TECHNIQUE FOR DETERMINATION OF CRITICAL VALUES OF PARAMETERS OF EXTERNAL THERMAL ACTIONS ON PYROTECHNICAL METAL OXIDE PRODUCTS IN OPERATING CONDITIONS

Authors

DOI:

https://doi.org/10.24025/2306-4412.2.2022.257014

Keywords:

fire safety, pyrotechnic mixtures, ignition and combustion processes, powders of metal fuels and metal oxides

Abstract

Ignition and subsequent fire and explosion destruction of products are preceded by external thermal actions to which they are exposed. This leads to premature ignition and explosive development of combustion of mixtures that are part of the products, and their subsequent flammable destruction. Therefore, techniques of prevention of forced premature fire-hazardous destruction of products in case of external thermal actions are of practical importance. They should be based on scientifically sound methods for determining critical values of thermal effects on products and technological parameters of mixtures, exceeding which leads to premature fire-hazardous destruction of products. The aim of the work is to develop a technique for determining the critical values of external thermal influences and controlled technological parameters of mixtures, which lead to premature ignition and explosive combustion of pyrotechnic mixtures of magnesium, aluminum and metal oxides, and ultimately to flammable destruction of products. A specialized software package of four standard packages of applications is formed. It consists of 80 individual software modules on modern numerical methods (nonlinear thermal conductivity and diffusion, thermo-gas dynamics, chemical kinetics, mathematical processing of experimental data, etc.), which are focused on the personal computer that allows to solve in the mode of dialogue and real time typical engineering and technological problems of fire safety of various pyrotechnic mixtures. A new scientifically sound technique based on the obtained mathematical, experimental and statistical models and specialized software in the form of four standard application packages has been developed. It allows in dialogue and real-time modes on the PC to form the necessary for practical use database of critical ranges of changes in the parameters of external thermal actions and controlled technological parameters of charges of mixtures, exceeding which leads to flammable destruction of products. It is shown that practical use of the developed technique in the form of means of control and technological recommendations allows to increase fire safety of pyrotechnic products (lighting, signal, tracer cartridges and shells, incendiary means, etc.) in the conditions of external thermal actions in 2… 3 times.

Author Biography

Ye.P. Kyrychenko, Cherkasy Institute of Fire Safety name after Chornobyl Heroes of National University of Civil Defense of Ukraine

Adjunct

References

V. V. Kovalyshyn, V. M. Marych, Y. M. No-vitskyi, В. M. Gusar, V. V. Chemetskiy, and O. L. Mirus, "Improvement of a discharge nozzle damping attachment to suppress fires of class D", Eastern-European Journal of Enterprise Technologies, no. 5 (95), pp. 68-76, 2018.

V. M. Fateev, Y. P. Prikhodko, and L. I. Ta- borov, Pyrotechnics. Kyiv, Ukraine: Naukova dumka, 2017 [in Ukrainian].

DSTU 8828:2019. Fire Security. Terms. Effective from 2020, Jan. 01. Kyiv: UkrNDNC, 2019 [in Ukrainian].

DSTU 8829:2019. Fire and explosion hazard of substances and materials. Nomenclature of indicators and methods of their definition. Classification. Effective from 2020, Jan. 01. Kyiv: UkrNDNC, 2019 [in Ukrainian].

V. M. Balanyuk, N. M. Kozyar, and O. I. Garasimyuk, "Application of aerosol-powder fire-extinguishing mixtures for pro-tection against incendiary mixtures", Science Rise, no. 2 (22), pp. 11-14, 2016 [in Ukrainian].

V. M. Marich, V. V. Kovalishin, and Ya. B. Kirillov, "Optimization of fire extin-guishing powders for magnesium extin-guishing", in Proc. Int. Sci.-Pract. Conf.

Theory and practice of firefighting and emergency response. Cherkasy, 2018 [in Ukrainian].

V. V. Kovalishyn, V. M. Marich, T. M. Voi-tovych, and B. M. Husar, "Use of environ-mentally friendly fire extinguishers", in Proc. Int. Sci.-Pract. Conf. Environmental security as a basis for sustainable development of society. European experience and prospects. DUBZD, 2018 [in Ukrainian].

V. M. Marich, V. V. Kovalishyn, and Ya. B. Kirillov, "Investigation of chemicals as components of fire-extinguishing pow-ders for extinguishing magnesium and its al-loys", in Proc. Int. Sci.-Pract. Conf. Theory and practice of firefighting and emergency response. Cherkasy, 2017 [in Ukrainian].

Study of trends and patterns of dynamics of the main indicators of fire statistics in Ukraine on a territorial basis: Report on re-search work. Kyiv: UkrNDICZ, 2018 [in Ukrainian].

O. Dibrova, О. Kyrychenko, R. Motrychuk, M. Tomenko, and V. Melnyk, "Fire safety improvement of pyrotechnic nitrate-metal mixtures under external thermal conditions", Technology audit and production reserves, no. 1/1 (51), pp. 44-49, 2020.

