SPHERICAL MODEL OF POLYATOMIC MOLECULES OF TECHNICALLY IMPORTANT GASES

Authors

  • В. И. Недоступ Физико-химический институт им. А.В. Богатского Национальной академии наук Украины, Люстдорфская дорога, 86, г. Одесса, 65080, Украина, Ukraine
  • О, В. Недоступ Физико-химический институт им. А.В. Богатского Национальной академии наук Украины, Люстдорфская дорога, 86, г. Одесса, 65080, Украина, Ukraine
  • В. Е. Кузьмин Физико-химический институт им. А.В. Богатского Национальной академии наук Украины, Люстдорфская дорога, 86, г. Одесса, 65080, Украина, Ukraine

DOI:

https://doi.org/10.18198/j.ind.gases.2004.0149

Keywords:

real gases, molecules, moments of inertia, electronegativity, dipole moments

Abstract

The method assuming free rotation of molecule for the search of any conformation sphere analog of the polyatomic molecule was developed. This method is based on the determination of inert radius calculated by the value of the principal  moments of inertia. Subject to this it is shown how to expect the average characteristic in the point on the sphere of found before radius. The calculation technique of the principal inert moments by the data on the molecule conformation, content of rotary isomers as well as properties of atoms included in molecule and characteristics of valence bonds are reported in the article. Sphere characteristics of refrigerant molecules of methane and ethane series are given as a result of calculation.

Author Biographies

В. И. Недоступ, Физико-химический институт им. А.В. Богатского Национальной академии наук Украины, Люстдорфская дорога, 86, г. Одесса, 65080, Украина

V. I. Nedostup

О, В. Недоступ, Физико-химический институт им. А.В. Богатского Национальной академии наук Украины, Люстдорфская дорога, 86, г. Одесса, 65080, Украина

O. V. Nedostup

В. Е. Кузьмин, Физико-химический институт им. А.В. Богатского Национальной академии наук Украины, Люстдорфская дорога, 86, г. Одесса, 65080, Украина

V. E. Kuz’min

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Issue

No. 4 (2004): Технические газы

Section

THERMOPHYSICAL PROPERTIES OF GASES AND THEIR MIXTURES. THERMODYNAMIC ANALYSIS OF PROCESSES IN LOW-TEMPERATURE SYSTEMS

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