Rheological behavor of kaoline water suspensions in presence of surfactants
DOI:
https://doi.org/10.15587/2312-8372.2013.12959Keywords:
kaolin, suspension, thixotropy, viscosity, surfactant, pseudoplasticity, dilatancy, adsorptionAbstract
Despite the great number of works devoted to the rheological behavior of kaolin water suspensions, there are no general guidelines for regulation of coagulation interaction with the addition of an effective concentration of various surfactants to the system, which can be adsorbed on the surface of a mineral. The article presents the study of interaction of kaolin with different surface activity and surfactants of anionic and nonionic types, which is of interest from both scientific and practical point of view, since it will permit to control the viscosity of compositions. It was found that the addition of an anionic surfactant to a suspension reduces the structure strength, and it occurs with a certain concentration. When the concentration is increased or decreased, the structural strength rises again, and in case of a nonionic surfactant, one can observe a monotonic decrease in the stability of structure. In future we will study the effect of stabilization of the modified kaolin suspensions to maximize the content of solid phase in dispersion while maintaining its sedimentation stability during transportation and processing.References
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- Lawrence, W.G. (1972). Ceramic Science for the Potter. 1st Edn., Canada: Chilton Book Company.
- Ryan, W. (1978). Properties of Ceramic Raw Materials. 2nd Edn., England: Pergamon Press.
- He, M. Wang, Y. and Forssberg, E. (2004). Slurry Rheology in WET Ultrafine Grinding of Industrial Minerals. Review, Powder Technology, 147, 94–112.
- Franco, F., Perez-Maqueda, L. A., and Perez-Rodríguez, J. L. (2004). The Effect of Ultrasound on the Particle Size and Structural Disorder of a Well-Ordered Kaolinite. Journal o Colloid and Interface Science, 274, 107–117.
- Tombácz, E. and Szekeres, M. (2004). Colloidal Behavior of Aqueous Montmorillonite Suspension: the Specific Role of pH in the Presence of Indifferent Electrolytes. Applied Clay Science, 27, 75–94.
- Yuan, J. and Hurray, H. H. (1997). The Importance of Crystal Morphology on the Viscosity of Concentrated Suspensions of Kaolinite. Applied Clay Science, 12, 209–219.
- Diz, H.M.M. and Rand, B. (1990). The Mechanism of Deflocculation of Kaolinite by Polyanions. British Ceramic Transaction Journal, 89, 77–82.
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- Williams, D. J. A. and Williams, K. P. (1982). Colloid Stability and Rheology of Kaolinite Suspensions. British Ceramic Transaction Journal, 81, 78–83.
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