Kinetics of photostimulated changes of the refractive index in As-S amorphous films

Authors

  • В. М. Кришеник Institute for Solid State Physics & Chemistry, Uzhhorod National University, Ukraine
  • В. І. Мікла Institute for Solid State Physics & Chemistry, Uzhhorod National University, Ukraine

DOI:

https://doi.org/10.24144/2415-8038.2010.28.80-86

Keywords:

Amorphous chalcogenides, Photo-sensitiveness, Thin films, Optical waveguide, Refractive index, Dynamical effects

Abstract

The kinetics of photostimulated changes in the layers of non-crystalline chalcogenides AsxS1-x with different compositions has been studied be waveguiding techniques. The nature of both dynamic and irreversible components of photoinduced variations in optical parameters has been analyzed. Possible mechanisms of transformation have been proposed by which reversible (temporal) and irreversible components of changes in film parameters are set. The role a defective microstructure of films including the molecular-phase separation for optical effects have been discussed.

References

Popescu M. Non-Crystalline Chalcogenides, – Solid State Science and Technology Library, V. 8, Kluwer Academic Publishers, Dordrecht, – 2000, –385 p.

Mikla V.I., Mikla V.V. Metastable states in amorphous chalcogenide semiconductors // Series: Springer Series in Material Science, vol. 128, 2010, – 122 p.

Tanaka K., Ohtsuka Y. Measurements of photoinduced transformations in amorphous As2S3 films by optical waveguiding // J. Appl. Phys. – 1978 – V. 49 (12) – P. 6132-6135.

Mikla V.I., Kryshenik V.M. Investigation of anisotropy in as-evaporated amorphous chalcogenide thin films by optical waveguiding // J. Non-Cryst. Solids – 2003 – V.330 – P.33-38.

Kryshenik V.M., Trunov M.L., Ivanitsky V.P., Vectoral respons under photo-excitation in amorphous chalcogenides and azobenzene polymer films: a comparison // J. Optoelectron. Adv. Mater. 2007 – V 9, – No 7, – P. 1949-1964.

Wang Fei, Boolchand P. Photo-structural transformation and global connectedness // Non-Crystalline Materials for Opto-electronics, V.1, INOE Publishers – Bucharest – 2004. – P. 15-42.

Yannopoulos S.N., Trunov M.L. Photoplastic effects in chalcogenide glasses: A review // Phys. Stat. Sol. – 2009 – V. 246 (8) – P. 1773-1785.

Li J., Drabold D.A. Direct Calculation of Light-Induced Structural Change and Diffusive Motion in Glassy As2Se3 //Phys. Rev. Lett. – 2000 – V. 85 (13) –P. 2785-2788.

Frumar M., Polak Z., Cernosek Z. Raman spectra and photostructural changes in the short-range order of amorphous As- S chalcogenides // J. Non-Cryst. Solids – 1999 – V.256-257 – P. 105-110.

Elliott S.R., Greaves G.N., Lowe A. et al. EXAFS studies of photostructural changes in chalcogenide glasses // J. De Physique – 1986 – V.12(47) –P. 363-368.

Published

2010-12-31

Issue

Section

Статті