Tectono-magmatogenering structures in zones of increased geodynamic instability as priority objects for exploration of hydrogen fields


  • A.E. Lukin Institute of Geological Sciences of the NAS of Ukraine, Ukraine
  • V.M. Shestopalov Radio-Environmental Centre of the NAS of Ukraine, Ukraine




Based on comparison of the migration activity of hydrocarbons, helium and hydrogen, the paper substantiates the types of cap rocks for hydrogen accumulations (pools), which most of all contributes to its partial shieldingat steady feed. Such cap rocks are represented by predominantly smectite clay, pure (without inclusions) salt at depths over 1—2 km, non-fractured quartz sandstone at depths over 4 km, effusive and hypabissal intrusive rocks, as well as basement rocks undisturbed by metamorphic decomposition processes. Endogenous hydrogen isconsidered as the main factor of dissipative structures formation. Occurrence of hydrogen, hydrocarbon and ore macro accumulations is a kind of energy, information-geochemical fluctuations, which are intermediate states of dissipative structures subordinated to the planetary heat and mass transfer processes caused by the deep Earth degassing. In this context, the nature of geodynamic instability (activation of vertical movements, shifts, tensile and compressive stresses) can be considered as a growing sequence of dissipative processes associated with the energy percolation role of endogenous hydrogen. In the hierarchy of ring structures (RS) (from minor depressions to large structures of dozens kilometres in diameter) special attention should be paid to Sribne RS within the Dnieper-Donets Basin and Kaluga RS within the SW part of the Voronezh anteclisepericline. These ring structuresare genetically related to explosion or volcanic calderas, and characterized by ancient origin (Proterozoic) and long-term development, including neo- and actuotectonic stages. Intensity of hydrogen degassing in the Sribne RSis confirmed by micro- and nano-inclusions in the black-shale domanicoid rocks of the productive horizons in the form of particles of native metals(including oxyphile elements Al, Zn, W and others), natural alloys and intermetallids, which are tracers of ascending flows of deep reduced fluids. It is reasonable to assume the occurrence of a large hydrogen or helium-hydrogen field (group of fields) within the Sribne RS in the Lower Visean, Lower Bashkirian and Lower Permian aged rocks, which are shielded by the Lower Permian salt deposits.


Arsiriy, Yu.A., Kabyshev, B.P., Lebed, V.P., Lukin, A.E., & Shevchenko, A.F. (1980). Prospects of oil-and-gas content in the Sribne Depression within the Dnieper-Donets Basin. Geologiya Nefti i Gaza, (5), 18—23 (in Russian).

Atlas of the geological structure and oil-and-gas content in the Dnieper-Donets Basin (1981). Kyiv: GKP CTE, 190 p. (in Russian).

Bagriy, I.D., Karpenko, O.M., Semenyuk, V.G, & Glon, V.A. (2016). Geological-structural-thermo-atmo-geochemical technologies of prediction, prospecting and exploration of hydrocarbon fields: textbook. Kyiv: Publ. of the Institute of Geological Sciences of the National Academy of Sciences of Ukraine, 309 p. (in Ukrainian).

Vaganov, V.I., Ivankin, P.F., Kropotkin, P.N., Trukhalev, A.I., Semenenko, N.P., Tsymbal, S.N., Tatarintsev, V.I., Glukhovskiy, M.Z., & Bulgakov, E.A. (1985). Explosion ring structures in the shields and platforms. Moscow: Nedra, 200 p. (in Russian)

Gavrish, V.K., Zabello, G.D., Ryabchun, L.I., Lukin, A.E., Nedoshovenko, A.I. (1989). Geology and oil-and-gas content of the Dnieper-Donets Basin. Depth structure and geotectonic development. Kiev: Naukova Dumka, 208 p. (in Russian).

Paffengolts, K.N. (Ed.). (1978). Dictionary of Geology (Vol. 1). Moscow: Nedra, 488 p. (in Russian).

