Study of the extraction kinetics of flavonoids from the fruits of Sophora japonica L. with sunflower oil
DOI:
https://doi.org/10.15587/2706-5448.2024.312703Keywords:
Sophora japonica L., sunflower oil, extraction, flavonoids, biologically active substances, kinetics, temperature, hydromoduleAbstract
Among the large number of biologically active substances contained in the fruits of Sophora japonica L., the extraction of flavonoids, substances of medium polarity, is particularly important. The process of extracting them with vegetable oil from fruits is quite complicated. The object of research is the kinetics of the process of extracting flavonoids from Sophora japonica L. fruits with sunflower oil. The influence of temperature, duration, and hydraulic modulus on the extraction process, as well as on the derivation of the equation of the mathematical model, is studied.
Mathematical modeling methods are used in the research. Processing of experimental data for the study of extraction kinetics in the vegetable oil:vegetable raw material system is carried out using the Statistica statistical package. In order to derive the equation of the mathematical model of the process of extracting flavonoids from Sophora japonica L. with sunflower oil, the influence of temperature, duration and hydromodulus on the process of transition of the target component – flavonoids to the extract – is investigated. A mathematical model of the dependence of flavonoids on the hydromodulus (H=10–25), temperature (t=25–45 °С) and the duration of the extraction process of Sophora japonica L. (τ=2–10 h) is obtained, which makes it possible to calculate the content of flavonoids with an average relative with an error within 5 %.
On the basis of the conducted experimental studies, basic technological schemes for obtaining unrefined sunflower oil of increased biological value are developed, which includes the following stages: preparation of raw materials, treatment of prepared raw materials with sunflower oil during dilution and mixing, separation of oil from raw materials by filtering. The proposed technology is promising, as its implementation is possible not only in food industry enterprises, but also in restaurant establishments, as it does not require expensive equipment, additional production premises and special training of personnel.
The mathematical models of the extraction process of Sophora japonica L. with unrefined sunflower oil proposed in the work allow to select the extraction parameters with a high degree of probability and offer the consumer flavonoid-enriched sunflower oil of increased biological value.
References
- Shylman, L. Z., Simakova, I. V. et al.; Shylman, L. Z. (Ed.) (2016). Zhyry u vyrobnytstvi kharchovoi produktsii. Sumy: Universytetska knyha, 278.
- Oseiko, M. I. (2006). Tekhnolohiia roslynnykh olii. Kyiv: Varta, 280.
- Hyrych, S. V., Loianich, H. S. (2018). Suchasni pohliady na spozhyvni perevahy ta problemy bezpeky roslynnykh olii. Intelekt XXI, 5, 37–41.
- Bielinska, A. P. (2011). Tekhnolohiia kupazhovanoi olii pidvyshchenoi biolohichnoi tsinnosti. PhD Dissertation.
- Demydova, A. O., Shemanska, Ye. I., Shulha, Ye. M. (2016). Doslidzhennia kharakterystyk ta okysliuvalnoi stabilnosti ryzhiievoi olii z nastupnym kupazhuvanniam. Visnyk NTU «KhPI», 19 (1191), 70–74.
- Radziievska, I. H., Kot, T. O. (2012). Doslidzhennia stabilnosti kupazhovanykh olii u protsesi yikh zberihannia. Kharchova nauka i tekhnolohiia, 1 (18), 70–72.
- Matvieieva, T. V. (2014). Kupazhi olii – dzherelo polinenasychenykh zhyrnykh kyslot. Naukovi pratsi ONAKhT, 2 (46), 210–213.
- Hulevata, M. A., Savchuk, Yu. Yu., Usatiuk, S. I. (2014). Zbalansuvannia zhyrnokyslotnoho skladu soniashnykovoi olii. Tekhnichni nauky: stan, dosiahnennia i perspektyvy rozvytku miasnoi, oliie-zhyrovoi ta molochnoi haluzei, 149–150.
- Bielinska, A. P. (2009). Oliini sumishi yak zbalansovanyi za skladom ta stabilnyi do okysliuvannia produkt. Naukovi zdobutky molodi – vyrishenniu problem kharchuvannia liudstva u XX stolitti. Kyiv: NUKhT, 106.
- Rzhontsov, M. M., Serdiuk, M. O. (2005). Pat. No. 7569 UA. Salatna oliia, zbahachena biolohichno aktyvnymy rechovynamy. MPK (2006) A23D 9/00. No. u200502977; declareted: 31.03.2005; published: 15.06.2005, Bul. No. 6.
- Topchii, O. A., Kotliar, Ye. O., Kyshenko, I. I. (2014). Kharakterystyka vitaminizovanykh kupazhiv roslynnykh olii. Kharchova nauka i tekhnolohiia, 4 (29), 93–97.
- Korshunova, H. F., Hlytsevych, V. A., Petrenko, T. V., Ildirova, S. K., Pohrebniak, V. H. (2000). Pat. No. 30754 UA. Vitaminizovana soniashnykova oliia. MPK (2006) C11B 5/00. No. 98052250; declareted: 29.12.1999; published: 15.12.2000, Bul. No. 7.
