Possibilities of enhancement of the strength and durability of epoxy composites by silicon carbide and titanium nitride filling

Authors

  • Dmitriy Starokadomsky Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine Henerala Naumova str., 17, Kyiv, Ukraine, 03164, Ukraine https://orcid.org/0000-0001-7361-663X
  • Sergij Golovan Institute of Macromolecular Chemistry of the National Academy of Sciences of Ukraine Kharkivske highway, 48, Kyiv, Ukraine, 02160, Ukraine
  • Nadia Sigareva Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine Henerala Naumova str., 17, Kyiv, Ukraine, 03164, Ukraine
  • Оlexander Тkachenko Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine Henerala Naumova str., 17, Kyiv, Ukraine, 03164, Ukraine
  • Nadia Moshkovska Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine Henerala Naumova str., 17, Kyiv, Ukraine, 03164, Ukraine
  • Lyudmyla Kоkhtych Institute of Physics of National Academy of Sciences of Ukraine Nauky ave., 46, Kyiv, Ukraine, 03028 National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute” Peremohy ave., 37, Kyiv, Ukraine, 03056, Ukraine https://orcid.org/0000-0002-6973-9984
  • Іvan Garashchenko Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine Henerala Naumova str., 17, Kyiv, Ukraine, 03164, Ukraine

DOI:

https://doi.org/10.15587/2313-8416.2019.164289

Keywords:

epoxy composite, strength, microhardness, heat resistance, diagrams, swelling in acetone, nitric acid, shrinkage

Abstract

Composites based on ED20+PEPA resin with filling of SiC, TiN microparticles and their mixtures with cement are studied. The possibilities for a significant increase in microhardness – 1.5-2 times, modulus at bending (1.4 - 1.7 times), compressive strength (for SiC), abrasion resistance and chemical resistance (in nitric acid and acetone/ethyl acetate) are revealed. At the same time, the fire resistance of the compositions and their strength properties significantly increases

Author Biographies

Dmitriy Starokadomsky, Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine Henerala Naumova str., 17, Kyiv, Ukraine, 03164

PhD, Senior Researcher

Department of Composite Materials

Sergij Golovan, Institute of Macromolecular Chemistry of the National Academy of Sciences of Ukraine Kharkivske highway, 48, Kyiv, Ukraine, 02160

Researcher

Nadia Sigareva, Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine Henerala Naumova str., 17, Kyiv, Ukraine, 03164

Postgraduate Student

Department of Composite Materials

Оlexander Тkachenko, Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine Henerala Naumova str., 17, Kyiv, Ukraine, 03164

Leading Engineer

Department of Composite Materials

Nadia Moshkovska, Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine Henerala Naumova str., 17, Kyiv, Ukraine, 03164

Engineer

Department of Composite Materials

Lyudmyla Kоkhtych, Institute of Physics of National Academy of Sciences of Ukraine Nauky ave., 46, Kyiv, Ukraine, 03028 National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute” Peremohy ave., 37, Kyiv, Ukraine, 03056

Researcher

Department of Coherent and Quantum Optics

Assistant

Department of Energy Systems

Іvan Garashchenko, Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine Henerala Naumova str., 17, Kyiv, Ukraine, 03164

Leading Engineer

Department of Composite Materials

References

Starokadomskiy, D. (2018). Dlinnyy vek epoksidki. Nauka i Zhizn, 1, 66–71.

Lypatov, Yu. S. (1991). Physico-chemistry of a filled polymers. Kyiv: Naukova Dumka, 220.

Starokadomsky, D. L. (2008). Some features of the swelling of photopolymer composites with various indicators of high-silica silica. Plastic Masses, 2, 33–36.

Emelina, O. Yu. (2014). Composite polymeric materials, modified by dispersion fillers, applicable in the construction and repair of equipment. Bulletin of Kazan Technological University, 17 (3), 128–130.

Voronkov, A. G., Yartsev, V. P. (2006). Epoxy polymer solutions for the repair and protection of building products and structures. Tambov: Publishing House of Tambov State Techn. University, 92.

Poornima, V., Thomas, S., Huczko, A. (2010). EpoxyresinSiC nanocomposites. Synthesis & characterization. Kompozyty, 10, 11–14.

Vijayan, P. P., Pionteck, J., Huczko, A., Puglia, D., Kenny, J. M., Thomas, S. (2014). Liquid rubber and silicon carbide nanofiber modified epoxy nanocomposites: Volume shrinkage, cure kinetics and properties. Composites Science and Technology, 102, 65–73. doi: http://doi.org/10.1016/j.compscitech.2014.07.017

Ishchenko, A., Radionenko, A., Ischenko, E. (2017). Tribotechnical research into friction surfaces based on polymeric composite materials. Eastern-European Journal of Enterprise Technologies, 6 (12 (90)), 12–19. doi: http://doi.org/10.15587/1729-4061.2017.114367

Reshetnyk, M., Starokadomsky, D., Ishenko, A. (2017). Filling with the Graphene Nanoplates as a Way to Improve Properties of Epoxy-Composites for Industrial and Geophysical Machinery. American Journal of Physics and Applications, 5 (6), 120–125. doi: http://doi.org/10.11648/j.ajpa.20170506.19

Kablov, V. F., Lifanov, V. S., Logvinova, M. Ya., Kochetkov, V. G. (2013). Fire and heat resistant epoxy composites filled with silicon carbide. Modern problems of science and education, 6, 10–17.

Starokadomsky, D. (2018). Physico-mechanical properties and micro-nanostructure of epoxy composites filled with gypsum, chalk and cement. Composites and Nanostructures, 10 (1 (37)), 45–57.

Zolotareva, V. V., Grigorenko, T. I., Kochergin, Yu. S., Samoylova, E. E. (2013). The effect of fine fillers (BN, SiO2, Cr2O3, Omiacarb, iron powder) on the wear of epoxy and epoxy-rubber polymers. Modern building materials, 1 (99), 108–114.

Downloads

Published

2019-04-16

Issue

No. 4 (2019)

Section

Chemistry

License

Copyright (c) 2019 Dmitriy Starokadomsky, Sergij Golovan, Nadia Sigareva, Оlexander Тkachenko, Nadia Moshkovska, Lyudmyla Kоkhtych, Іvan Garashchenko

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Our journal abides by the Creative Commons CC BY copyright rights and permissions for open access journals.

Authors, who are published in this journal, agree to the following conditions:

1. The authors reserve the right to authorship of the work and pass the first publication right of this work to the journal under the terms of a Creative Commons CC BY, which allows others to freely distribute the published research with the obligatory reference to the authors of the original work and the first publication of the work in this journal.

 2. The authors have the right to conclude separate supplement agreements that relate to non-exclusive work distribution in the form in which it has been published by the journal (for example, to upload the work to the online storage of the journal or publish it as part of a monograph), provided that the reference to the first publication of the work in this journal is included.