COAL ACID PROCESSING OF WASTE GASES OF POWER PLANTS
DOI:
https://doi.org/10.24025/2306-4412.1.2020.185531Keywords:
combustion, electrocatalysis, ozone gas purification, photosynthesis, blue-green al-gae, biodiesel.Abstract
Gaseous and diesel fuels are produced on an industrial scale by converting solar energy with genetically modified cyano-bacteria (blue-green algae), which use CO2 for development, resulting in high yields when converting carbon dioxide into hydrocarbons. The disadvantage of using carbon dioxide as a source of CO2 is the content of various toxic compounds that inhibit photosynthesis and will pollute the environment when burning biodiesel. The solution of the problems of reducing carbon dioxide emissions into the atmosphere and creating optimal conditions for its processing is possible only with a comprehensive approach to solving a number of specific technological problems.
In this work a method of recycling of carbon dioxide exhaust gases of power plants is described. The purpose of the work is to reduce the activation energy of the combustion process in the presence of a catalyst. Theoretical foundations of the process of electrocatalysis, intensification of combustion of gaseous and solid fuels are elucidated. The main problem, impedimental to the use of smoke gases as raw material for the production of pure carbon dioxide, is the formation at incineration of fuel of such toxic compounds as carbon oxide (II), nitrogen oxides, and benzo(a)pyrene, formaldehyde, vapors of hydrochloric and hydrofluoric acids, toxic metals. Suppressions of formation CO, NOx and other harmful admixtures in smoke gases is possible to attain on the stage of burning with the use of new technology: electronic catalysis of flame in the discharge zone. The method of heterophasic ozo-nation minimizes content CO, NOx and other toxic admixtures in smoke gases. Photosynthesis – by converting pure CO2 into hydrocarbons with the use of solar energy – enables to receive on a com-mercial scale genetically modified cyano-bacteria (blue-green algae). Oils, got from them, a gaseous and diesel fuel during incineration result in the decrease of maintenance of toxic compounds in smoke gases. Thus, the creation of clean energy biocomplex is achieved.
References
Yu. Varnatz, W. Meuse and R. Dibble, Combustion. Physical and chemical aspects, modeling, experiments, formation of pollu-tants / G. L. Agafonov, trans. from Engl.; P. A. Vlasov. еd. Moscow: FIZMATLIT, 2003 [in Russian]
Yu. D. Martsinyshyn, H. S. Stolyarenko, and V. M. Vyazovik, "Method of intensification of gaseous fuel combustion", Patent of Ukraine no. 82036, 2007 [in Ukrainian].
Yu. D. Martsinyshyn, H. S. Stolyarenko, V. M. Vyazovik, "Method of intensification of solid fuel combustion", Patent of Ukraine no. 82036, 2008 [in Ukrainian].
H. S. Stolyarenko, "The method of feeding the internal combustion engine", A.C. 1240943 USSR, MKI F 02 M 25/10, no. 3710524/25-06; appl. 11.03.84; publ. 06.30.86, Bul. № 24, 1986 [in Ukrainian].
H. S. Stolyarenko, "Study of the effect of low doses of ozone on the operation of a carburetor internal combustion engine", Cherk. fil. KPI. Cherkasy, Rus dep. in ONIITEChIM Cherkasy, no. 451, 1991 [in Ukrainian].
H. S. Stolyarenko, "Mechanism of ozone chemodestruction reaction in heterophase oxidation processes", Visnyk Cherkaskogo inzhenerno-tekhnolohichnogo instytutu, no. 2, pp. 93-96, 1999 [in Ukrainian].
H. S. Stolyarenko, "Electrocatalytic ion-radical method of flue gas conditioning", Visnyk Cherkaskogo inzhenerno-tekhnolohichnogo instytutu, no. 4, pp. 116-119, 1999 [in Ukrainian].
G. S. Stoliarenko, "Intensification of the combustion process of gaseous fuels", Vis-nyk DU "Lvivska Politehnika", Himiya, teh-nologiya rechovyn ta yih zastosuvannya, no. 374, pp. 26-30, 1999 [in Russian].
