The thermal expansion of glasses Ge<sub>x</sub>As</sub>40-x</sub>Se<sub>60</sub>
DOI:
https://doi.org/10.24144/2415-8038.2010.28.52-56Keywords:
Chalcogenide glass, Thermal expansion, Dilatometry, AnharmonicityAbstract
The thermal expansion of glasses GeхAs40-хSe60 is investigated with use the vertical quartz dilatometer in the temperature range 80-550 K is investigated. The temperature ranges of the strong increase the coefficient of linear expansion α of these materials and spacing stabilization are found. The concentration transformation of the dependences α(T) are interpreted on the basis of structural changes in the structure of the grid of glasses of Ge-As-Se. It is shown, that with increasing dimension of the structural glass network the anharmonicity of the thermal vibrations of atoms decreases.
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