Glon, V.A. (2019). Features of formation and forecast of oil-and-gas content of the Sribne depression based on complex of structural-thermo-atmogeochemical studies. Extended abstract of candidate’s thesis. Kyiv, 21 p. (in Ukrainian).

Gonshakova, V.I., Chernyshev, N.M., & Volkova, V.M. (1989). Subdivision of Precambrian trap formations in the southwest of the East European Platform. Sovetskaya Geologiya, (9), 65—72 (in Russian).

Gordienko, V.V., & Tarasov, V.N. (2001). Recent activation and helium isotopy of the Ukrainian territory. Kyiv: Znaniya, 100 p. (in Russian)

Goryainov, P.M., & Ivanyuk, G.Yu. (2011). Energy percolation — a resource of new ideas in geotectonics. Vestnik Voronezhskogo universiteta. Geologiya, (11), 7—22 (in Russian).

Gufeld, I.L. (2007). Seismic process. Physical and chemical aspects. Moscow: TsNIIMash, 160 p. (in Russian)

Gufeld, I.L., & Matveeva, M.I. (2011). Barrier effect of degassing and destruction of the Earth’s crust. Doklady RAN, 438(2), 253—258 (in Russian).

Ermakov, I.M., Lukin, A.E., & Turchanenko, N.T. (1988). Pre-Devonian graben in the Dnieper-Donets avlacogene. Doklady AN USSR, (3), 10—13 (in Russian).

Zhabrev, I.P. (1986). Super reservoirs and their role in management of the development system. Geologiya Nefti i Gaza, (8), 1—6 (in Russian).

Kazankova, E.R., & Kornilova, N.V. (2019). Geoecological aspects of the functioning of the Severo-Staropolskoye underground gas storage (from the standpoint of nonlinear geodynamics). Groznenskiy yestestvennonauchnyy byulleten, 4(3), 41—48. https://doi.org/10.25744/genb.2020.17.3.005 (in Russian).

Kazankova, E.R., & Kornilova, N.V. (2009). Geo-environmental problems of underground gas storage facilities (using Moscow region as an example). Byulleten Moskovskogo Obshchestva Ispytatelei Prirody. Otdel Biologicheskiy, 114(3). Annex 1, part 1, 388—397 (in Russian).

Kazankova, E.R., & Kornilova, N.V. (2015). Kaluga ring structure as a result of self-organization of geological media. Georesursy, Geoenergetika, Geopolitika, (1), 11 p. Retrieved from http://www.oilgasjournal.ru (in Russian).

Kazankova, E.R., Sudo, R.M. (2000). Non-linear geodynamics and ecology of the Earth's interior (in terms of self-organization of stress fields). In Basis research for new technologies in oil-and-gas industry (pp. 359—364). Moscow: GEOS (in Russian).

Kozlova, I.S., Rudakov, V.P., Shuleikin, V.I., Voitov, G.I., & Baranova, L.V. (1999). Emanation and electrical effects in subsoil atmosphere above the Kaluga impact ring structure. Rossiyskiy Zhurnal nauk o Zemle, 1(6), 503—510 (in Russian).

Kropotkin, P.N. (1973). Tectonic stresses in the Earth’s crust according to direct measurements. In Stressed state of the Earth’s crust (pp. 21—31). Moscow: Nauka (in Russian).

Kropotkin, P.N., & Efremov, V.N. (1987). Tectonic stresses on platforms and global variations of cyclicity. Geotektonika, (1), 3—25 (in Russian).

Levshunova, S.P. (1994). Hydrogen and its biogeochemical role in the formation of hydrocarbon gases in sedimentary rocks of the Earth’s crust. Extended abstract of candidate’s thesis. Moscow, 39 p. (in Russian).

Letnikov, F.A. (1992). Ultradeep fluid systems of the Earth. Novosibirsk: Nauka, 150 p. (in Russian).

