The room temperature visible photoluminescence in g- As<sub>2</sub>S<sub>3</sub> and Ge-based glasses

Authors

  • G. Lovas Uzhhorod National University, Ukraine
  • V. Mitsa Uzhhorod National University, Ukraine
  • R. Holomb Uzhhorod National University, Ukraine
  • I. Rosola Uzhhorod National University, Ukraine
  • E. Borkach II. Rákóczi Ferenc Transcarpathian Hungarian Institute, Ukraine

DOI:

https://doi.org/10.24144/2415-8038.2013.34.54-58

Keywords:

Visible photoluminescence, Chalcogenide glass, Oxide phase, Edge absorption, GeS2

Abstract

PL radiation from long term aged fractured surfaces of GeS2-based glasses was assigned to the surface contaminant effect from native oxidized layer, which might have formed in the air. When have been used for PL measuring the freshly fractured surface of g-GeS2(T3V2) all PL peaks which was connected with GeOx species where disappeared in PL spectrum.

References

Zalkovsij M., Bisgaard C. Zoffman, Novitsky A., Malureanu R., Savastru D., Popescu A., Jepsen P.U., Lavrinenko A.V. Ultraboardband terahertz spectroscopy of chalcogenide glasses // Applied Physics Latters. 2012. - vol. 100. - P. 031901-1-031901-6.

Mitsa V., Holomb R., Veres M., Mar¬ton A., Rosola I., Fekeshgazi I., Koós M. Non-linear optical properties and structure of wide band gap non-crystalline semiconductors // Phys. Stat. Sol. C. - vol. 8. - № 9. – 2011. - P. 2696-2700.

Liu X., Naftaly M., Iha A. Spectroscopic evidence for oxide dopant sites in GeS2-based glasses using visible photo-luminescence from Pr3+ probe ions // Journal of Luminescence. - vol. 96. - 2002. - P. 227-238.

Gamulin O., Ivanda M., Mitsa V., Balarin M., Kosovic M. Monitoring structural phase transition of (Ge2S3)x(As2S3)1-x chalcogenide glass with Raman spectroscopy // Journal of Molecular Structure. - vol. 993. - 2011. – P. 264–268.

Eggleton B.J., Luther-Davies B., Richardson K. Chalcogenide photonics // Nature Photonics. - vol. 5. – 2011. - P. 141-148.

Mitsa V., Babinets Y., Gvardionov Y. and Yermolovich I. Photoluminescence in GexAsyS1-x-y by varying the average coordination number // J. of Non-Crystalline Solids. - vol. 137&138. – 1991. - P. 959-962.

Popescu M. Non-Crystalline Chalcogenides // KluwerAcademic Publishers. – New York. – 2000.

Kolobov A.V. Photo-induced metastability in amorphous semiconductors // Wiley-VCH. - 2003.

Fairman R. and Ushkov B. Semiconducting Chalcogenide Glass.

P.I–III. P.I. Glass formation,structure, and simulated transformations inchalcogenide glass; P. II. Properties of glasses // Elsevier. - 2004.

Davydova N.A., Bondar N.V., Tyschenko V.V. Photoiduced effects in luminescent spectra of chalcogenide glasses // Journal of Applied Spectroscopy. - vol. 69. – 2002. - P. 258-262.

Nakanishi 3.T., Tomii Y., Hachiya K. Temperature dependence of the photoinduced fatigue-recovery phenomena of photoluminescence under prolonged irradiation in GeS2 chalcogenide glass // J. of Non-Crystalline Solids. - vol. 354. – 2008. - P. 1627-1632.

Terakado N., Tanaka K. Does the charged defect exist in nano-structured chalcogenide glass? // Applied Physics Express. - vol. 1. – 2008. - P. 081501-1-081501-3.

Holomb R., Mitsa V., Petrachenkov O., Veres M., Stronski A. and Vlček M. Comparison of structural transformations in bulk and as-evaporated optical media under action of polychromatic or photon-energy dependent monochromatic illumination // Phys. Stat. Sol. C. - vol. 8. - № 9. – 2011. - P. 2705-2708.

Murayama K., Bösch M.A. Radiative recombination in crystalline As2S3 // Physical Review B. - vol. 23. – 1981. - P. 6810-6812.

Tanaka K. Excitation-energy-dependent photoluminescence in glassy As–S and crystalline As2S3 // Phys. Status Solidi B. - vol. 1–6. – 2013. - DOI 10.1002/pssb.201248519.

Kartopu G., Bayliss S.C., Karavansckii V.A., Curry R.J., Turan R., Sapelkin A.V. On the origin of the 2.2-2.3 photoluminescence from chemically etched germanium // J of Luminescence. - vol. 101. – 2003. - P. 275-283.

Ko T.S., Shieh J., Yang M.C., Lu T.C., Kuo H.C., Wang S.C. Phase transformation and optical characteristics of porous germanium thin films // This Solid Films. - vol. 516. – 2008. - P. 2934-2938.

Sun K.W., Sue S.H., Liu C.W. Visible luminescence from Ge quantum dots // Physica E. - vol. 28. – 2005. - P. 525-530.

Lezal D. Chalcogenide glasses – survay and progress // Journal of Optoelectronics and Advanced Materials. - vol. 5. -2003. - P. 23–34.

Bishop S.G., Shanabrook B.V., Strom U. and Taylor P.C. Comperison of optically induced localized states in chalcogenide glasses and their crystalline counterparts // J. De Phisique E. - vol. 42. – 1981. - P. C4-383-C4-386.

Mingfa Peng, Yang Li, Jing Gao, Duo Zhang, Zheng Jiang, Xuhui Sun. Electronic Structure and Photoluminescence Origin of Single-Crystalline Germanium Oxide Nanowires with Green Light Emission // J. Phys. Chem. C. - vol. 115. – 2011. - P. 11420–11426.

Zyubin A.S., Mebel A.M., Lin S.H. Photoluminescence of oxygen-deficient defects in germanium oxides: A quantum chemical study // The Journal of Chemical Physics. - vol. 125. – 2006. - P. 064701-0647011.

Holomb R., Johansson P., Mitsa V., Rosola I. Local structure of technologically modified g-GeS2: resonant Raman and absorption edge spectroscopy combined with ab initio calculations // Philosophical Magazine. - 2005. - vol. 85.- P. 2947-2960.

Banik I. On photoluminescence in chalcogenide glasses based on barrier-cluster model // J. of Non – Oxide and Photonic Glasses. - vol. 1. – 2009. - P. 29-33

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Published

2013-11-25

Issue

Vol. 34 (2013)

Section

Статті

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