Obtaining the nanosized particles from aqueous solution of silver by plasma chemical method
DOI:
https://doi.org/10.15587/2312-8372.2015.47714Keywords:
non-equilibrium plasma, discharge, liquid cathode, low pressure, aqueous solutionAbstract
The influence of plasma chemical treating of aqueous solution containing silver ions for formation of the nanosilver particles, their size and their variation over a predetermined time interval are studied. As a processing tool is used the contact non-equilibrium low-temperature plasma that formed between the electrode (anode), located in the gas phase and the liquid surface, a recessed electrode therein. As the cathode it is used an electrolytic solution AgNO3 in the distilled water. Characteristics of the obtained nanoparticles, their absorption spectra, size, stability in aqueous medium and in the dry state in powder form are studied. The results will be used to create a refined mathematical model of plasma-chemical treatment of liquid media, the general equation of which is given in this article.
References
- Krutyakov, Y. Ya., Kudrytskiy, A. A. Olenin, A. Y., Lisichkin, G. V. (2008). Synthesis and properties of silver nanoparticles: Achievements and Prospects. Russian Chemical Reviews, 3 (77), 242–269.
- Rycenga, M., Cobley, C. M., Zeng, J., Li, W., Moran, C. H., Zhang, Q., Qin, D., Xia, Y. (2011). Controlling the Synthesis and Assembly of Silver Nanostructures for Plasmonic. Chemical Reviews, Vol. 111, № 6, 3669–3712. doi:10.1021/cr100275d
- Curtis, C. J., Miedaner, A., Rivkin, T., Alleman, J., Schulz, D. L., Ginley, D. S. (2000). Direct Write Metallizations for Ag and Al. MRS Proceedings, Vol. 624, 59–64. doi:10.1557/proc-624-59
- Kuzmina, L. N, Zvidentsova, N. S., Kolesnikov, L. V. (2007). Preparation of silver nanoparticles by chemical reduction. Journal of the Russian Chemical Society. D. I. Mendeleev, 8, 7–12.
- Rogov, I. S., Galanov, A. I. (2013). Preparation of silver nanoparticles by electric-wet dispersion Proceedings of the IV All-Russian Conference of Students' "Resource-efficient technologies – the energy and enthusiasm of the young". Tomsk: Publishing House of Tomsk Polytechnic University, 90–93.
- Danilenko, N. B., Galanov, A. I., Kornev, Ya. I. et al. (2006). The use of pulsed electric discharges for nanomaterials and their use for the purification of water. Nanotechnics, 4 (8), 81–91.
- Sergeyev, B. M., Kiryuhin, M. V., Prusov, A. N., Sergeyev, V. G. (1999). Preparation of silver nanoparticles in aqueous solutions of polyacrylic acid. Bulletin of Moscow University, Series 2: Chemistry, Vol. 40, № 2, 129–133.
- Sergeyeva, O. V., Pivovarov, A. A., Frolova, L. A., Dubovik, T. N. (2012). Recovery of silver ions from aqueous solution by plasmachemical processing Materiály VIII Mezinárodní vědecko – praktická conference «Přední vědecké novinky – 2012" 27 srpna–05 září. Chemie a chemická technologie zemědělství. Praha, 27–30
- Rogach, A. L., Hvalyuk, V. N., Gurin, V. S. (1994). The formation of fine silver in the reduction of Ag+ ions in aqueous solutions. Colloid Journal, 56 (12), 276–278.
- Skillman, D. C., Berry, C. R. (1968). Effect of Particle Shape on the Spectral Absorption of Colloidal Silver in Gelatin. The Journal of Chemical Physics, Vol. 48, № 7, 3297–3304. doi: 10.1063/1.1669607
- Pіvovarov, O. A.,Vorobyova, M. І., Sergeyeva, O. V. (12.10.2014). Sposіb otrimannya koloidnogo rozchinu nanochastok srіbla. Patent UA № 06343. IPC (2014.01) V01J 13/00. Appl. № u2014 12650. Filed 10.06.2014. Bull. № 23.
- Koltsova, E. M., Gordeev, L. S. Agatina, A. V. (1998). Algorithmic problems of nonlinear dynamics in the process of mass crystallization from solutions Software Products and Systems, 1, 29–35.
- Larson, M. A., Garside, J. (1986). Solute clustering and interfacial tension. Journal of Crystal Growth, Vol. 76, № 1, 88–92. doi:10.1016/0022-0248(86)90013-8
- Larson, M. A., Garside, J. (1986). Solute clustering in supersaturated solutions. Chemical Engineering Science, Vol. 41, № 5, 1285–1289. doi:10.1016/0009-2509(86)87101-9
- Sergeyeva, O. V., Pivovarov, A. A., Ovcharenko, O. V. (2009). Example solutions Direct problem hymycheskoy kinetics Using funds with Mathcad Professionel. Questions of chemistry and chemical technology, 5, 166–170.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2016 Ольга Вячеславовна Сергеева, Александр Андреевич Пивоваров
![Creative Commons License](http://i.creativecommons.org/l/by/4.0/88x31.png)
This work is licensed under a Creative Commons Attribution 4.0 International License.
The consolidation and conditions for the transfer of copyright (identification of authorship) is carried out in the License Agreement. In particular, the authors reserve the right to the authorship of their manuscript and transfer the first publication of this work to the journal under the terms of the Creative Commons CC BY license. At the same time, they have the right to conclude on their own additional agreements concerning the non-exclusive distribution of the work in the form in which it was published by this journal, but provided that the link to the first publication of the article in this journal is preserved.