Letnikov, F.A. (1992). Synergetics of geological systems. Novosibirsk: Nauka, 232 p. (in Russian).

Letnikov, F.A., Karpov, I.K., Kiselev, A.I., & Shkondriy, B.O. (1977). Fluid regime of the Earth’s crust and upper mantle. Moscow: Nauka, 214 p. (in Russian).

Lukin, A.E. (2002). Hypogenous-allogenetic decompression — a leading factor in the formation of secondary oil-and-gas reservoirs. Geologichnyi Zhurnal, (4), 15—32 (in Russian).

Lukin, A.E. (2005). Deep hydrogeological inversion as synergistic global phenomenon: theoretical and applied aspects. Article 2: Tectonic and geodynamic aspects of deep hydrogeological inversion. Geologichnyi Zhurnal, (1), 50—67 (in Russian).

Lukin, A.E. (1997). Injections of deep hydrocarbon-polymineral substance in the deep lying rocks of oil-and-gas bearing basins. Kyiv: Naukova Dumka, 225 p. (in Russian).

Lukin, A.E. (2000). Injection of deep hydrocarbon-polymineral substance in the deep lying rocks of oil-and-gas bearing basins: nature, applied and epistemological significance. Geologichnyi Zhurnal, (2), 7—21 (in Russian).

Lukin, A.E. (1989). Lithogeodynamic factors of oil and gas accumulation in avlacogenic basins. Extended abstract of Doctor’s thesis. Kiev, 42 p. (in Russian).

Lukin, A.E. (2004). Problems of naftidosynerge-tics — nonlinear geology of oil-and-gas. Geologichnyi Zhurnal, (1), 21—39 (in Russian).

Lukin, A.E. (2020).The Early Visean Euxinic basin in the system of Paleo-Tethys (in the light of modern data). Geologiya i korysni kopalyny Svitovogo okeanu, 16(2), 24—48 (in Russian).

Lukin, A.E., Vladimirov, A.S., Ermakov, I.M., & Turchanenko, N.T. (1992). Problem of Pre-Devonian riftogenesis in the Dnieper-Donets avlacogen. Geotektonika, (2), 30—46 (in Russian).

Lukin, A.E., Gafich, I.P., Makogon, V.V., & Kholodnykh, A.B. (2016). Prospects for gas-petroleum potential of deep-lying Waulsortian carbonate bosses in the central part of the Dnieper-Donets Depression. Dopovidi NAN Ukrayiny, (8), 70—78 (in Russian).

Lukin, A.E., Dovzhok, E.I., Knishman, A.Sh., Goncharenko, V.I., & Dzyubenko, A.I. (2012а). Helium anomaly in petroliferous Visean carbonate reservoirs of the Dnieper-Donets Depression. Dopovidi NAN Ukrayiny, (7), 97—104 (in Russian).

Lukin, A.E., Melikhov, V.A., & Gridin, V.I. (1978). Method of detecting poorly marked oil-and-gas traps. Doklady AN USSR, 245(6), 1447—1451 (in Russian).

Lukin, A.E., & Novgorodova, M.I. (1994). On discovery of iron silicide of extra-terrestrial origin. Doklady RAN, 334(1), 73—76 (in Russian).

Lukin, A.E., Tsekha, O.G., Geyko, T.S., & Omelchenko, V.V. (2012б). Tectonics of the northern flank of the Dnieper-Donets avlacogen in the context of general regularities of continental riftogenesis. Geologichnyi zhurnal, (3), 7—38 (in Russian).

Lukin, A.E., & Shestopalov, V.M. (2020). Ferrosilicide as indicator of mineral composition of the Earth's mantle? Geofizicheskiy Zhurnal, 42(5), 3—15. https://doi.org/10.24028/gzh.0203-3100.v42i5.2020.215069 (in Russian).

Lukin, A.E., Shpak, P.F., Chepil, V.P., & Machulin, S.V. (1994а). On the Sribne Middle Visean megaatoll in the Dnieper-Donets Depression. Dopovidi NAN Ukrayiny, (8), 101—105 (in Russian).

