Research of methanol content in technological flows of facilities that process gas preparation by low-temperature separation method

Authors

DOI:

https://doi.org/10.15587/2706-5448.2024.318926

Keywords:

natural gas, associated formation water, inhibitor, gas hydrates, computer modeling

Abstract

The object of research is methanol as an inhibitor, which is used in the process of collecting and preparing products from gas, gas condensate, and oil fields to protect against hydrate formations. It is important to ensure the rational consumption of this inhibitor, taking into account its solubility in gas, water, and liquid hydrocarbons. This work is aimed at analyzing the use of the methanol hydrate formation inhibitor in the process of low-temperature gas preparation and determining ways to use it more effectively.

The work presents the results of modeling the distribution of the hydrate formation inhibitor along the technological flows of low-temperature gas separation units according to the following schemes:

– low-temperature separation with gas cooling due to the Joule-Thompson effect;

– compression of gas from wells using PCS (pressure compressor station) + low-temperature separation with gas cooling due to the Joule-Thompson effect;

– compression of gas from wells using PCS + low-temperature separation with gas cooling due to the operation of a turboexpander unit;

– compression of gas from wells using PCS + low-temperature separation with gas cooling due to the operation of an artificial refrigeration unit (propane refrigeration unit).

The use of a computer simulator allowed to track in detail the distribution of methanol during the gas preparation process. The iteration method determined the minimum values of methanol consumption at which the hydrate-free operation mode of the equipment is maintained. Based on the modeling results, an analysis of methanol content in technological flows was performed. And the patterns of inhibitor separation in the separation equipment were also determined, namely, the dependence of methanol distribution on gas pressure in separators, and the methanol content in the output lines of gas preparation units.

It was established that the results of the study can be applied in the development of technologies for the collection, regeneration and reuse of methanol in technological processes of low-temperature gas preparation. The practical value of the results lies in the possibility of improving typical methods of protecting equipment from hydrate formations by developing an automated inhibitor supply system that, by monitoring the parameters of the technological process, changes the inhibitor dosage and ensures its economical use.

Author Biographies

Viktoriia Dmytrenko, National University “Yuri Kondratyuk Poltava Polytechnic”

PhD, Associate Professor

Department of Oil and Gas Engineering and Technology

Taras Podoliak, National University “Yuri Kondratyuk Poltava Polytechnic”

