THERMODYNAMIC MODEL OF GAS HYDRATES

Authors

  • В. И. Недоступ Физико-химический институт им. А.В. Богатского Национальной академии наук Украины, Люстдорфская дорога, 86, г. Одесса, Украина, 65080, Ukraine
  • О. В. Недоступ Физико-химический институт им. А.В. Богатского Национальной академии наук Украины, Люстдорфская дорога, 86, г. Одесса, Украина, 65080, Ukraine

DOI:

https://doi.org/10.18198/j.ind.gases.2008.0384

Keywords:

Gas hydrates, Rare gases, Methane, Water, Potential function, Enthalpy, Ener-gy, Heat, Phase transition

Abstract

The interest to gas hydrates grows last years. Therefore working out of reliable settlement-theoretical methods of definition of their properties is necessary. The thermodynamic model of gas hydrates in which the central place occupies a behaviour of guest molecule in cell is described. The equations of interaction of molecule hydrate formative gas with cell are received, and also an enthalpy and energy of output of molecule from a cell are determined. The equation for calculation of thermodynamic characteristics of hydrate on curve  of hydrate formative is developed.

Author Biographies

В. И. Недоступ, Физико-химический институт им. А.В. Богатского Национальной академии наук Украины, Люстдорфская дорога, 86, г. Одесса, Украина, 65080

V.I. Nedostup

О. В. Недоступ, Физико-химический институт им. А.В. Богатского Национальной академии наук Украины, Люстдорфская дорога, 86, г. Одесса, Украина, 65080

O.V. Nedostup

Downloads

Issue

No. 4 (2008): Технические газы

Section

THERMOPHYSICAL PROPERTIES OF GASES AND THEIR MIXTURES. THERMODYNAMIC ANALYSIS OF PROCESSES IN LOW-TEMPERATURE SYSTEMS

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