CALCULATION METHOD OF THERMODYNAMIC PROPERTIES GASEOUS MIXTURES
DOI:
https://doi.org/10.18198/j.ind.gases.2011.0587Keywords:
Gaseous mixtures, Thermodynamic properties, Equation of state, Intermolecular interactionsAbstract
Theoretical model of gaseous mixture useful for practical calculations that realizes conception of thermodynamic similarity for three-parameter potential (n–6) is proposed. The form of mixture state equation, method of parameter determination of n repulsion's steepness and other parameters needed for calculate, as well as a method for determining the energy of interaction of heterogeneous molecular data on the interaction of the pure components are explained. The potential parameters and other values are given for a large number of technically important gases required for the calculation of thermodynamic properties of mixtures of arbitrary composition.
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