Lukin, A.E., Shumlyanskiy, V.A., Diachenko, G.I., & Ivantishina, O.M. (1994б). Problems of cold degassing of the Earth. Kyiv, Prepr. IGS NASU, 71 p. (in Russian).

Malkovskiy, V.I., Pek, A.A., Aleshin, A.P., & Velichkin, V.I. (2008). Estimation of the time of magma chamber solidification under Streltsovо caldera and its influence on non-stationary distribution of temperatures in the upper part of the Earth crust (Eastern Trans-Baikal Region, Russia). Geologiya rudnykh mestorozhdeniy, 50(3), 217—224 (in Russian).

Marakushev, A.A. (1981). Impactites. Moscow: Moscow: Publishing house of the Moscow State University, 240 p. (in Russian).

Masaitis, V.L. (1975). Astroblemеs on the territory of the USSR. Sovetskaya Geologiya, (11), 52—64 (in Russian).

Pushcharovskiy, Yu.M. (Ed.) (1994). Nonlinear geodynamics. Collected works. Moscow: Nauka, 191 p. (in Russian).

Nicolis, G., & Prigozhin, I. (1977). Self-organization in nonequilibrium systems. Moscow: Mir, 512 p. (in Russian).

Perevozchikov, V.G. (2012). Hydrogen field within the Gazli field according to geochemical studies in the oil-and-gas region of Central Asia. Neftegazovaya Geologiya, 7(1), 1—13 (in Russian).

Petrov, V.G. (1969). Structural features of the Kaluga structure. Byulleten Moskovskogo Obshchestva Ispytatelei Prirody. Otdel Geologicheskiy, 44(6) (in Russian).

Petrov, V.P. (1971). On the separation of the Kaluga-Belsk structural zone. Byulleten Moskovskogo Obshchestva Ispytatelei Prirody. Otdel Geologicheskiy, 46(3) (in Russian).

Portnov, A.M. (2005). Energy of volcanoes. Priroda i chelovek, (4), 10—11 (in Russian).

Prigogine, I., & Stengers, I. (1986). Order out of Chaos. Moscow: Progress, 432 p. (in Russian).

Ryabov, V.V., & Lapkovskiy, A.A. (2008). Volcano-tectonic structures in Siberian traps as are-as of accumulation and discharge of formation fluids during tectonic-magmatic activation of the region. Geologiya i Geofizika, (11), 490—495 (in Russian).

Svoren, I.M. (1985). Physico-chemical model of solids enrichment with hydrogen. Proceedings from the 7th All-Union Conference «Thermobarometry and geochemistry of ore-forming fluids (by inclusions in minerals)» (pp. 224—226). Part 2. Lviv (in Russian).

Nalivkin, V.D. (Ed.). (1988). Dictionary of Petroleum Geology. Leningrad: Nedra, 680 p. (in Russian).

Sokolov, V.A. (1971). Geochemistry of natural gases. Moscow: Nedra, 334 p. (in Russian).

Travnikova, L.G., & Astakhov, M.I. (1981). Isotope-geochemical characteristics of natural gases of the Dnieper-Pripyat oil-gas-bearing province. In: Origin and formation of natural gas composition according to isotopic geochemistry (pp. 83—104). Leningrad: VNIGRI (in Russian).

Fesenkov, V.G. (1949). Meteors and meteorites. Alma-Ata: Publishers of the Academy of Sciences of Kaz. SSR, 49 p. (in Russian).

Shestopalov, V.M. (2020). On geological hydrogen. Geofizicheskiy Zhurnal, 42(6), 3—35. https: //doi.org/10.24028/gzh.0203-3100.v42i6.2020222278 (in Russian).

