Determination of kinetic parameters of the reaction of formation of the solid-phase adsorbents

Authors

  • Виктор Иванович Булавин National Technical University «Kharkiv Polytechnic Institute», str. Frunze 21, Kharkov, Ukraine, 61002, Ukraine https://orcid.org/0000-0002-0161-1669
  • Николай Андреевич Блинков National Technical University «Kharkiv Polytechnic Institute», str. Frunze 21, Kharkov, Ukraine, 61002, Ukraine https://orcid.org/0000-0002-4354-9525

DOI:

https://doi.org/10.15587/2312-8372.2015.43793

Keywords:

reaction, rate, order, kinetics, crystalline hydrates, orthophosphates, ethyl alcohol, equation

Abstract

Reaction order of crystalline hydrate formation is calculated in the article. This reaction often takes place during contact with water of a number of inorganic salts, at least – acids and alkalis. Sometimes – and organic substances, such as known hydrocarbon and methane hydrates. These processes are often unwanted, so hydrate inhibitors are used in the main pipelines.

But the formation of crystalline hydrates is useful process too. Thus, their use allows to form crystals, and more importantly, to remove unwanted water. This ability is applied for gas drying as well as organic and inorganic liquids, even – removal of these unwanted water. New compound forms after removal of anhydrous salt water from. The theoretical experience show that the quality of some dehydration salts is very high.

Certain inorganic salts may bind more water by weight than weigh yourself. They also have the ability to some extent to give the bound water and again become anhydrous salts. This ability makes it possible to use them several times with almost no losses.

So, we have a problem how exactly the process of interaction of inorganic salt with water to form crystalline takes place. It is used the fact that lowering the temperature of the reaction is faster, and that on this basis we can calculate the activation energy.

Establishment of the reaction order and activation energy calculation contributes to the proper conducting this reaction in an industrial environment.

Author Biographies

Виктор Иванович Булавин, National Technical University «Kharkiv Polytechnic Institute», str. Frunze 21, Kharkov, Ukraine, 61002

Candidate of Chemical Sciences, Associate Professor, Head of Department

Department of General and Inorganic Chemistry

Николай Андреевич Блинков, National Technical University «Kharkiv Polytechnic Institute», str. Frunze 21, Kharkov, Ukraine, 61002

Postgraduate

Department of General and Inorganic Chemistry

References

  1. Borisenko, E. M. (1969). Izuchenie kinetiki degidratatsii nekotoryh kristallogidratov. Minsk: Belarusian Red Banner of Labor State University named after V. I. Lenina, 3-6.
  2. Aristov, Yu. I., Gordeeva, L. G., Korotkih, V. N., Parmon, V. N., Tokarev, M. M.; assignee: Institute of Catalysis named after G. K. Boreskov, Siberian Branch of Russian Academy of Sciences. (27.06.2001). Kompozitnyi osushitel' gazov i zhidkostei. Patent RF № 2169606; B01D53/26, B01J20/28. Appl. №99112544/12. Filed 15.06.1999. Available: http://ru-patent.info/21/65-69/2169606.html
  3. Aristov, Yu. I., Tokarev, M. M., Korotkih, V. N., Ostrovskii, N. M., Chumakova, N. A., Koptiug, I. V., Hitrina, L. Yu., Bernikovskaia, N. V., Buhavtsova, N. M. (2001). Sushka vozduha: novye kompozitnye sorbenty "sol' v poristoi matritse". In: Sovremennye podhody k issledovaniiu i opisaniiu protsessov sushki poristyh tel. Novosibirsk: SO RAN, 180-211.
  4. Goronovskii, I. T., Nazarenko, Yu. P., Nekriach, E. F. (1987). Kratkii spravochnik po himii. Ed. 5. K.: Naukova dumka, 833.
  5. Gankin, Yu. V. (2007). Kak obrazuetsia himicheskaia sviaz' i protekaiut himicheskie reaktsiit. M.: Granitsa, 318.
  6. Tovazhnianskii, L. L., Loboiko, O. Ya., Yavorskii, V. T., Voloshin, M. D., Stoliarenko, G. S.; In: Tovazhnianskii, L. L. (2011). Tehnologiia fosfornosoderzhashchih udobrenii, kislot i solei. Kharkov: NTU «KhPI», 94.
  7. Levine, R. D. (2005). Molecular Reaction Dynamics. Cambridge University Press, 568. doi:10.1017/cbo9780511614125
  8. Laidler, K. J. (1987). Chemical Kinetics. Ed. 3. Harper & Row, 531.
  9. Nikandrov, M. I., Nikandrov, I. S., Krasnov, Yu. V. (2010). Issledovanie kristallizatsii odno- dvuh- i triohzameshchionnyh fosfatov natriia. Trudy NGTU im. R. E. Alekseeva. Nizhny Novgorod: Nizhny Novgorod State Technical University named after R. E. Alekseeva, 249-254.
  10. Chorkendorff, I., Niemantsverdriet, J.; Translated from English Roldugin, V. (2010). Concepts of Modern Catalysis and Kinetics. Ed. 2. Dolgoprudnyi: Intellekt, 504.
  11. Gmurman, V. E. (2003). Teoriia veroiatnostei i matematicheskaia statistika. Ed. 9. M.: Vysshaia shkola, 479.
  12. Baklanov, A. V. (2009). Himicheskaia kinetika. Novosibirsk: Publishing center of the NSU, 99.
  13. Galushnik, A. V. (2002). Energiia aktivatsii stadii protsessu elektrohimicheskogo osazhdeniia medi. K.: National Institute named after Vernadsky, 17.
  14. Gankin, V. Yu., Gankin, Yu. V. (2007). Kak obrazuetsia himicheskaia sviaz' i protekaiut himicheskie reaktsii. M.: Granitsa, 318.
  15. Lidin, R. A., Andreeva, L. L., Molochko, V. A. (2008). Konstanty neorganicheskih veshchestv. M.: Drofa, 685.

Published

2015-05-28

How to Cite

Булавин, В. И., & Блинков, Н. А. (2015). Determination of kinetic parameters of the reaction of formation of the solid-phase adsorbents. Technology Audit and Production Reserves, 3(4(23), 38–41. https://doi.org/10.15587/2312-8372.2015.43793

Issue

Section

Technology organic and inorganic substances