Products composition catalytic cracking via aerosol nanocatalysis for modified Si/Zr- catalyst

Authors

  • Сергей Александрович Кудрявцев Volodymyr Dahl East Ukrainian National University Soviet Ave, 59a, Severodonetsk, Luhansk region., 93400, Ukraine
  • Марат Аронович Гликин Volodymyr Dahl East Ukrainian National University, Soviet Ave, 59a, Severodonetsk, Luhansk region., 93400, Ukraine
  • Али Хашим Магди Ministry of Science and Technology from republic of Iraq, Baghdad, Iraq
  • Хабиб Алсуз Амер Volodymyr Dahl East Ukrainian National University, Soviet Ave, 59a, Severodonetsk, Luhansk region., 93400, Ukraine

DOI:

https://doi.org/10.15587/2312-8372.2013.19500

Keywords:

catalytic cracking, aerosol nanocatalysis, mechanochemical activation of catalyst

Abstract

The analysis of experimental studies of the process of catalytic cracking of vacuum gasoil in conditions of the aerosol nanocatalysis technology for a new sample of the Si/Zr-catalyst is given. The influence of the process temperature and the frequency of mechanochemical activation (MCA) of the catalyst on the yield of cracking products - gasoline and diesel fractions is determined. The process of catalytic cracking of vacuum gasoil in the investigated conditions proceeds with high light-products selectivity and primary formation of the diesel fraction (DF). The maximum yield of the DF was 60%. The frequency of MCA of 6 Hz leads to the maximum of the formation of the gasoline fraction (GF) at temperatures of 350, 400, 450, 5000C and the frequency of 6.5 Hz is optimal for the maximum obtaining of the product with a maximum of 300 and 5500C. The temperature of the beginning of the catalytic reaction is determined. The temperature of ignition of the studied sample of the Si/Zr-catalyst in conditions of AnC was 3500C and at the increase of the frequency of MCA decreased to 3000C.

Author Biographies

Сергей Александрович Кудрявцев, Volodymyr Dahl East Ukrainian National University Soviet Ave, 59a, Severodonetsk, Luhansk region., 93400

PhD

Department of Technology of organic substances, fuels and polymers

Марат Аронович Гликин, Volodymyr Dahl East Ukrainian National University, Soviet Ave, 59a, Severodonetsk, Luhansk region., 93400

Doctor of Technical Sciences, Professor

Head of Department of Technology of organic substances, fuels and polymers

Али Хашим Магди, Ministry of Science and Technology from republic of Iraq, Baghdad

Bch Chemical Engineer Designs,

Circle of Renewable Energy

Department of Energy designs

Хабиб Алсуз Амер, Volodymyr Dahl East Ukrainian National University, Soviet Ave, 59a, Severodonetsk, Luhansk region., 93400

