GREEN SYNTHESIS OF SILVER NANOPARTICLES AND THEIR CATALYTIC APPLICATION FOR THE DEGRADATION OF ORGANIC POLLUTANTS
DOI:
https://doi.org/10.24025/2306-4412.3.2019.178444Keywords:
silver nanoparticles, plasma discharge, aqueous extract, frute waster, methilen bluAbstract
A simple and rapid method of green synthesis of silver nanoparticles (AgNPs) was developed using aqueous extract of grape pomas (GP) obtained from by plasma-chemical extraction technique, and their catalitic potential was investigated. With this aim, the plasma-chemical obteained aqueous solutions of grape pomace and AgNO3 (0.25-6.0 mM) were mixed (1:1 v/v), and heated for 10 mim. The synthesized GP-AgNPs were characterized by UV-visible spectroscopy, AFM, DSL analyses. The synthesized AgNPs showed an intense surface plasmon resonance band at 405-420 nm. The AgNPs were in highly uniform shape (everage size 20 nm). The role of pH in the green synthesis of silver nanoparticles (AgNPs) is investigated. The presence of silver nanoparticles with sun light was proven very effective for degradation of organic dyes. The reaction kinetics was found to be pseudo first order with respect to the dye concentration. The outcomes of the current study confirmed that the synthesized AgNPs had an awesome guarantee for application in catalysis and wastewater treatmen.
References
W. Zhang, X. Xiao, T. An, Z. Song, J. Fu, G. Sheng, and M. Cui, "Kinetics, degradation pathway and reaction mechanism of advanced oxidation of 4-nitrophenol in water by a UV/H2O2 process," J. Chem. Technol. Biotechnol., vol. 78, pp. 788-794, 2003.
R. Dai, J. Chen, J. Lin, S. Xiao, S. Chen, and Y. Deng, "Reduction of nitro phenols using nitroreductase from E. coli in the presence of NADH," J. Hazard. Mater., vol. 170, pp. 141-143, 2009.
M. Nasrollahzadeh, E. Mehdipour, and M. Maryami, "Efficient catalytic reduction of nitroarenes and organic dyes in water by synthesized Ag/diatomite nanocomposite using Alocasia macrorrhiza leaf extract", J. Mater. Sci. Mater. Electron., vol. 29, pp. 17054-17066, 2018.
V. Vidhu, and D. Philip, "Catalytic degradation of organic dyes usingbiosynthesized silver nano-particles", Micron, vol. 56, pp. 54-62, 2014.
B. Manu, and S. Chaudhari, "Anaerobic decolorisation of simulated textile wastewater containing azo dyes", Bioresour. Technol., vol. 82, pp. 225-231, 2002.
K. T. Chung, and C. E. Cerniglia, "Mutagenicity of azo dyes: structureactivity relationships", Mutat. Res., vol. 277, pp. 201-220, 1992.
M. Boxall, S. C. Monteiro, A. B. A. Boxall, "Factors affecting the degradation of pharmaceuticals in agricultural soils", Environmental Toxicology and Chemistry, vol. 28 (12), pp. 2546-2554, 2009.
D. Tiwari, J. Behari, and P. Sen, "Application of nanoparticles in waste water treatment". World Appl. Sci. J., vol. 3, pp. 417-433, 2008.
S. Das, J. Chakraborty, S. Chatterjee, and H. Kumar, "Prospects of biosynthesized nanomaterials for remediation of organic and inorganic environmental contaminants", Environmental Science: Nano., vol. 5, pp. 2784-2808, 2018.
S. Das, B. Sen, and N. Debnath, "Recent trends in nanomaterials applications in environmental monitoring and remediation", Environ. Sci. Pollut. Res., vol. 22, pp. 18333-18344, 2015.[11] B. Nowack, H. F. Krug, and M. Height, "120 years of nanosilver history: implications for policy makers", Environmental Science and Technology, vol. 45, no. 4, pp. 1177-1183, 2011.
T. Quang Huy, N. van Quy, and L. Anh-Tuan, "Silver nanoparticles: synthesis, properties, toxicology, applications and perspectives", Advances in Natural Sciences: Nanoscience and Nanotechnology, vol. 4, no. 3, p. 033001, 2013.
Y. A. Krutyakov, A. A. Kudrinskiy, A. Y. Olenin, and G. V. Lisichkin, "Synthesis and properties of silver nanoparticles: advances and prospects", Russian Chemical Reviews, vol. 77, no. 3, pp. 233-257, 2008.
Isiaka A. Adelere, and Agbaje Lateef, "A novel approach to the green synthesis of metallic nanoparticles: The use of agro-wastes, enzymes, and pigments", Nanotechnology Reviews, vol. 5, no. 6, pp. 567-587, 2016.
M. I. Skiba, A. A. Pivovarov, A. K. Makaro-va, and V, I. Vorobyova, "Plasma-chemical synthesis of silver nanoparticles in the presence of citrate", CJM.ASM.MD., vol. 13, no. 1, pp. 7-14, 2018.
M. Skiba, A. Pivovarov, V. Vorobyova, T. Derkach, and I. Kurmakova, "Plasma-chemical formation of silver nanoparticles: The silver ions concentration effect on the particle size and their antimicrobial properties", Journal of Chemical Technology and Metallurgy, vol. 54, no. 2, pp. 311-318, 2019.
Downloads
Published
How to Cite
Issue
Section
URN
License
Copyright (c) 2020 M. I. Skiba, О. А. Pivovarov, V. I. Vorobyova The authors who publish in this journal agree to the following terms:The authors reserve the right to authorship of their work and give the journal the right to first publish this work under the terms of the Creative Commons Attribution License CC BY-NC, which allows other persons to freely distribute published work with a mandatory reference to authors of the original work and the first publication of the work in this journal.
Authors have the right to conclude separate additional agreements for the non-exclusive distribution of the paper in the form in which it was published by this journal (for example, posting work in electronic repository or publishing as part of a monograph), provided that the link to the first publication in this journal is maintained.
The journal policy allows and encourages authors to post on the Internet (for example, in repositories of institutions or on personal websites) the manuscript of work, both before the submission of this manuscript to the editorial staff, and during its editorial work, as it contributes to the emergence of productive scientific discussion and positively affects the efficiency and dynamics of published work citation (see The Effect of Open Access).