G. S. Stoliarenko, "Ozone-radical and elec-trocatalytic methods of fuel combustion in-tensification", in Proc. 30th All-Rus. Semi-nar Ozone and other environmentally friend-ly oxidizers. Science and Technology, Moscow: MGU, 2008, pp. 86-96 [in Russian].
G. S. Stoliarenko, V. M. Vyazovik, and A. V. Gromyko, "Ozone-radical method of intensification of the combustion process of gaseous fuels", in Proc. First All-Rus. Conf. Ozone and other environmentally friendly oxidizers. Science and Technology, Mos-cow: Knizhnyy dom MGU, 2005, 165 p. [in Russian].
G. S. Stoliarenko, "Mechanism of ozone intensification reactions of liquid fuel combustion process", Voprosyi himii i himicheskoy tehnologii, no. 1, pp. 223-225, 2000 [in Russian].
H. S. Stolyarenko, E. V. Myslyuk, V. A. Kryvoorot, O. M. Demchenko, and O. M. Shchurov, "Method for biofuels production for diesel engines", Patent of Ukraine no. 19494, 2006 [in Ukrainian].
H. S. Stolyarenko, and E. B. Myslyuk, "Diesel biofuel plant", Patent of Ukraine no. 19495, 2006 [in Ukrainian].
G. S. Stoliarenko et al., "High-temperature electrocatalytic processes for the intensification of combustion of solid and gaseous fu-els", in Proc. Int. Sci.-Pract. Conf. Energy Efficiency–2007, Kiev: In-t gaza NANU, 2007, pp. 78-79 [in Russian].
H. S. Stolyarenko et al., "Method of intensi-fication of solid fuel combustion", Patent of Ukraine no. 78474, 2007 [in Ukrainian].
H. S. Stolyarenko, E. B. Myslyuk, S. L. Yushchenko, and N. M. Fomina, "Me-thod for obtaining alcohol ethers (biodiesel)", Patent of Ukraine no. 266814, 2007 [in Ukrainian].
A. N. Shumsky, V. M. Eskov-Soskovets, and G. S. Stoliarenko (Ukraine), "A method of manufacturing a micro relief on a dielec-tric surface", Patent of Russia no. 1819250, 1993 [in Russian].
A. N. Shumsky, V. M. Eskov-Soskovets, and G. S. Stoliarenko (Ukraine), "Dielectric with microrelief on its surface mainly for ozonizers", Patent of Russia no. 2016840, 1994 [in Russian].
A. N. Shumsky, V. M. Eskov-Soskovets, and G. S. Stoliarenko (Ukraine), "Device for electron-beam processing of objects", Patent of Russia no. 2023746, 1994 [in Russian].
H. Stolyarenko, U. Martsinyshyn, V. Viazovik, O. Vodianik, and S. Honchar, "The al-ternative burning of hydrocarbon", in Contributed Papes Int. Workshop Nonequili-brium Processes in Combustion and Plasma Based Technologies, 2008, pp. 84-88.
H. S. Stolyarenko, I. M. Astrelin, N. M. Fomina, and V. I. Demyanenko, "Heteropha-sious ozone method of smoke gases denitrfi-cation", EKO-INFORMA 2001, USA: Illi-nois, 2001, pp. 14-18.
Downloads
Published
How to Cite
Issue
Section
URN
License
Copyright (c) 2020 Геннадій Степанович Столяренко The authors who publish in this journal agree to the following terms:The authors reserve the right to authorship of their work and give the journal the right to first publish this work under the terms of the Creative Commons Attribution License CC BY-NC, which allows other persons to freely distribute published work with a mandatory reference to authors of the original work and the first publication of the work in this journal.
Authors have the right to conclude separate additional agreements for the non-exclusive distribution of the paper in the form in which it was published by this journal (for example, posting work in electronic repository or publishing as part of a monograph), provided that the link to the first publication in this journal is maintained.
The journal policy allows and encourages authors to post on the Internet (for example, in repositories of institutions or on personal websites) the manuscript of work, both before the submission of this manuscript to the editorial staff, and during its editorial work, as it contributes to the emergence of productive scientific discussion and positively affects the efficiency and dynamics of published work citation (see The Effect of Open Access).
