Rheological behavor of kaoline water suspensions in presence of surfactants

Authors

  • Алексей Алексеевич Сикорский National Technical University of Ukraine “Kyiv Polytechnic Institute”, 37 Peremogy ave. Kyiv, Ukraine, 03056, Ukraine https://orcid.org/0000-0002-3730-2016
  • Алексей Владимирович Миронюк National Technical University of Ukraine “Kyiv Polytechnic Institute”, 37 Peremogy ave. Kyiv, Ukraine, 03056, Ukraine https://orcid.org/0000-0003-0499-9491
  • Валентин Анатольевич Свидерский National Technical University of Ukraine “Kyiv Polytechnic Institute”, 37 Peremogy ave. Kyiv, Ukraine, 03056, Ukraine https://orcid.org/0000-0002-4457-6875

DOI:

https://doi.org/10.15587/2312-8372.2013.12959

Keywords:

kaolin, suspension, thixotropy, viscosity, surfactant, pseudoplasticity, dilatancy, adsorption

Abstract

Despite the great number of works devoted to the rheological behavior of kaolin water suspensions, there are no general guidelines for regulation of coagulation interaction with the addition of an effective concentration of various surfactants to the system, which can be adsorbed on the surface of a mineral. The article presents the study of interaction of kaolin with different surface activity and surfactants of anionic and nonionic types, which is of interest from both scientific and practical point of view, since it will permit to control the viscosity of compositions. It was found that the addition of an anionic surfactant to a suspension reduces the structure strength, and it occurs with a certain concentration. When the concentration is increased or decreased, the structural strength rises again, and in case of a nonionic surfactant, one can observe a monotonic decrease in the stability of structure. In future we will study the effect of stabilization of the modified kaolin suspensions to maximize the content of solid phase in dispersion while maintaining its sedimentation stability during transportation and processing.

Author Biographies

Алексей Алексеевич Сикорский, National Technical University of Ukraine “Kyiv Polytechnic Institute”, 37 Peremogy ave. Kyiv, Ukraine, 03056

Graduate

The chair of polymer and composite materials

Алексей Владимирович Миронюк, National Technical University of Ukraine “Kyiv Polytechnic Institute”, 37 Peremogy ave. Kyiv, Ukraine, 03056

Ph.D., assistant

The chair of polymer and composite materials

Валентин Анатольевич Свидерский, National Technical University of Ukraine “Kyiv Polytechnic Institute”, 37 Peremogy ave. Kyiv, Ukraine, 03056

Doctor of Technical Sciences, Professor

The chair of polymer and composite materials

References

  1. Konta, J. Clay and Man: Clay Raw Materials in the Service of Man [Text] / J. Konta. – Applied Clay Science. – 1995. – Vol. 10. – pp. 275–335.
  2. Lawrence, W. G. Ceramic Science for the Potter [Text] / W. G. Lawrence. – 1st Edn., Canada: Chilton Book Company. – 1972.
  3. Ryan, W. Properties of Ceramic Raw Materials [Text] / W. Ryan. – 2nd Edn., England: Pergamon Press. – 1978.
  4. He, M. Slurry Rheology in WET Ultrafine Grinding of Industrial Minerals [Text] / M. He, Y. Wang, and E. Forssberg // Review, Powder Technology. – 2004. – Vol. 147. – pp. 94–112.
  5. Franco, F. The Effect of Ultrasound on the Particle Size and Structural Disorder of a Well-Ordered Kaolinite [Text] / F. Franco, L. A. Perez-Maqueda, and J. L. Perez-Rodríguez // Journal o Colloid and Interface Science. – 2004. – Vol. 274. – pp. 107–117.
  6. Tombácz, E. Colloidal Behavior of Aqueous Montmorillonite Suspension: the Specific Role of pH in the Presence of Indifferent Electrolytes [Text] / E. Tombácz, and M. Szekeres // Applied Clay Science. – 2004. – Vol. 27. – pp. 75–94.
  7. Yuan, J. The Importance of Crystal Morphology on the Viscosity of Concentrated Suspensions of Kaolinite [Text] / J. Yuan, and H. H. Hurray // Applied Clay Science. – 1997. – Vol. 12. – pp. 209–219.
  8. Diz, H.M.M. The Mechanism of Deflocculation of Kaolinite by Polyanions [Text] / H. M. M. Diz and B. Rand // British Ceramic Transaction Journal. – 1990. – Vol. 89. – pp. 77–82.
  9. Ryan, W. White wares: Production, Testing and Quality Control [Text] / W. Ryan and C. Radford // 2nd. Edn., England. – The Institute of Materials. – 1997.
  10. Williams, D. J. A. Colloid Stability and Rheology of Kaolinite Suspensions [Text] / D. J. A. Williams and K. P. Williams // British Ceramic Transaction Journal. – 1982. – Vol. 81. – pp. 78–83.
  11. Konta, J. (1995). Clay and Man: Clay Raw Materials in the Service of Man. Applied Clay Science, 10, 275–335.
  12. Lawrence, W.G. (1972). Ceramic Science for the Potter. 1st Edn., Canada: Chilton Book Company.
  13. Ryan, W. (1978). Properties of Ceramic Raw Materials. 2nd Edn., England: Pergamon Press.
  14. He, M. Wang, Y. and Forssberg, E. (2004). Slurry Rheology in WET Ultrafine Grinding of Industrial Minerals. Review, Powder Technology, 147, 94–112.
  15. Franco, F., Perez-Maqueda, L. A., and Perez-Rodríguez, J. L. (2004). The Effect of Ultrasound on the Particle Size and Structural Disorder of a Well-Ordered Kaolinite. Journal o Colloid and Interface Science, 274, 107–117.
  16. Tombácz, E. and Szekeres, M. (2004). Colloidal Behavior of Aqueous Montmorillonite Suspension: the Specific Role of pH in the Presence of Indifferent Electrolytes. Applied Clay Science, 27, 75–94.
  17. Yuan, J. and Hurray, H. H. (1997). The Importance of Crystal Morphology on the Viscosity of Concentrated Suspensions of Kaolinite. Applied Clay Science, 12, 209–219.
  18. Diz, H.M.M. and Rand, B. (1990). The Mechanism of Deflocculation of Kaolinite by Polyanions. British Ceramic Transaction Journal, 89, 77–82.
  19. Ryan, W. and Radford, C. (1997). White wares: Production, Testing and Quality Control. 2nd. Edn., England, The Institute of Materials.
  20. Williams, D. J. A. and Williams, K. P. (1982). Colloid Stability and Rheology of Kaolinite Suspensions. British Ceramic Transaction Journal, 81, 78–83.

Published

2013-03-29

How to Cite

Сикорский, А. А., Миронюк, А. В., & Свидерский, В. А. (2013). Rheological behavor of kaoline water suspensions in presence of surfactants. Technology Audit and Production Reserves, 2(1(10), 45–48. https://doi.org/10.15587/2312-8372.2013.12959