Thermodynamics estimation of copper plasma efficiency from secondary raw material

Authors

  • Віктор Сергійович Козьмін Zaporozhe state engineering academy other of Lenin, 226, m. Zaporozhe, Ukraine, 69006, Ukraine
  • Іван Федорович Червоний Doctor of Technical Sciences, Professor, Head of Department Department of nonferrous metals, Ukraine
  • Віктор Миколайович Бредхін Donetsk national technical university Ukraine, 83001, Donetsk, Artem, 58, Ukraine
  • Ольга Василівна Циганкова Zaporozhe state engineering academy other Lenin 226, m. Zaporozhe, Ukraine, 69006, Ukraine
  • Вадим Миколайович Міхайлін Zaporozhe state engineering academy Lenin 226, m. Zaporozhia, Ukraine, 69006, Ukraine

DOI:

https://doi.org/10.15587/2313-8416.2014.27268

Keywords:

copper, recycled materials, plasma, refining, impurity, Gibbs potential, thermodynamic assessment

Abstract

The results of the thermodynamic evaluation of oxidative plasma copper refining efficiency recycled from impurities present in the feedstock are shown. It was established that the type of impurity factor increasing the efficiency of the plasma refining the potential change of Gibbs varies from 1,4 to 4, 8, and for silver, and of gold there is a transition from an unlikely to real positive state. 

Author Biographies

Віктор Сергійович Козьмін, Zaporozhe state engineering academy other of Lenin, 226, m. Zaporozhe, Ukraine, 69006

Magistrate

Department of metallurgy of the colored metals

Іван Федорович Червоний, Doctor of Technical Sciences, Professor, Head of Department Department of nonferrous metals

Zaporozhye State Engineering Academy, Lenina, 226, Zaporozhye, Ukraine, 69006

Віктор Миколайович Бредхін, Donetsk national technical university Ukraine, 83001, Donetsk, Artem, 58

Candidate of engineering sciences, professor

Department of the colored metals and construction materials

Ольга Василівна Циганкова, Zaporozhe state engineering academy other Lenin 226, m. Zaporozhe, Ukraine, 69006

Graduate student

Department of metallurgy of the colored metals

Вадим Миколайович Міхайлін, Zaporozhe state engineering academy Lenin 226, m. Zaporozhia, Ukraine, 69006

Doctor of engineering sciences, professor

Department of physical and biomedical electronics

References

Review and Outlook for Copper, Lead and Zinc 2013 (2013). J-SUMIT Tokyo, Japan, 14.

World copper statistics 2013. April 01, 2014 Comment (2014). Available at: http://im-mining.com/2014/04/01/world-copper-statistics-2013/.

World refined copper production and usage trends 2008-2014 (2014). Available at: http://www.icsg.org/index.php/component/jdownloads/finish/ 165/871.

Savenkov, Yu. D., Dubodelov, V. I., Shpakovskiy, V. A., Kozhanov, V. A., Shtepan, E. V. (2008). Rafinirovannaya med’ Ukraini, 176.

Bredikhin, V. N., Maniak, N. A., Kaftanenko, A. Ya. (2006). Med’ vtorichnaya, 416.

Kruger, J., Markus, A. R., Kogler, C., Probst, T. (2014). Metallurgical Furnaces. Electrothermal Reactors. Plasma Furnaces, 37-38. Available at: http://web.vscht.cz/~vun/Metallurgical%20Furnaces.pdf.

Modeling of the Reduction Stage During the Continuous Refining of Copper in a Packed Bed Reactor (2012). Available at: http://www.comsol.com/offers/conference2012papers/papers/file/id/13065/file/15099_mansilla_paper.pdf.

Metal smelting and refining sources of CDDs/CDFs. Secondary Copper Smelters. Available at: http://www.epa.gov/ncea/pdfs/dioxin/2k-update/pdfs/Dioxin_Chapter_7.pdf.

Bhat, G. K. (1984). Potential1 problems and innovations of plasma heat applications in the metallurgical industry. Pure & Appi. Chern., 56(2), 209-214. Available at: http://pac.iupac.org/publications/pac/pdf/1984/pdf/5602x0209.pdf.

Naidek, V. L., Narivskiy, A. V. (2008). Povishenie kachestva otlivok iz aluminievikh i mednikh splavov plazmoreagentnoi obrabotkoi ikh rasplavov, 182.

Shapovalov, V. O., Sheiko, I. V., Remizov, G. O. (2012). Plazmovi processi ta ustatkuvannya v metalurgii, 384.

Dembovskiy, V. (1981). Plazmennaya mettalurgia, 280.

FactSage – free access to thermochemical software and compound databases. Available at: http://www.factsage.com/.

Published

2014-09-16

Issue

Section

Technical Sciences