EQUILIBRIUM LIQUID-VAPOR IN BINARY MIXTURES OF CARBON DIOXIDE WITH METHANE AND HELIUM

Authors

  • А. А. Вассерман Одесский национальный морской университет, ул. Мечникова, 34, г. Одесса, Украина, 65029, Ukraine https://orcid.org/0000-0001-8147-8417
  • В. Н. Галкин Одесский национальный морской университет, ул. Мечникова, 34, г. Одесса, Украина, 65029, Ukraine

DOI:

https://doi.org/10.18198/j.ind.gases.2017.0856

Keywords:

Binary mixtures, Liquid-vapor equilibrium, Carbon dioxide, Methane, Helium, Equations of phase equilibrium

Abstract

Compiled equations describing the experimental data of the liquid-vapor phase equilibrium in binary mixtures of carbon dioxide with methane and helium. Equations represents the dependence of liquid or vapor pressure from temperature and composition. At their compiling the program selected most significant coefficients of equation. Standard deviations of the experimental values of the pressure from calculated are equal from 3,0 to 4,1 %. Equations permits to determine the composition or temperature of phases at known values of  other parameters of the phase equilibrium.

Author Biographies

А. А. Вассерман, Одесский национальный морской университет, ул. Мечникова, 34, г. Одесса, Украина, 65029

A.A. Vasserman, Doctor of Technical Sciences

В. Н. Галкин, Одесский национальный морской университет, ул. Мечникова, 34, г. Одесса, Украина, 65029

V.N. Galkin

Issue

Section

THERMOPHYSICAL PROPERTIES OF GASES AND THEIR MIXTURES. THERMODYNAMIC ANALYSIS OF PROCESSES IN LOW-TEMPERATURE SYSTEMS