SORPTION OF SULFANILIC ACID AND COPPER IONS BY ACTIVATED CARBON MODIFIED WITH METAL OXIDES

Authors

  • Ирина Владимировна Косогина National Technical University of Ukraine "Igor Sikorsky Kyiv Polytechnic Institute", Ukraine https://orcid.org/0000-0002-9795-7110
  • Наталья Аркадиевна Клименко Colloid Chemistry and Chemistry of Water, State Research Institute, Ukraine https://orcid.org/0000-0003-0693-865X
  • Людмила Андреевна Савчина Colloid Chemistry and Chemistry of Water, State Research Institute,
  • Светлана Александровна Кирий National Technical University of Ukraine "Igor Sikorsky Kyiv Polytechnic Institute", Ukraine https://orcid.org/0000-0002-2805-7821
  • Игорь Михайлович Астрелин National Technical University of Ukraine "Igor Sikorsky Kyiv Polytechnic Institute", Ukraine https://orcid.org/0000-0002-8775-2744
  • Елена Александровна Самсони-Тодорова Colloid Chemistry and Chemistry of Water, State Research Institute,

DOI:

https://doi.org/10.24025/2306-4412.3.2019.178235

Keywords:

sorption, modified activated carbon, structural-sorption characteristics, sulfanilic acid, copper ions, water treatment.

Abstract

The possibility of using activated carbon brand Filtrasorb 300 modified with metal oxides (F300 M) in comparison with unmodified (F300 H) for the simultaneous extraction of organic com-pounds and copper ions from water has been established. A solution of metal chloride obtained by acid-thermal activation of waste from alumina production "red mud" is used as a modifier. The process of sulfanilic acid and copper ions sorption by modified and unmodified activated carbon Filtrasorb 300 (AC F300) is investigated. The structural-sorption characteristics of the studied materials, such as: static exchange cationic and anionic capacities and the number of surface groups (carboxyl, lactone, phenolic), are determined. Positive effect of activated carbon modification by metal oxides that has been obtained as a result of acid-thermal treatment of “red mud” is shown. The presence of negatively charged active centers on modified activated carbon surface makes it possible to increase by 59 % the value of sulfanilic acid adsorption due to the interaction of the ma-terial surface with –NH2 group of the acid with the absence of copper ions in the solution, which is 24 % more than AB F300. Simultaneous presence of copper ions and sulfanilic acid reduces their adsorption on the modified sorbent as a result of blocking the active groups and reducing the electrostatic interaction. Taking into account the complex nature of physical-chemical interactions in a system that contains sulfanilic acid with acidic and basic groups, and the competing effect under certain conditions, it can be expected that the modification of activated carbon with a metal chloride solution (obtained by acidic activation of alumina production wastes with their subsequent conversion to oxide form), is a promising direction in water treatment in case of containing both organic compounds and non-ferrous metal ions.

Author Biographies

Ирина Владимировна Косогина, National Technical University of Ukraine "Igor Sikorsky Kyiv Polytechnic Institute"

доцент кафедры технологии неорганических веществ, водоочистки и общей химической технологии, Химико-технологический факультет, Национальный технический университет Украины «Киевский политехнический институт имени Игоря Сикорского»,

Наталья Аркадиевна Клименко, Colloid Chemistry and Chemistry of Water, State Research Institute

зам.директора института коллоидной химии и химии воды им. А.В. Думанского НАН Украины, доктор химических наук, профессор

Людмила Андреевна Савчина, Colloid Chemistry and Chemistry of Water, State Research Institute

старший научный сотрудник института коллоидной химии и химии воды им. А.В. Думанского НАН Украины

Светлана Александровна Кирий, National Technical University of Ukraine "Igor Sikorsky Kyiv Polytechnic Institute"

ассистент кафедры технологии неорганических веществ, водоочистки и общей химической технологии, Химико-технологический факультет, Национальный технический университет Украины «Киевский политехнический институт имени Игоря Сикорского»

Игорь Михайлович Астрелин, National Technical University of Ukraine "Igor Sikorsky Kyiv Polytechnic Institute"

Декан Химико-технологичного факультета, Национальный технический университет Украины «Киевский политехнический институт имени Игоря Сикорского», доктор технических наук, профессор, заслуженный деятель науки и техники Украины.

Елена Александровна Самсони-Тодорова, Colloid Chemistry and Chemistry of Water, State Research Institute

научный сотрудник Института коллоидной химии и химии воды им. А.В. Думанского НАН Украины

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Published

2019-10-23

How to Cite

Косогина, И. В., Клименко, Н. А., Савчина, Л. А., Кирий, С. А., Астрелин, И. М., & Самсони-Тодорова, Е. А. (2019). SORPTION OF SULFANILIC ACID AND COPPER IONS BY ACTIVATED CARBON MODIFIED WITH METAL OXIDES. Bulletin of Cherkasy State Technological University, (3), 83–91. https://doi.org/10.24025/2306-4412.3.2019.178235

Issue

No. 3 (2019)

Section

Chemical Technologies and Engineering, Environmental Safety

URN

http://vtn.chdtu.edu.uaurn:2306:44553.2019.178235

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