Methods of obtaining bitumen from heavy oil processing residues

Authors

DOI:

https://doi.org/10.15587/2312-8372.2015.51054

Keywords:

bitumen, heavy oil, oxidation, modification, tar, rubber crumb

Abstract

The article describes several methods for solving urgent problems: obtaining the qualitative bituminous materials from unsuitable for recycling heavy oil processing residues. The work was carried out in three directions. The results of the study of the basic laws of oxidation of heavy oils processing residues showed that this method for obtaining the bitumen is failed. The basic laws of joint oxidation of tar from heavy Orkhovitsk oil with heavy pyrolysis resin and neutralized acid tar. It was shown that the method of co-oxidation of Orkhovitsk oil residue and 11-13 % masses of heavy pyrolysis resin at the temperature of 250 °С, air supply 2,5 h-1 during 6 hours allows obtaining the road bitumen of the grade BND 60/90 according to DSTU 4044-2001. The process of modification of residual bitumen derived from heavy Orkhovitsk oil by the Butonal latex and rubber crumb is described. It is established that the use of these modifiers makes it possible to improve the properties of bitumen obtained from heavy oils. The results, presented in this article, can be used in the development of industrial technology for obtaining the bitumen from heavy oil processing residues.

Author Biographies

Олег Богданович Гринишин, Lviv Polytechnic National University, str. S. Bandery, 12, 79013, Lviv

Doctor of Technical Sciences, Associate Professor

Department of Chemical Engineering of Oil and Gas

Юрій Ярославович Хлібишин, Lviv Polytechnic National University, str. S. Bandery, 12, 79013, Lviv

Candidate of Technical Sciences, Associate Professor

Department of Technology of Organic Products

Олег Антонович Нагурський, Lviv Polytechnic National University, str. S. Bandery, 12, 79013, Lviv

Doctor of Technical Sciences, Associate Professor, Head of Department

Department of Civil Security

Андрій Олегович Нагурський, Lviv Polytechnic National University, str. S. Bandery, 12, 79013, Lviv

Postgraduate

Department of Chemical Engineering of Oil and Gas

References

  1. Hairudinov, I. R., Sultanov, F. M. (2011). Protsess sol'ventnoi deasfal'tizatsii – perspektivnaia osnova dlia dostizheniia vysokoi glubiny pererabotki nefti. Mir nefteproduktov, 3, 17–19.
  2. Sultanov, F. M., Hairudinov, I. R. (2011). Novyi protsess deasfal'tizatsii neftianyh ostatkov. Neftepererabotka i neftehimiia, 10, 8–13.
  3. Riabov, V. G., Shirkunov, A. S. (2008). Poluchenie kachestvennyh dorozhnyh bitumov s ispol'zovaniem vysokoviazkih gudronov. Neftepererabotka i neftehimiia, 8, 26–31.
  4. Tabarov, S. L., Savdrahmonov, S. S. (2003). Tiazhelye nefti Respubliki Tadzhikistan i vozmozhnye puti ih pererabotki. Nauka i tehnologiia uglevodorodov, 2, 7–14.
  5. Leonenko, V. V., Safonov, G. A. (2001). Nekotorye aspekty modifikatsii bitumov polimernymi materialami. Himiia i tehnologiia topliv i masel, 5, 43–45.
  6. Zolotarev, V. A. (2003). Svoistva bitumov, modifitsirovannyh polimerami tipa SBS. Avtoshliakhovyk Ukrainy, 5, 25–27.
  7. Kishchynskyi, S. V. (2003). Doslidzhennia vplyvu termoelastoplastiv na vlastyvosti bitumiv. Avtoshliakhovyk Ukrainy, 6, 28–30.
  8. Shevchenko, V. P., Romanenko, S. M., Rebenok, O. Ye. et al. (2003). Vlastyvosti asfaltobetoniv na osnovi bitumiv, modyfikovanykh polimeramy. Avtoshliakhovyk Ukrainy, 1, 27–28.
  9. Grynyshyn, O., Astakhova, O., Chervinskyy, T. (2010). Production of bitumen modified by petroleum resins on the basis of tars of Ukrainian oils. Chemistry & Chemical Technology, Vol. 4, № 3, 241–246.
  10. García-Morales, M., Partal, P., Navarro, F. J., Gallegos, C. (2006, May). Effect of waste polymer addition on the rheology of modified bitumen. Fuel, Vol. 85, № 7-8, 936–943. doi:10.1016/j.fuel.2005.09.015
  11. Sun, D., Lu, W. (2003, January 6). Investigation and Improvement of Storage Stability of SBS Modified Asphalt. Petroleum Science and Technology, Vol. 21, № 5-6, 901–910. doi:10.1081/lft-120017456
  12. Pronyk, Yu. D., Vyrozhemskyi, V. K., Kishchynskyi, S. V. (2004). Polimerni modyfikatory orhanichnykh viazhuchykh serii Butonal u dorozhnomu budivnytstvi. Avtoshliakhovyk Ukrainy, 1, 41–42.
  13. Pavliukh, Y. S., Pavliukh, O. Y. (2005). Naftovi poklady Orkhovytskoho rodovyshcha u konteksti zahalnoi naftonosnosti Zovnishnoi zony Peredkarpatsykoho prohynu. Naftova i hazova promyslovist, 3, 15–19.
  14. Mokhammad Shakyr Abd Al-Ameri, Hrynyshyn, O. B., Saban, I. I. (2012). Modyfikuvannia zalyshkovoho bitumu orkhovytskoi nafty polimeramy. Visnyk Natsionalnoho universytetu «Lvivska politekhnika», Khimiia, tekhnolohiia rechovyn ta yikh zastosuvannia, 726, 463–467.
  15. Zaporozhets, O., Nikitchenko, Yu. (2013). Environmental risks assessment at used tyres storage at landfills. Eastern-European Journal Of Enterprise Technologies, 2(11(62)), 19–24. Available: http://journals.uran.ua/eejet/article/view/11725

Published

2015-09-22

How to Cite

Гринишин, О. Б., Хлібишин, Ю. Я., Нагурський, О. А., & Нагурський, А. О. (2015). Methods of obtaining bitumen from heavy oil processing residues. Technology Audit and Production Reserves, 5(4(25), 45–48. https://doi.org/10.15587/2312-8372.2015.51054

Issue

Section

Technologies of food, light and chemical industry