Baddeleyite ilmenite deposits from Ukraine and EPR data

Authors

  • Леонид Сергеевич Дерский M.P. Semenenko institute of geochemistry, mineralogy and ore formation Prospect Palladina, № 34 Kiev, Ukraine, 03680, Ukraine

DOI:

https://doi.org/10.15587/2313-8416.2014.26378

Keywords:

Baddeleite, mineral, EPR spectrum, titanium, uranium impurity, hafnium, yttrium, a paramagnetic center, the structure of the mineral

Abstract

Metal oxide mineral baddeleyite has been studied. The purpose of this study was investigation of isomorphic impurities in baddeleyite structure. Electron spin resonance metod (ESR) was used in this work. ESR signal from Ti3+ ions was detected. Spectroscopic characteristics of this signal are g1=1,997, g2=1,9729 and g3=1,9681. ESR spectrum of baddeleyite has the same characteristics for temperatures T=77K and T=300K.

Author Biography

Леонид Сергеевич Дерский, M.P. Semenenko institute of geochemistry, mineralogy and ore formation Prospect Palladina, № 34 Kiev, Ukraine, 03680

Ml. Researcher at the Department of Physics and mineral structures Biomineralogy

References

Lazarenko, E. K.(1951) Course mineralogy. Kiev, State of technical literature of Ukraine, 688.

Votyakov, S. L., Krasnobaev, A. A., Krokhalev, V. Y. (1993). Problems of Applied Spectroscopy minerals. Ekaterinburg, USSR: RUIF Science, 236.

Carlos, R. Vera, Carlos, L. Pieck, Kiyoyuki Shimizu, Carlos, A. Querini, Parera (1999). Catalysts during Isomerization of n-Butane and Its Relation to the Reaction Mechanism. Journal of Catalysis, 187, 39–49.

Huiwen, Liu, Feng, Lianbo, Zhang ,Xushou, Xue, Qunji (1995). ESR Characterization of ZrO2 Nanopowder. J.Phys. Chem., 99, 332–334.

Occhiuzzi, Manlio, Cordischi Dante, Dragone Roberto (2002). Intrinsic and Extrinsic Paramagnetic Centers in Zirconia. J.Phys. Chem., 106 (B), 12464–12469.

Qin, Zhao, Xinping, Wang, Tianxi, Cai (2004). The study of surface properties of ZrO2. Applied Surface Science., 225, 7–13.

Iacconi, P., Lapraz, D., Caruba, R. (1978). Traps and emission centers in thermo luminescent ZrO2. Phys. Stat. Sol., 50 (a), 275–283.

Tsymbal, S. N, Polkanoff ,Yu. A. (1975). Mineralogy of titanium-zirconium placers of Ukraine. Kiev, USSR:

Naukova Dumka, 248.

Kvasnitsa, V. N., Krochuk ,V. M., Zumbal, S. N. et al (1979). Crystal morphology baddeleyite from carbonatites and placers of Ukraine. Min. Journal 1 (1), 69–77.

Dersky, L. S. (2008). ELECTRONIC PARAMAGNETIC RESONANCE Ti3 + in baddeleyite. Proceedings of the International Mineralogical seminar. Syktyvkar, Komi Republic, Russia, .274–275.

Dersky, L. S., Brik, A. B., Bondarenko, I. N., et al (2008). Baddeleyite EPR data, electron microscopy and microprobe analysis. Proceedings of the International Conference. Voronezh, Russia, 77–78.

Carrington, A., Mc Lechlan, E. (1970). Magnetic resonance and its applications in chemistry. Moscow, USSR: World, 447.

Konstantinova, E. A., Gayvoronskiy, V. Y., Timoshenko, V. U. et al (2010). Study spin centers in the nanocrystalline titanium dioxide with a high degree of photocatalytic activity. Semiconductor Physics and Technology, 44 (8), 1093–1096.

Gaft, M. A., Gorobetc, B. S. Barsukov, N. S. (1980). Luminescence of titanium complexes in the baddeleyite. Union notes. Mineralogical Society, 109 (4), 493–497.

Published

2014-08-13

Issue

Section

Geological Sciences