Thermodynamic analysis of reactions in the system Al2O3–SiO2–CaO–P2O5

Authors

  • Юлия Вячеславовна Харыбина National Technical University «Kharkiv Polytechnic Institute», 21, Frunze str., 61002, Kharkiv, Ukraine https://orcid.org/0000-0001-5421-6702

DOI:

https://doi.org/10.15587/2312-8372.2016.80422

Keywords:

enthalpy, entropy, Gibbs energy, coupled reactions, coexisting phases

Abstract

The object of the research is identification of the coexisting phases in the system Al2O3SiO2–CaO–P2O5. To achieve this aim it is necessary to use the thermodynamical method. This method allows to study the physical and chemical processes in the system Al2O3SiO2–CaO–P2O5. Output thermodynamic data are calculated in the article: enthalpy ΔHo298, entropy So298, dependence formula of heating capacity from temperature Cp = f(T) for some combinations of system Al2O3SiO2–CaO–P2O5, by different methods. This is important for carrying out thermodynamic analysis of phase equilibriums in this system. An opportunity of coupled reactions is determined. It is indicated about restructuring of conodes in the researching system. Knowledge of the structure of this system (due to the thermodynamical data) will allow to predict the phase transformations in the process of obtaining new refractory products.

Author Biography

Юлия Вячеславовна Харыбина, National Technical University «Kharkiv Polytechnic Institute», 21, Frunze str., 61002, Kharkiv

Postgraduate

Department of the technology of ceramics, refractories, glass and enamels

References

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Published

2016-09-29

How to Cite

Харыбина, Ю. В. (2016). Thermodynamic analysis of reactions in the system Al2O3–SiO2–CaO–P2O5. Technology Audit and Production Reserves, 5(3(31), 7–11. https://doi.org/10.15587/2312-8372.2016.80422

Issue

Section

Technologies of food, light and chemical industry