Application of the Bjerrum model to pure water electric conductivity
DOI:
https://doi.org/10.15587/2313-8416.2019.188649Keywords:
water electrical conductivity, ionization constant of water, Bjerrum model, activation energy, pH measurementAbstract
An alternative mechanism of electrical conductivity in water is considered. Calculations of activation energies for flow and ionization show their proportionality. Therefore, it is assumed that during the water ionization, not intramolecular forces are involved, but intermolecular and electrical conductivity of water is associated with the appearance in it of L and D defects in hydrogen bonds between water molecules considered in the Bjerrum model for ice
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