O. V. Kirichenko, O. S. Dibrova, R. B. Mot-richuk, V. A. Vashchenko, S. O. Kolinko, T. I. Butenko, and V. V. Tsybulin, "Deter-mination of critical modes of development of combustion processes of pyrotechnic ni-trate-metal mixtures in the conditions of ex-ternal thermal actions", Vísnyk Cherkaskogo derzhavnogo tekhnologíchnogo uníversitetu, no. 2, pp. 123-133, 2020 [in Ukrainian].

O. V. Kyrychenko, O. S. Dibrova, R. B. Mot-richuk, V. A. Vashchenko, and S. O. Kolinko, "Investigation of ignition and combustion of particles of aluminum and magnesium alloys in the decomposition products of solid pyro-technic fuels", Scientific Bulletin Civil Pro-tection and Fire Safety, no. 2 (8), pp. 81-85, 2019.

O. V. Kirichenko, O. S. Dibrova, R. B. Mot-richuk, E. O. Tishchenko, and V. V. Tsy-bulin, "Determination of permissible modes of heating of pyrotechnic mixtures during their operation", Vísnik Cherkaskogo derzhavnogo tekhnologíchnogo uníversitetu, no. 2, pp. 5-11, 2018 [in Ukrainian].

O. S. Dibrova, O. V. Kirichenko, R. B. Mot-richuk, and V. A. Vashchenko, "Improving fire safety of pyrotechnic nitrate-metal mix-tures in the conditions of external thermal actions", Intenauka, no. 5/5799, 2020. [Online]. Available: http://www.inter-nauka.com [in Ukrainian].

O. S Dibrova, O. V. Kirichenko, R. B. Mot-richuk, and V. A. Vashchenko, "Regularities of influence of technological parameters on fire safety of pyrotechnic nitrate-titanium mixtures in the conditions of external ther-mal actions", Intenauka, no. 5/5798, 2020. [Online]. Available: http://www.inter-nauka.com [in Ukrainian].

O. V. Kirichenko, O. S. Dibrova, and R. B. Motrichuk, "Influence of technological parameters on the dependences of the rate of development of the combustion process of pyrotechnic mixtures", in Proc. XI Int. Sci.-Pract. Conf. Theory and practice of firefighting and emergency response. Cherkasy: Cherkas. in-t pozhezhnoyi bezpeky im. Heroyiv Chornobylya, 2020 [in Ukrainian].

R. B.Motrichuk, O. V. Kirichenko, V. A. Va-shchenko, S. O. Kolinko, T. I. Butenko, E. P. Kirichenko, and V. V. Tsybulin, "Regularities of influence of technological parameters and external factors on tempera-ture and composition of combustion products of pyrotechnic nitrate-metal mix-tures", Vísnyk Cherkaskogo derzhavnogo tekhnologíchnogo uníversitetu, no. 4, pp. 131-142, 2020 [in Ukrainian].

E. P. Kirichenko, V. M. Gvozd, V. A. Vash-chenko, O. V. Kirichenko, O. O. Dyadyu-shenko, and V. P. Melnik, "Regularities of the influence of technological parameters and external factors on the ignition tempera-ture and combustion time of magnesium and aluminum particles in the decomposition products of metal oxides", Tsyvilnyy zakhyst ta pozhezhna bezpeka, no. 2 (12), pp. 112-122, 2021 [in Ukrainian].

E. P. Kirichenko, "Research of processes of external thermal shock actions on pyrotech-nic metal oxide products in the conditions of a shot and flight", Pozhezhna bezpeka: teoriya i praktyka: coll. of sci. papers of Cherkasy Institute of Fire Safety named af-ter Chornobyl Heroes, vol. 5, no. 2, pp. 87-102, 2021 [in Ukrainian].

E. P. Kirichenko, V. V. Kovalishin, V. M. Gvozd, V. A. Vashchenko, S. O. Ko-linko, and V. V. Tsybulin, "Research of the mechanism and development of the model of development of burning process of pyro-technic mixes metal fuel + metal oxide at external thermal actions", Vísnyk Cherkas-kogo derzhavnogo tekhnologíchnogo uníversitetu, no. 4, pp. 68-82, 2021 [in Ukrainian].

Published

2022-06-27

How to Cite

Kyrychenko, Y. (2022). TECHNIQUE FOR DETERMINATION OF CRITICAL VALUES OF PARAMETERS OF EXTERNAL THERMAL ACTIONS ON PYROTECHNICAL METAL OXIDE PRODUCTS IN OPERATING CONDITIONS. Bulletin of Cherkasy State Technological University, (2), 53–63. https://doi.org/10.24025/2306-4412.2.2022.257014

Issue

Section

Chemical Technologies and Engineering, Environmental Safety

URN