LOW-FREQUENCIES (LF) RAMAN SPECTRUMS OF AsxSi-x GLASSES, VIBRATIONAL SPECTRUMS OF As„Sm CLUSTERS CALCULATED BY "AB INITIO" METHOD AND THE DISTRIBUTION OF CLUSTERS LENGTH

Authors

  • R. M. Holomb Uzhgorod State University, Ukraine
  • M. V. Mitsa Uzhgorod State University, Ukraine
  • N. I. Mateleshko Uzhgorod State Universit, Ukraine

DOI:

https://doi.org/10.24144/2415-8038.2002.11.136-140

Keywords:

Ab intitio, Raman Spectrum, Clusters

Abstract

The results of comparison of spectral position of the LF bands of As-S glass sys­tem with theoretical calculation of vibrational spectra of different clusters (As2S3,

As2S5, As4S6, As6S9) in the LF region (5-100 cm' ) are given. Calculated distribution of clusters lengths f(L) for As2S3 glass

References

Phillips J, C- Topology of covalent non crystalline solids. Medium-range in chai cogenide alloys a-Si(Ge). // J. Non- Cryst.Sol, I981.-Vol. 43. №1. - p.37-47.

Lucovsky G, Wong С. K, Pollard W. B. Vibrational properties of glasses: intermediate range order. // J. Non-Cryst.SoI, 1983,-Vot. 59-60. №2. - p. 839-846.

V. M. Mitsa, Vibrational spectra and Structural correlation in non-oxide glassy alloys, Ed. Ministry of High Educ. Of Ukraine, Kiev, 1992.

Glotin M, Mandelkem L. On the use of Raman active longitudinal acoustic mode

in study of crystallite distribution in polyethylene. // I. Polim. Science: Polimer Lett. - 1983. - Vol.21.-p. 807-811.

G- R. Stnobl and Eckel, J, Polym. Sci. Polym. Phys. Ed., 14,913(1976)

G. V, Fraser, Polymer, 19, 857 (1978)

S. L. Hsu and S. Kriitim, J. Appl. Phys., 47, 4265 (1976)

M, Glotin and L. Mandelkem, J. Polvm. Sci. Polym. Phys, Ed, 21,29(1983)

R. G. Snyder, S. J. Krause, and J. R. Coherer, J. Polym. Sci. Polym. Phys. Ed, 16,1593(1978)

R. G. Snyder and J. R. Coherer, J. Polym. Sci. Polym. Phys. Ed, 18, 421 (1980).

Gaussian 94, Revision В.2, M. J. Frisch, G. W. Trucks, H. B. Schlegel, at oil., Gaussian, Inc., Pittsburgh PA, 1995

Malinovsky V. K., Novikov V. N., Sokolov A. P. Investigation of structural correlation in disordered materials by Raman scattering measurements. 11 J. Non-Cryst. Sol., 1987. - Vol. 90. №1-3. - p. 485-488.

Thorpe M., Cai J. Mechanical and vibra¬tional properties of network structure. // J. Non-Cryst. Sol. - 1989. Vol. 114. №1. p. 19-24. (1999) 109-115.

Birgit Effey, R.L. Cappalletti. Neutron inelastic scattering study of Ge-As-Se glasses: A test of the vibrational isocoordinate rule. // J. Phys. Rev., 1999. - Vol. 59. №6.-p. 4119-4124.

W. A. Kamitakahara, R.L. Cappalletti, P. Boolchand, B. Halfpap, F. Gompf, D. A. Neumann, H. Mutka. Vibrational densities of states and network rigidity in chalcogenide glasses. // J. Phys. Rev., 1991. - Vol. 44. №1. - p. 94-100.

Downloads

Issue

Section

Статті