PhD Student

Department of Oil and Gas Engineering and Technology

References

  1. Carrol, J. (2020). Natural Gas Hydrates A Guide for Engineers. Elsevier, 184–208. https://doi.org/10.1016/c2019-0-04277-x
  2. Hu, P., Ke, W., Chen, D. (2022). Molecular Dynamics Simulation of Methane Hydrate Formation on Pipeline Surface in the Presence of Corrosion Inhibitors. Energy & Fuels, 37 (1), 301–309. https://doi.org/10.1021/acs.energyfuels.2c03337
  3. Samie, N. N. (2016). Systems and Equipment for Offshore Platform Design. Practical Engineering Management of Offshore Oil and Gas Platforms. Cambridge: Gulf Professional Publishing, 213–346. https://doi.org/10.1016/b978-0-12-809331-3.00003-x
  4. Makwashi, N., Ahmed, T. G. (2021). Gas Hydrate Formation: Impact on Oil and Gas Production and Prevention Strategies. Nigerian Research Journal of Engineering and Environmental Sciences, 6 (1), 61–75. https://doi.org/10.5281/zenodo.5047631
  5. Micucci, L., Nigi, S. (2021). Natural gas liquids extraction and separation. Gas Processing & LNG, 1/1/2021. Available at: http://gasprocessingnews.com/articles/2021/02/natural-gas-liquids-extraction-and-separation/
  6. Zhao, J., Lang, C., Chu, J., Yang, L., Zhang, L. (2023). Flow Assurance of Hydrate Risk in Natural Gas/Oil Transportation: State-of-the-Art and Future Challenges. The Journal of Physical Chemistry C, 127 (28), 13439–13450. https://doi.org/10.1021/acs.jpcc.3c02134
  7. Dmytrenko, V. I., Zezekalo, I. G., Vynnykov, Y. L. (2022). The use of bischofite in the gas industry as an inhibitor of hydrate formation. IOP Conference Series: Earth and Environmental Science, 1049 (1), 012052. https://doi.org/10.1088/1755-1315/1049/1/012052
  8. Dmytrenko, V., Zezekalo, I., Vynnykov, Y., Manhura, A. (2021). Efficiency evaluation of using highly mineralized reservoir waters for preventing hydrate formation of natural gas in the conditions of Zakhidno-Radchenkivske gas-condensate field. IOP Conference Series: Earth and Environmental Science, 628 (1), 012015. https://doi.org/10.1088/1755-1315/628/1/012015
  9. Marsetyo, M. M., Suranto, Herianto, Ratnaningsih, D. R., Kristanto, D. (2023). Study of hydrate formation due to the Joule Thomson effect and optimization of methanol (MeOH) injection as a hydrate prevention method. 4TH International Conference on Earth Science, Mineral and Energy, 2598, 030012. https://doi.org/10.1063/5.0126565
  10. Teixeira, A. M., Arinelli, L. de O., de Medeiros, J. L., Araújo, O. de Q. F. (2018). Recovery of thermodynamic hydrate inhibitors methanol, ethanol and MEG with supersonic separators in offshore natural gas processing. Journal of Natural Gas Science and Engineering, 52, 166–186. https://doi.org/10.1016/j.jngse.2018.01.038
  11. Lauricella, M., Ghaani, M. R., Nandi, P. K., Meloni, S., Kvamme, B., English, N. J. (2022). Double Life of Methanol: Experimental Studies and Nonequilibrium Molecular-Dynamics Simulation of Methanol Effects on Methane-Hydrate Nucleation. The Journal of Physical Chemistry C, 126 (13), 6075–6081. https://doi.org/10.1021/acs.jpcc.2c00329
  12. Pandey, J., Khan, S., von Solms, N. (2022). Screening of Low-Dosage Methanol as a Hydrate Promoter. Energies, 15 (18), 6814. https://doi.org/10.3390/en15186814
  13. Sloan Jr., E. D., Koh, C. A., Koh, C. A. (2007). Clathrate Hydrates of Natural Gases. CRC Press. https://doi.org/10.1201/9781420008494
  14. Hammerschmidt, E. G. (1934). Formation of Gas Hydrates in Natural Gas Transmission Lines. Industrial & Engineering Chemistry, 26 (8), 851–855. https://doi.org/10.1021/ie50296a010
  15. Dmytrenko, V. (2009). The influence of surfactants on the conditions of propane hydrate formation. Chemistry and Modern Technologies. Dnipropetrovsk: UDCTU, 43.
  16. Trevor, R. (2019). Oil and Gas Field Application of Hydrate Kinetics Modeling. Memorial University of Newfoundland. Available at: https://books.google.com.ua/books/about/Oil_and_Gas_Field_Application_of_Hydrate.html?id=ayQxzwEACAAJ&redir_esc=y
  17. Rebai, N., Hadjadj, A., Benmounah, A., Berrouk, A. S., Boualleg, S. M. (2019). Prediction of natural gas hydrates formation using a combination of thermodynamic and neural network modeling. Journal of Petroleum Science and Engineering, 182, 106270. https://doi.org/10.1016/j.petrol.2019.106270
  18. Bozorgian, A. (2020). Methods of Predicting Hydrates Formation. Advanced Journal of Science and Engineering, 1 (2), 34–39.
  19. Toyin Olabisi, O., Chukwuemeka Emmanuel, U. (2019). Simulation of Laboratory Hydrate Loop Using Aspen Hysys. Engineering and Applied Sciences, 4 (3), 52–58. https://doi.org/10.11648/j.eas.20190403.11
  20. Kaiser, M. J. (2020). The Offshore Pipeline Construction Industry Activity Modeling and Cost Estimation in the U.S Gulf of Mexico. Elsevier. https://doi.org/10.1016/c2019-0-01414-8
  21. Mokhatab, S., Poe, W. A., Mak, J. Y. (2019). Handbook of Natural Gas Transmission and Processing. Principles and Practices. Elsevier, 133–152. https://doi.org/10.1016/c2017-0-03889-2
  22. Johannes Fink (2021). Petroleum Engineer's Guide to Oil Field Chemicals and Fluids Third Edition. Elsevier. https://doi.org/10.1016/c2020-0-02705-2
  23. Kidnay, A. J., Parrish, W. R., McCartney, D. G. (2019). Fundamentals of Natural Gas Processing. Kidnay: CRC Press, 172–178. https://doi.org/10.1201/9780429464942
  24. Bavoh, C. B., Nashed, O., Rehman, A. N., Othaman, N. A. A. B., Lal, B., Sabil, K. M. (2021). Ionic Liquids as Gas Hydrate Thermodynamic Inhibitors. Industrial & Engineering Chemistry Research, 60 (44), 15835–15873. https://doi.org/10.1021/acs.iecr.1c01401
  25. Dubey, S., Gurjar, P., Kumar, U., Sahai, M., Kumar, S., Kumar, A. (2023). Elucidating the Impact of Thermodynamic Hydrate Inhibitors and Kinetic Hydrate Inhibitors on a Complex System of Natural Gas Hydrates: Application in Flow Assurance. Energy & Fuels, 37 (9), 6533–6544. https://doi.org/10.1021/acs.energyfuels.3c00430
  26. Abidin, M. Z. Z., Aman, Z. M., May, E. F., Johns, M. L., Lou, X. (2023). Hydrate dispersion stability in synergistic hydrate inhibition of monoethylene glycol and anti-agglomerants. Chemical Engineering Science, 269, 118462. https://doi.org/10.1016/j.ces.2023.118462
  27. Chen, L., Merey, S. (2021). Oceanic Methane Hydrates Fundamentals, Technological Innovations, and Sustainability. Elsevier. https://doi.org/10.1016/c2018-0-03857-8
  28. Zhang, L., Dong, H., Dai, S., Kuang, Y., Yang, L., Wang, J., Zhao, J., Song, Y. (2022). Effects of depressurization on gas production and water performance from excess-gas and excess-water methane hydrate accumulations. Chemical Engineering Journal, 431, 133223. https://doi.org/10.1016/j.cej.2021.133223
  29. Peng, D.-Y., Robinson, D. B. (1976). A New Two-Constant Equation of State. Industrial & Engineering Chemistry Fundamentals, 15 (1), 59–64. https://doi.org/10.1021/i160057a011
  30. Okonji, S., Ariavie, G., Egware, H., Kwasi-Effah, C. (2020). Review of Gas Hydrate Plug Dissociation in Oil and Gas Pipeline: Downstream Pressure Reduction Approach. Journal of Science and Technology Research, 2 (1), 182–199.
Research of methanol content in technological flows of facilities that process gas preparation by low-temperature separation method

Downloads

Published

2024-12-31

How to Cite

Dmytrenko, V., & Podoliak, T. (2024). Research of methanol content in technological flows of facilities that process gas preparation by low-temperature separation method. Technology Audit and Production Reserves, 6(1(80). https://doi.org/10.15587/2706-5448.2024.318926

Issue

Section

Technology and System of Power Supply