution based on rheological measurement. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 332 (1), 13–18. doi: 10.1016/j.colsurfa.2008.08.022

Antonov, N. M. (2015). Development of composite materials based on a polymer Na-CMC with metal powder fillers for the formation of functional coatings and porous films. Novocherkassk, 329.

Koksharov, A. V. (2013). Improvement of fire-extiоnguishing capability low expansion foam. Bulletin of Voronezh Institute of Russian Ministry for Emergency Situations, 4 (9), 48–49.

Zhang, H., Deng, L., Sun, P., Que, F., Weiss, J. (2016). Solubilization of octane in cationic surfactant–anionic polymer complexes: Effect of ionic strength. Journal of Colloid and Interface Science, 461, 88–95. doi: 10.1016/j.jcis.2015.09.028

Tiitu, M., Laine, J., Serimaa, R., Ikkala, O. (2006). Ionically self-assembled carboxymethyl cellulose/surfactant complexes for antistatic paper coatings. Journal of Colloid and Interface Science, 301 (1), 92–97. doi: 10.1016/j.jcis.2006.04.072

Downloads

Published

2017-04-21

Issue

Vol. 4 (2017)

Section

Chemistry

License

Copyright (c) 2017 Olga Voliuvach, Yuriy Ishkov

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Our journal abides by the Creative Commons CC BY copyright rights and permissions for open access journals.

Authors, who are published in this journal, agree to the following conditions:

1. The authors reserve the right to authorship of the work and pass the first publication right of this work to the journal under the terms of a Creative Commons CC BY, which allows others to freely distribute the published research with the obligatory reference to the authors of the original work and the first publication of the work in this journal.

 2. The authors have the right to conclude separate supplement agreements that relate to non-exclusive work distribution in the form in which it has been published by the journal (for example, to upload the work to the online storage of the journal or publish it as part of a monograph), provided that the reference to the first publication of the work in this journal is included.