Study of destructive processing of hydrocarbons in inorganic melts. Influence of control parameters

Authors

  • Марат Аронович Гликин Technological Institute of East Ukraine Volodymyr Dahl National University, 59 prospect Radyanskyi, Severodonetsk, Lugansk region, Ukraine, 93400, Ukraine https://orcid.org/0000-0002-6502-4527
  • Вадим Юрьевич Тарасов Technological Institute of East Ukraine Volodymyr Dahl National University, 59 prospect Radyanskyi, Severodonetsk, Lugansk region, Ukraine, 93400, Ukraine https://orcid.org/0000-0003-3614-0913
  • Евгений Иванович Зубцов Technological Institute of East Ukraine Volodymyr Dahl National University, 59 prospect Radyanskyi, Severodonetsk, Lugansk region, Ukraine, 93400, Ukraine https://orcid.org/0000-0002-5916-1656
  • Евгений Юрьевич Черноусов Technological Institute of East Ukraine Volodymyr Dahl National University, 59 prospect Radyanskyi, Severodonetsk, Lugansk region, Ukraine, 93400, Ukraine https://orcid.org/0000-0002-9069-6421

DOI:

https://doi.org/10.15587/2312-8372.2015.43874

Keywords:

hydrocarbons, destruction, melt, eutectic mixtures, control parameters

Abstract

This article is devoted to the study of the destructive processing of hydrocarbons of different composition in inorganic melts. With the help of established methods of laboratory studies it is obtained reliable experimental data on the basis of which the influence of the main control parameters of the process is defined. it is determined an influence of the chemical composition of the melt temperature (in the range 400-600 °C) and contact times (in the range of 0,09-0,27 sec) on the composition and yield of the products in the processing of crude oil, black mineral oil, fuel oil, straight-run gasoline and n-hexane. Researches were conducted using melts of binary eutectic mixtures of metal chlorides (LiCl-KCl, NaCl-CuCl, CuCl-ZnCl2, NaCl-ZnCl2, KCl-ZnCl2, NaCl-MgCl2, CuCl-CaCl2, KCl-FeCl3), and also Pb-Sn. The optimal process conditions are virtually identical to the raw material of any composition when the maximum liquid yield temperature of about 500 ° C, contact time – from 0,15-0,20 sec, melts – a mixture of metal chlorides with ZnCl2 or FeCl3.

Processing of hydrocarbons in optimal conditions can increase the yield of light oil products for crude oil – by 22,1-23,9 %, for black mineral oil – by 23,7-25,9 %; to increase the octane number of straight-run gasoline by 26 points, mainly due to increase in the yield of isoparaffins; obtain a high yield of isomers in the processing of individual hydrocarbons (to 28,9 % from n-hexane).

Author Biographies

Марат Аронович Гликин, Technological Institute of East Ukraine Volodymyr Dahl National University, 59 prospect Radyanskyi, Severodonetsk, Lugansk region, Ukraine, 93400

Doctor of Technical Sciences, Professor

Department of Technology of Organic Substances, Fuels and Polymers

Вадим Юрьевич Тарасов, Technological Institute of East Ukraine Volodymyr Dahl National University, 59 prospect Radyanskyi, Severodonetsk, Lugansk region, Ukraine, 93400

Candidate of Technical Sciences, Associate Professor

Department of General and Physical Chemistry

Евгений Иванович Зубцов, Technological Institute of East Ukraine Volodymyr Dahl National University, 59 prospect Radyanskyi, Severodonetsk, Lugansk region, Ukraine, 93400

Candidate of Technical Sciences, Associate Professor

Department of Technology of Inorganic Substances and Ecology

Евгений Юрьевич Черноусов, Technological Institute of East Ukraine Volodymyr Dahl National University, 59 prospect Radyanskyi, Severodonetsk, Lugansk region, Ukraine, 93400

Postgraduate

Department of Technology of Organic Substances, Fuels and Polymers

References

  1. Chekryishkin, Yu. S., Panteleev, E. V., Shakirov, I. V., Haymenov, A. P. (1989). Neorganicheskie rasplavyi-katalizatoryi prevrascheniya organicheskih veschestv. Moscow: Nauka, 134.
  2. Paxman, D. (2014). Experimental and theoretical investigation of solar molten media methane cracking for hydrogen production. A thesis for the degree of Master of Science. Canada: University of Alberta, 199.
  3. Chernousov, E. Yu. (2013). Kreking syiroy nefti v rasplave metallov. Visnik of the Volodymyr Dahl East Ukrainian national university, 14 (203), 64-68.
  4. Ai, N., Zeng, G., Zhou, H., He, Y. (2013, January 31). Co-Production of Activated Carbon and Bio-Oil from Agricultural Residues by Molten Salt Pyrolysis. BioResources, Vol. 8, № 2, 1551-1562. doi:10.15376/biores.8.2.1551-1562
  5. Jiang, H., Wu, Y., Fan, H., Ji, J. (2012). Hydrogen Production from Biomass Pyrolysis in Molten Alkali. AASRI Procedia, Vol. 3, 217-223. doi:10.1016/j.aasri.2012.11.036
  6. Hathaway, B. J., Davidson, J. H., Kittelson, D. B. (2011). Solar Gasification of Biomass: Kinetics of Pyrolysis and Steam Gasification in Molten Salt. Journal of Solar Energy Engineering, Vol. 133, № 2. Available: http://doi.org/10.1115/1.4003680
  7. Nakatsuji, Y., Ikkaku, Y., Nomura, M., Kikkawa, S. (1978). The Hydrocracking of Alkyl-substituted Polynuclear Aromatic Hydrocarbons over ZnCl2/CuCl Molten Salt Catalyst. Bulletin of the Chemical Society of Japan, Vol. 51, № 12, 3631–3634. doi:10.1246/bcsj.51.3631
  8. Lanetti, P. E. O. (2011). Molten salt oxidation – a safe process for hazardous organic wastes decomposition. Proceedings of the 3rd International Workshop – Advances in Cleaner Production: “Cleaner Production Initiatives and Challenges for a Sustainable World”, 9.
  9. Nygard, H. S., Olsen, E. (2012, January 22). Review of thermal processing of biomass and waste in molten salts for production of renewable fuels and chemicals. International Journal of Low-Carbon Technologies, Vol. 7, № 4, 318-324. doi:10.1093/ijlct/ctr045
  10. Glikin, M. A., Chernousov, Ye. Yu. (2015). Protsessyi destruktivnoy pererabotki uglevodorodnogo syirya v neorganicheskih rasplavah. Kratkiy analiz. Himichna promislovist Ukrayini, 1 (126), 31-39.
  11. Glikin, M. A., Mamedov, B. B., Chernousov, Ye. Yu., Nechistyak, Ye. Yu. (2014). Issledovanie kinetiki krekinga individualnyih uglevodorodov v rasplave hloridov natriya i tsinka. Himichna promislovist Ukrayini, 3 (122), 42-47.

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Published

2015-05-28

How to Cite

Гликин, М. А., Тарасов, В. Ю., Зубцов, Е. И., & Черноусов, Е. Ю. (2015). Study of destructive processing of hydrocarbons in inorganic melts. Influence of control parameters. Technology Audit and Production Reserves, 3(4(23), 57–63. https://doi.org/10.15587/2312-8372.2015.43874

Issue

Vol. 3 No. 4(23) (2015): Technology organic and inorganic substances

Section

Technology organic and inorganic substances

License

Copyright (c) 2016 Марат Аронович Гликин, Вадим Юрьевич Тарасов, Евгений Иванович Зубцов, Евгений Юрьевич Черноусов

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