- Demydov, I. M., Demydova, A. O., Peshuk, L. S. (2010). Doslidzhennia mekhanizmu antyoksydantnoho vplyvu soniashnykovoho fosfatydnoho kontsentratu na okysnennia soniashnykovoi olii. Kharchova promyslovist, 9, 7–10.
- Wagner, K.-H., Elmadfa, I. (2000). Effects of tocopherols and their mixtures on the oxidative stability of olive oil and linseed oil under heating. European Journal of Lipid Science and Technology, 102 (10), 624–629. https://doi.org/10.1002/1438-9312(200010)102:10<624::aid-ejlt624>3.0.co;2-i
- Beddows, C. G., Jagait, C., Kelly, M. J. (2001). Effect of ascorbyl palmitate on the preservation of α-tocopherol in sunflower oil, alone and with herbs and spices. Food Chemistry, 73 (3), 255–261. https://doi.org/10.1016/s0308-8146(00)00295-8
- Ghasemifard, N., Hassanzadeh-Rostami, Z., Abbasi, A., Naghavi, A. M., Faghih, S. (2022). Effects of vitamin D-fortified oil intake versus vitamin D supplementation on vitamin D status and bone turnover factors: A double blind randomized clinical trial. Clinical Nutrition ESPEN, 47, 28–35. https://doi.org/10.1016/j.clnesp.2021.12.025
- Silva, F. A. M., Borges, F., Ferreira, M. A. (2001). Effects of Phenolic Propyl Esters on the Oxidative Stability of Refined Sunflower Oil. Journal of Agricultural and Food Chemistry, 49 (8), 3936–3941. https://doi.org/10.1021/jf010193p
- Kamkar, A., Javan, A. J., Asadi, F., Kamalinejad, M. (2010). The antioxidative effect of Iranian Mentha pulegium extracts and essential oil in sunflower oil. Food and Chemical Toxicology, 48 (7), 1796–1800. https://doi.org/10.1016/j.fct.2010.04.003
- Özcan, M. M., Arslan, D. (2011). Antioxidant effect of essential oils of rosemary, clove and cinnamon on hazelnut and poppy oils. Food Chemistry, 129 (1), 171–174. https://doi.org/10.1016/j.foodchem.2011.01.055
- Dubinina, A. A., Lenert, S. O., Khomenko, O. O. (2014). Oxidation stabilization of peanut-linen blend lipids. Technology Audit and Production Reserves, 4 (2 (18)), 10–14. https://doi.org/10.15587/2312-8372.2014.26401
- Beddows, C. G., Jagait, C., Kelly, M. J. (2001). Effect of ascorbyl palmitate on the preservation of α-tocopherol in sunflower oil, alone and with herbs and spices. Food Chemistry, 73 (3), 255–261. https://doi.org/10.1016/s0308-8146(00)00295-8
- Drahoniuk, O. A., Drahoniuk, M. A., Marushko, L. P. (2012). Antyoksydantna diia ekstraktiv likarskykh roslyn rodyny Lamiaceae na stabilnist olii soniashnykovoi v protsesi zberihannia. Naukovyi visnyk Volynskoho natsionalnoho universytetu imeni Lesi Ukrainky, 17, 127–132.
- Iqbal, S., Haleem, S., Akhtar, M., Zia-ul-Haq, M., Akbar, J. (2008). Efficiency of pomegranate peel extracts in stabilization of sunflower oil under accelerated conditions. Food Research International, 41 (2), 194–200. https://doi.org/10.1016/j.foodres.2007.11.005
- Labeiko, M. A., Matvieieva, T. V., Mazaieva, V. S., Fediakina, Z. P. (2023). Vlastyvosti oliinykh ekstraktiv prianykh trav. Innovatsiini tekhnolohii: Aktualni pytannia nauky ta praktyky, 7, 12–18.
- Vasylenko, O. M., Mirkushova, L. V., Fediakina, Z. P. (2004). Pat. No. 50980 UA. Salatna oliia z priano-aromatychnymy domishkamy (varianty). MPK (2006) A23D 9/00. declareted: 01.11.2001; published: 15.07.2004, Bul. No. 7.
- Korshunova, H. F., Petrenko, T. V., Ildirova, S. K. et al. (2000). Pat. No. 28571 UA. Sposib stabilizatsii soniashnykovoi olii do okyslennia. No. 97073487. declareted: 02.07.1997; published: 16.10.2000, Bul. No. 5, 3.
- Kamsulina, N. V. (2002). Tekhnolohiia roslynnoi olii, zbahachenoi karotynoidamy morkvy, ta yii vykorystannia pry vyrobnytstvi produktiv kharchuvannia. Extended abstract of PhD thesis; Kharkivskyi derzh. un-t kharch. ta torhivli.