Department of Technology of organic substances, fuels and polymers

References

  1. Ющенко, Н. Л. Философия крекинга [Текст] / Н. Л. Ющенко // Нефтепереработка и нефтехимия. – 2001. – № 11. – С. 3-6.
  2. Гликин, М. А. Осуществление различных процессов переработки нефти аэрозольным нанокатализом [Текст]: материалы открытой школы-конференции стран СНГ "Ультрамелкозернистые и наноструктурные материалы", 4-9 августа 2008, г. Москва / М. А. Гликин, И. М. Гликина, С. А. Кудрявцев // Перспективные материалы. – 2009. – № 7. – С. 24-29.
  3. Decroocq, D. Major Scientific and technical challenges about development of new processes in refining and petrochemistry [Text] / D. Decroocq // Revue de Institut Francais du petrole. – 1997. – Vol. 52, № 5. – P. 469-489.
  4. Glikin, M. A. Specific control parameters in the technology of aerosol nanocatalysis [Text] / M. A. Glikin, I. M. Glikina, S. A. Kudryavtsev // ANNALES Universitatis Mariae Curie-Sklodowska, sectio AA CHEMIA. – 2009. – Vol. LXIV. – P. 218-226.
  5. Гликина, И. М. Исследование каталитической активности Si/Zr катализатора в условиях аэрозольного нанокатализа в виброожиженном слое. [Текст]: материалы VII Международной конференции "Стратегия качества в промышленности и образовании", 3-10 июня 2011, г. Варна (Болгария) / И. М. Гликина, С. А. Кудрявцев, А. С. Кащеев. – В 3-ех томах, Т. 3. – С. 63-67.
  6. Glikin, M. A. Investigations and Applications of Aerosol Nano-catalysis in a Vibrofluidized (Vibrating) Bed. [Text] / M. A. Glikin, I. M. Glikina, E. Kauffeldt // Adsorption Science&Technology. – 2005. – Vol. 23, No.2. – P. 135-143.
  7. Glikin, M. А. Conversion of natural gas in the process of steam reforming via aerosol nanocatalysis technology [Text] / M. А. Glikin, S. А. Kudryavtsev, S. М. А. Mahmmod // Journal of Chemical Technology (Kaunas university of technology, Lithuania). – 2012. – Vol. 159, № 1.– P. 5-12.
  8. Кащеев, А. С. Процесс крекинга вакуумного газойля в условиях аєрозольного нанокатализа. Исследование поведения Si/Zr катализатора. [Текст] / М. А. Гликин, И. М. Гликина, Б. Б. Мамедов, А. С. Кащеев, С. А. Кудрявцев // Хімічна промисловість України. – 2012. – №1. – С. 16-22.
  9. Glikin, M. А. A new way to increase catalytic activity [Text] / M. A. Glikin, D. A. Kutakova, I. M. Glikina, A. I. Volga // Adsorption science and technology. – 2001. – V. 19, N. 2. – P. 101-111.
  10. Ахметов, С. А. Технология глубокой переработки нефти и газа [Текст] учеб. пос. для вузов / С. А. Ахметов. – Уфа: Гилем, 2002. – 672 с.
  11. Yuschenko, N. L. (2001). Philosophy cracking. Refining and Petrochemicals, №11, 3-6.
  12. Glikin, M. A., Glikina, I. M., Kudryavtsev, S. A. (2009). Implementation of various refining processes aerosol nanokatalizom: Materials school conference of CIS countries "Ultrafine and Nanostructured Materials", August 4-9, 2008 Moscow. Advanced Materials, № 7, 24-29.
  13. Decroocq, D. (1997). Major Scientific and technical challenges about development of new processes in refining and petrochemistry. Revue de Institut Francais du petrole, Vol. 52, № 5, 469-489.
  14. Glikin, M. A., Glikina, I. M., Kudryavtsev, S. A. (2009). Specific control parameters in the technology of aerosol nanocatalysis. ANNALES Universitatis Mariae Curie-Sklodowska, sectio AA CHEMIA, Vol. LXIV, 218-226
  15. Glikina, I. M., Kudryavtsev, S. A., Kascheev, A. S. (2011). Study catalytic activity Si/Zr catalyst under a spray nanokataliza vibroozhizhennom layer. Proceedings of the VII International Conference "Quality Strategy in industry and education", 3-10 June 2011, Varna (Bulgaria), Vol. 3, 63-67
  16. Glikin, M. A., Glikina, I. M., Kauffeldt, E. M. (2005). Investigations and Applications of Aerosol Nano-catalysis in a Vibrofluidized (Vibrating) Bed. Adsorption Science&Technology, Vol. 23, No.2, 135-143.
  17. Glikin, M. А., Kudryavtsev, S. А., Mahmmod, S. М. А. (2012). Conversion of natural gas in the process of steam reforming via aerosol nanocatalysis technology. Journal of Chemical Technology (Kaunas university of technology, Lithuania), Vol. 159, № 1, 5-12.
  18. Glikin, M. A., Glikina, I. M., Kascheev, A. S., Mamedov, B. B., Kudryavtsev, S. A. (2012). The process of cracking of vacuum gas oil by aerosol nanocatalysis. Study the behavior of Si/Zr catalyst. Chemical Industry of Ukraine, №1, 16-22.
  19. Glikin, M. A., Kutakova, D. A., Glikina, I. M., Volga, A. I. (2001). A new way to increase catalytic activity. Adsorption science and technology, v. 19, N. 2, 101-111.
  20. Ahmetov, S. A. (2002). Technology of deep processing of oil and gas. Textbook for universities. Ufa: Guillem, 672.

Downloads

Published

2013-11-28

How to Cite

Кудрявцев, С. А., Гликин, М. А., Магди, А. Х., & Амер, Х. А. (2013). Products composition catalytic cracking via aerosol nanocatalysis for modified Si/Zr- catalyst. Technology Audit and Production Reserves, 6(2(14), 16–18. https://doi.org/10.15587/2312-8372.2013.19500

Issue

Vol. 6 No. 2(14) (2013): Production reserves

Section

Production reserves

License

Copyright (c) 2016 Сергей Александрович Кудрявцев, Марат Аронович Гликин, Али Хашим Магди, Хабиб Алсуз Амер

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

The consolidation and conditions for the transfer of copyright (identification of authorship) is carried out in the License Agreement. In particular, the authors reserve the right to the authorship of their manuscript and transfer the first publication of this work to the journal under the terms of the Creative Commons CC BY license. At the same time, they have the right to conclude on their own additional agreements concerning the non-exclusive distribution of the work in the form in which it was published by this journal, but provided that the link to the first publication of the article in this journal is preserved.