Novel approaches to the creation of alternative motor fuels from renewable raw materials

Authors

  • Ольга Олександрівна Гайдай Institute of Bioorganic Chemistry and Petrochemistry National Academy of Sciences of Ukraine Kharkiv highway, 50, Kiev, Ukraine, 02660, Ukraine https://orcid.org/0000-0003-2710-2560
  • Наталія Юріївна Хімач Institute of Bioorganic Chemistry and Petrochemistry National Academy of Sciences of Ukraine Kharkiv highway, 50, Kiev, Ukraine, 02660, Ukraine https://orcid.org/0000-0002-3383-1439
  • Володимир Степанович Пилявський Institute of Bioorganic Chemistry and Petrochemistry National Academy of Sciences of Ukraine Kharkiv highway, 50, Kiev, Ukraine, 02660, Ukraine
  • Євген Васильович Полункін Institute of Bioorganic Chemistry and Petrochemistry National Academy of Sciences of Ukraine Kharkiv highway, 50, Kiev, Ukraine, 02660, Ukraine

DOI:

https://doi.org/10.15587/2313-8416.2016.71955

Keywords:

syngas, methanol, heterogeneous catalysis, ethanol fuel, onions, chemmotological fuel characteristics

Abstract

The paper considers the method of obtaining aliphatic alcohols as components of alternative fuels by catalytic processing of synthesis gas under the conditions of mechanochemical activation of the catalyst without using high pressure.

It is established that the introduction of hydrocarbon spherical clusters (onions) in the alternative fuel changes physical, chemical and chemmotological characteristics of fuel due to the effect of structure formation. The results of comparative studies of the performance properties of hydrocarbon and alternative fuels are displayed

Author Biographies

Ольга Олександрівна Гайдай, Institute of Bioorganic Chemistry and Petrochemistry National Academy of Sciences of Ukraine Kharkiv highway, 50, Kiev, Ukraine, 02660

Junior Researcher

Department of Homogeneous catalysis and additives to petroleum products

Наталія Юріївна Хімач, Institute of Bioorganic Chemistry and Petrochemistry National Academy of Sciences of Ukraine Kharkiv highway, 50, Kiev, Ukraine, 02660

Junior Researcher

Department of Homogeneous catalysis and additives to petroleum products

Володимир Степанович Пилявський, Institute of Bioorganic Chemistry and Petrochemistry National Academy of Sciences of Ukraine Kharkiv highway, 50, Kiev, Ukraine, 02660

Candidate of technical science, Leading Researcher

Department of Homogeneous catalysis and additives to petroleum products

Євген Васильович Полункін, Institute of Bioorganic Chemistry and Petrochemistry National Academy of Sciences of Ukraine Kharkiv highway, 50, Kiev, Ukraine, 02660

Candidate of chemical science, Head of department

Department of Homogeneous catalysis and additives to petroleum products

References

Platt, S. M., Haddad, I. E., Pieber, S. M., Huang, R.-J., Zardini, A. A., Clairotte, M. et. al (2014). Two-stroke scooters are a dominant source of air pollution in many cities. Nature Communications, 5. doi: 10.1038/ncomms4749

Karpov, S. A. (2006). Sovremennye aspekty primenenija antidetonatorov v avtomobil'nyh benzinah. Neftepererabotka i neftehimi, 10, 26–33.

Subramani, V., Gangwal, S. K. (2008). A Review of Recent Literature to Search for an Efficient Catalytic Process for the Conversion of Syngas to Ethanol. Energy Fuels, 22 (2), 814–839. doi: 10.1021/ef700411x

Zuo, Z.-J., Wang, L., Liu, Y.-J., Huang, W. (2013). The effect of CuO–ZnO–Al2O3 catalyst structure on the ethanol synthesis from syngas. Catalysis Communications, 34, 69–72. doi: 10.1016/j.catcom.2013.01.008

Yue, H., Ma, X., Gong, J. (2014). An Alternative Synthetic Approach for Efficient Catalytic Conversion of Syngas to Ethanol. Accounts of Chemical Research, 47 (5), 1483–1492. doi: 10.1021/ar4002697

Gajdaj, O. O., Pyljavs'kyj, V. S., Polunkin, Je. V. (2016). Polipshennja ekspluatacijnyh vlastyvostej etanol'nyh motornyh palyv mikrodozamy karbonovyh sferoi'dal'nyh nanoklasteriv. Naukojemni tehnologii', 1, 3–8.

Li, H., He, X., Kang, Z., Huang, H., Liu, Y., Liu, J. et. al (2010). Water-Soluble Fluorescent Carbon Quantum Dots and Photocatalyst Design. Angewandte Chemie International Edition, 49 (26), 4430–4434. doi: 10.1002/anie.200906154

Higashihara, H., Shigematsu, K. (1992). Pat. N 06.24720. JP. Manufacture of fluorinated fullerenes. 06.07.92. Japane.

Ginzburg, B. M., Bajdakova, M. V., Kireenko, O. F. (2000). Vlijanie fullerena S60, fullerenovyh sazh i drugih uglerodnyh materialov na granichnoe trenie skol'zhenija metallov. Zhurnal tehnicheskoj fiziki, 70 (12), 87–97.

Himach, N. Ju., Polunkin, Je. V., Kolomys, O. F., Mel'nykova, S. L. (2006). Mehanohimichna modyfikacija mid'-cynk-aljumooksydnogo katalizatora syntezu metanolu. Voprosy hymyy y hymycheskoj tehnologyy, 1, 78–82.

Himach, N. Ju., Polunkin, Je. V., Filonenko, M. M., Mel'nykova, M. M. (2016). Aktyvacija katalizatora syntezu metanolu shljahom mehanichnoi' dii'. Dopovidi Nacional'noi' akademii' nauk Ukrai'ny, 3, 86–92.

Buyanov, R. A., Molchanov, V. V., Boldyrev, V. V. (2009). Mechanochemical activation as a tool of increasing catalytic activity. Catalysis Today, 144 (3-4), 212–218. doi: 10.1016/j.cattod.2009.02.042

Kapustin, V. M., Karpov, S. A., Carev, A. V. (2011). Oksigenaty v avtomobil'nyh benzinah. Moscow: KolosS, 336.

Frolov, K. V. (2008). Sovremennaja tribologija: itogi i perspektivy. Moscow: Izd-vo LKI, 480.

Piljavsky, V. S., Kovtun, G. A., Polunkin, E. V. et. al (2009). The tribological properties of modified fullerenes in different disperses mediums. Hydrogen Materials Science and Chemistry of Carbon Nanomaterials. Yalta, 478.

Goncharuk, V. V., Smirnov, V. N., Syroeshkin, A. V., Maljarenko, V. V. (2007). Klastery i gigantskie geterofaznye klastery vody. Himija i tehnologija vody, 29 (1), 3–16.

Debaj, P., Dzjaloshinskij, I. E. (1987). Izbrannye trudy. Stat'i 1909–1965. Leningrad: Nauka, 526.

Published

2016-06-30

Issue

Section

Technical Sciences