- Iehorov, B. V., Mohylianska, N. O. (2014). Otsinka sanitarnykh pokaznykiv priano-aromatychnoi syrovyny ta priano-oliinykh sumishei. Kharchova nauka i tekhnolohiia, 2, 34–38.
- Mazaieva, V. S., Sytnik, N. S., Fediakina, Z. P. (2023). Vyvchennia okysliuvalnoi stabilnosti oliinykh ekstraktiv z riznoiu priano-aromatychnoiu syrovynoiu. Problemy ta dosiahnennia suchasnoi biotekhnolohii. Kharkiv, 256–257.
- Cherevko, O. I., Yancheva, M. O., Yurchenko, O. I., Annienko, S. V., Maksymenko, H. I. (2019). Pat. No. 134635 UA. Sposib zbahachennia soniashnykovoi olii biolohichno aktyvnymy komponentamy roslynnoi syrovyny. MPK A23D 9/02 (2006.01); No. u201813041. declareted: 28.12.2018; published: 27.05.2019, Bul. No. 10.
- Fedoryshyn, O. M. (2021). Mekhanizm ta kinetyka ekstrahuvannia biolohichno aktyvnykh rechovyn z roslynnoi syrovyny. Doctoral dissertation. Natsionalnyi universytet «Lvivska politekhnika».
- Pelekhova, L. S., Usatiuk, S. I., Koroliuk, T. A. (2012). Perspektyvy vykorystannia sofory yaponskoi dlia zbahachennia oliiezhyrovykh produktiv. Tekhnichni nauky: stan, dosiahnennia i perspektyvy rozvytku miasnoi, oliiezhyrovoi ta molochnoi haluzei. Kyiv: NUKhT, 100.
- Usatiuk, S. I., Pelekhova, L. S., Usatiuk, O. M. (2012). Perspektyvy vykorystannia sofory yaponskoi yak dzherela antyoksydantiv v oliino-zhyrovii haluzi kharchovoi promyslovosti. Naukovi pratsi ONAKhT, 1 (42), 351–354.
- Cholak, I. S. (2010). Novi biolohichno aktyvi spoluky v syrovyni sofory yaponskoi (SOPHORA JAPONICA L.) ta yikh biolohichna aktyvnist (ohliad literatury). Fitoterapiia. Chasopys, 4, 79–82.
- Wang, J.-H., Lou, F.-C., Wang, Y.-L., Tang, Y.-P. (2003). A flavonol tetraglycoside from Sophora japonica seeds. Phytochemistry, 63 (4), 463–465. https://doi.org/10.1016/s0031-9422(02)00757-4
- Szydlowskaczerniak, A., Dianoczki, C., Recseg, K., Karlovits, G., Szlyk, E. (2008). Determination of antioxidant capacities of vegetable oils by ferric-ion spectrophotometric methods. Talanta, 76 (4), 899–905. https://doi.org/10.1016/j.talanta.2008.04.055
- Sailova, D. D. (1996). Doslidzhennia i kompleksne vykorystannia sofory yaponskoi. Extended abstract of PhD thesis.
- Usatiuk, S. Y., Pelekhova, L. S., Usatiuk, E. M. (2015). Yssledovanye protsessa ekstrahyrovanyia proyzvodnikh khlorofylla yz petrushky kudriavoi. Vestnyk Almatynskoho tekhnolohycheskoho unyversyteta, 1 (106), 16–20.
- Pelekhova, L. S., Usatiuk, S. I. (2013). Doslidzhennia bakteriostatychnykh vlastyvostei soniashnykovoi olii, obroblenoi soforoiu yaponskoiu. Tekhnichni nauky: stan, dosiahnennia i perspektyvy rozvytku miasnoi, oliiezhyrovoi ta molochnoi haluzei. Kyiv: NUKhT, 165.
- Usatiuk, S. I., Pelekhova, L. C. (2011). Tekhnolohiia otrymannia oliinoho ekstraktu z sofory yaponskoi yak dzherela biolohichno aktyvnykh rechovyn. Suchasni tekhnolohii ta obladnannia kharchovykh vyrobnytstv. Ternopilskyi natsionalnyi tekhnichnyi universytet imeni Ivana Puliuia.
- Usatiuk, S. I., Pelekhova, L. S., Sus, L. V. (2012). Vyznachennia pokaznykiv yakosti ta bezpeky soniashnykovoi olii z pidvyshchenoiu stiikistiu do okysnennia. Ukrainian Food Journal, 1, 55–57.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2024 Liubov Pelekhova, Svitlana Usatiuk, Olena Tyshchenko, Viacheslav Honcharov
This work is licensed under a Creative Commons Attribution 4.0 International License.
The consolidation and conditions for the transfer of copyright (identification of authorship) is carried out in the License Agreement. In particular, the authors reserve the right to the authorship of their manuscript and transfer the first publication of this work to the journal under the terms of the Creative Commons CC BY license. At the same time, they have the right to conclude on their own additional agreements concerning the non-exclusive distribution of the work in the form in which it was published by this journal, but provided that the link to the first publication of the article in this journal is preserved.