Analysis of the behavior of low-molecular cationic and high-molecular anionic surfactants on the interface of phases «binary aqueous solution – air»
DOI:
https://doi.org/10.15587/2313-8416.2017.97643Keywords:
surface properties, binary solutions, hexadecylpyridinium bromide, carboxymethylcellulose sodium saltAbstract
Specific features of the behavior of hexadecylpyridinium bromide and sodium carboxymethyl cellulose at the interface between solution-air phases at different weight ratios of components in solutions, pH of the medium at a constant concentration of cationic surfactant are studied. The composition of adsorption layers and the parameter of intermolecular interaction of surfactants in them are calculated. Optimal conditions for surface concentration of cationic surfactants are proposed
References
Holmberg, K., Jonsson, B., Kronberg, B., Lindman, B. (2007). Surfactants and Polymer in Aqueous Solution. Moscow: BEAN. Laboratory knowledge, 528.
Kochkodan, O. D., Karmazin, T. V. (2014). The thermodynamic characteristics of micelle formation as a measure of interaction between the molecules of water and surfactant. SWorld, 30 (4), 91–96.
Voliuvach, O. V., Streltsova, O. О. (2011). Adsorption of dodecylpyridinium chloride from solutions containing Tweens (Tween-40, Tween-60). Ukrainian Chemical Journal, 77 (3), 21–25.
Voliuvach, O. V. (2013). Quantitative and thermodynamic assessment of the interaction of iodide hexadecylpyridinium and Tween-20 in mixed aqueous solutions and adsorption layers. Herald of the National University "Lviv Polytechnic". Series: Chemistry, materials technology and their applications, 761, 64–70.
Streltsova, E. A., Voliuvach, O. V. (2009). Analysis of adsorption hexadecylpyridinium bromide and sodium alkylsulfate on the binary surfactant solution – air phase interface. Bulletin of the Odessa National University. Series: Chemistry, 14 (12), 114–120.
Voliuvach, O. V., Menchuk, V. V., Dragunovskaya, O. I. (2012). Pat. No. 70434 UA. Detergent based on a synergistic combination of cationic and non-ionic surfactants. MPK C11D 1/72. No. u201114074; declareted: 29.11.2011; published: 11.06.2012, Bul. No. 11.
Voliuvach, O. V. (2006). Colloidal-Сhemical Regularities of Isolation of Hexadecylpyridinium Salts from Aqueous Solutions. Kyiv, 135.
Voliuvach, O. V. (2011). Intensification of process flotational isolation sodium dodecylsulfate from aqueous solutions at the presence of Tweens. Questions of chemistry and chemical technology, 6, 194–199.
Langevin, D. (2009). Complexation of oppositely charged polyelectrolytes and surfactants in aqueous solutions. Advances in Colloid and Interface Science, 147-148, 170–177. doi: 10.1016/j.cis.2008.08.013
Llamas, S., Guzman, E., Ortega, F., Baghdadli, N., Cazeneuve, C., Rubio, R. G., Luengo, G. S. (2015). Adsorption of polyelectrolytes and polyelectrolytes-surfactant mixtures at surfaces: a physico-chemical approach to a cosmetic challenge. Advances in Colloid and Interface Science, 222, 461–487. doi: 10.1016/j.cis.2014.05.007
Zhilyakova, E. T., Popov, N. N., Novikov, M. Yu., Novikov, O. О., Khalikov, M. A., Kazakov, V. S. (2011). Study of physico-chemical and technological characteristics of the sodium carboxymethylcellulose to create long-acting dosage form with a liquid dispersion medium. Scientific statements Belgorod State University. Series: Medicine. Pharmacy, 13-2 (4 (99)), 146–153.
Ivankin, A. N., Panferov, V. I., Fahretdinov, H. A., Vostrikova, N. I., Golovanova, P. M. (2015). Nanomicrocomposite wound coverings on the basis of collagen and carboxymethylcellulose. Forest Gazette. Rational use of forest resources and wood products, 19 (1), 41–45.
Dhar, N., Au, D., Berry, R. C., Tam, K. C. (2012). Interactions of nanocrystalline cellulose with an oppositely charged surfactant in aqueous medium. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 415, 310–319. doi: 10.1016/j.colsurfa.2012.09.010
Mata, J., Patel, J., Jain, N., Ghosh, G., Bahadur, P. (2006). Interaction of cationic surfactants with carboxymethylcellulose in aqueous media. Journal of Colloid and Interface Science, 297 (2), 797–804. doi: 10.1016/j.jcis.2005.11.022
Liu, J., Zheng, L., Sun, D., Wei, X. (2010). Salt effect on the complex formation between 1-dodecyl-3-methylimidazolium bromide and sodium carboxymethylcellulose in aqueous solution. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 358 (1-3), 93–100. doi: 10.1016/j.colsurfa.2010.01.034
Wu, Q., Du, M., Shangguan, Y., Zhou, J., Zheng, Q. (2009). Investigation on the interaction between C16TAB and NaCMC in semidilute aqueous solution based on rheological measurement. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 332 (1), 13–18. doi: 10.1016/j.colsurfa.2008.08.022
Antonov, N. M. (2015). Development of composite materials based on a polymer Na-CMC with metal powder fillers for the formation of functional coatings and porous films. Novocherkassk, 329.
Koksharov, A. V. (2013). Improvement of fire-extiоnguishing capability low expansion foam. Bulletin of Voronezh Institute of Russian Ministry for Emergency Situations, 4 (9), 48–49.
Zhang, H., Deng, L., Sun, P., Que, F., Weiss, J. (2016). Solubilization of octane in cationic surfactant–anionic polymer complexes: Effect of ionic strength. Journal of Colloid and Interface Science, 461, 88–95. doi: 10.1016/j.jcis.2015.09.028
Tiitu, M., Laine, J., Serimaa, R., Ikkala, O. (2006). Ionically self-assembled carboxymethyl cellulose/surfactant complexes for antistatic paper coatings. Journal of Colloid and Interface Science, 301 (1), 92–97. doi: 10.1016/j.jcis.2006.04.072
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