Shestopalov, V.M., Lukin, A.E., Zgonnik, V.A., Makarenko, A.N., Larin, N.V., & Boguslavskiy, A.S. (2018). Essays on Earth Degassing. Kyiv, 632 p. (in Russian).

Yakutseni, V.P. (1968). Helium geology. Leningrad: Nedra, 232 p. (in Russian).

Briere, D., & Jerzykiewicz, T. (2016). On generating a geological model for hydrogen gas in the southern Taoudeni Megabasin (Bourakebougou area, Mali). International Conerence and Exhibition. Barcelona, Spain, 3—6 April 2016. 342 p. https://doi.org/10.1190/ice2016-6312821.1.

Gilat, A.L., & Vol, A. (2012). Degassing of primordial hydrogen and helium as the major energy source for internal terrestrial processes. Geoscience Frontiers, 3(6), 911—921. https://doi.org/10.1016/j.gsf.2012.03.009.

Keller, G., Adatte, T., Berner, Z., Harting, M., Baum, G., Prauss, M., & Stueben, D. (2007). Chicxulub impact predates K-T boundary: New evidence from Brazos, Texas. Earth and Planetary Science Letters, 255(3—4), 339—356. https://doi.org/10.1016/j.epsl.2006.12.026.

Keller, G., Mateo, P., Monkenbusch, J., Thibault, N., Punekar, J., Spangenberg, J.E., Abramovich, S., Ashckenazi-Polivoda, S., Schoene, B., Eddy, M.P., Samperton, K.M., Khadri, S.F.R., & Adatte, T. (2020). Mercury linked to Deccan Traps volcanism, climate change and the end-Cretaceous mass extinction. Global and Planetary Change, 194, 1—17. https://doi.org/10.1016/j.gloplacha.2020.103312.

Larin, N.V., Zgonnik, V., Rodina, S., Deville, E., Prinzhofer, A., & Larin, V.N. (2015). Natural molecular hydrogen seepage associated with surficial, rounded depressions on the European Craton in Russia. Natural Resources Research, 24, 369—38. https://doi.org/10.1007/s11053-014-9257-5.

Mateo, D., Keller, G., Adatte, T., Bitchong, A.M., Spangenberg, J.E., Vennemann, T., & Hollis, C.J. (2019). Deposition and age of Chicxulub impact spherules on Gorgonilla Island, Colombia. GSA Bulletin, 132, 215—232. https://doi.org/10.1130/b35287.1.

Prinzhofer, A., Cisse, C.S.T., & Diallo, A.B. (2018). Discovery of a large accumulation of natural hydrogen in Bourakebougou (Mali). International Journal of Hydrogen Energy, 43(42), 19315—19326. https://doi.org/10.1016/j.ijhydene.2018.08.193.

Sanders, D., Keller, G., Schlagintweit, F., & Studeny, M. (2019). Cretaceous-Paleocene transition along a rocky carbonate shore: Implications for the Cretaceous-Paleocene boundary event in shallow platform environments and correlation to the deep sea. In Mass Extinctions, Volcanism, and Impacts: New Developments (pp. 137—165). Geological Society of America. https://doi.org/10.1130/2019.2544(06).

Schoene, B., Eddy, M.P., Samperton, K.M., Keller, C.B., Keller, G., Adatte, T., & Khadri, S.F.R. (2019). U-Pb constraints on pulsed eruption of the Deccan Traps across the end-Cretaceous mass extinction. Science, 363, 862—866. https://doi.org/10.1126/science.aau2422.

Zgonnik, V. (2020). The occurrence and geoscience of natural hydrogen: a comprehensive review. Earth-Science Reviews, 203, 103140. https://doi.org/10.1016/j.earscirev.2020.103140.



How to Cite

Lukin, A. ., & Shestopalov, V. (2021). Tectono-magmatogenering structures in zones of increased geodynamic instability as priority objects for exploration of hydrogen fields. Geofizičeskij žurnal, 43(4), 3–41. https://doi.org/10.24028/gzh.v43i4.239953