Effectiveness research of new catalyst for oil and fat interesterification by using chromatographic analysis
DOI:
https://doi.org/10.15587/2312-8372.2015.53285Keywords:
interesterification, catalyst, fatty acid composition, palm olein, triacyglyceride composition, gas-liquid chromatographyAbstract
Distribution of interesterification process as a tool for oil and fat modification, as well as the need to import industrial catalysts that are unstable chemical compounds and dangerous in terms of safety, determine the feasibility of introducing new interesterification catalysts.
In this article the efficiency of the new interesterification catalyst – potassium glycerate, which were obtained in the laboratory conditions is investigated. As a result of chromatographic analysis it was found a change of triacyglyceride composition of palm olein after the interesterification reaction in the presence of potassium glycerate and industrial catalysts – sodium methylate. The study of calculated statistically equilibrium triacyglyceride composition and output and interesterificated samples of palm olein showed that triacyglyceride composition obtained after reaction with potassium glycerate is more close to settlement. So potassium glycerate is an effective catalyst for chemical interesterification of fats. The results of the study confirmed the possibility of using potassium glycerate in enterprises of oil and fat industry with the process of interesterification of oils and fats. Moreover, it can get directly at the enterprise.
References
- Ukrainian Research Institute of Oils and Fats NAAS. (2015). Oliino-zhyrova haluz Ukrainy. Pokaznyky roboty za 1 kvartal 2015 r., 2014/15 MR. Kharkiv: Ukrainian Research Institute of Oils and Fats NAAS, 104.
- Kirkebi, P. G. (2007). Tehnologiia proizvodstva margarina, obogashchennogo omega-3 zhirnymi kislotami. Masla i zhiry, 10 (80), 19–22.
- Miskandar, M. S., Man, Y. C., Affandi Yusoff, M. S., Rahman, Abd. R. (2005). Quality of margarine: fats selection and processing parameters. Asia Pac. J. Clin. Nutr., Vol. 14, № 4, 387–395.
- Miloradova, E. V., Slager, H. (2010). Fraktsii pal'movogo masla kak osnova dlia sozdaniia zhirov povyshennoi pishchevoi tsennosti. Maslozhirovaia promyshlennost', 3, 14–16.
- Paska, M. Z., Demydov, I. M., Zhuk, O. I. (2013). Tekhnolohiia marharyniv ta promyslovykh zhyriv. Lviv: SPOLOM, 187.
- Ignatov, V. I. (2010). Trebovaniia rynka k spetszhiram i margarinovoi produktsii dlia promyshlennogo primeneniia. Maslozhirovaia promyshlennost', 1, 4–6.
- Mel'nikova, O. A., Perova, N. V. (2010). Trans-izomery nenasyshchennyh zhirnyh kislot kak faktor vysokogo riska zbolevanii. Maslozhirovaia promyshlennost', 2, 12–15.
- Costales-Rodríguez, R., Gibon, V., Verhé, R., De Greyt, W. (2009, May 30). Chemical and Enzymatic Interesterification of a Blend of Palm Stearin: Soybean Oil for Low trans-Margarine Formulation. Journal of the American Oil Chemists’ Society, Vol. 86, № 7, 681–697. doi:10.1007/s11746-009-1395-2
- Hunter, J. E. (2004). Alternatives to trans fatty acids in foods. Inform, Vol. 15, № 8, 510–512.
- Mel'nikov, V. V. (2011). Zamenitel' molochnogo zhira dlia spredov. Maslozhirovaia promyshlennost', 6, 15–16.
- Noor Lida Habi Mat Dian, Kalyana Sundram, Asman Ismail. (2006). Interesterified palm products as hard stock for solid fat formulations. MPOB Informatiom series, 323, 330–331.
- Tiutiunnykov, B. N., Bukhshtab, Z. I., Hladkyi, F. F. et al. (2002). Khimiia zhyriv. Kharkiv: NTU „KhPI”, 432.
- Amir, R. M., Shabbir, M. A., Khan, M. R., Hussain, S. (2012). Interesterification of fats and oils – a review. Pak. J. of Food Sci., Vol. 22, № 3, 143–153.
- Demydov, I. M., Sytnik, N. S., Gusak, V. A. (2015). Perspektyvni napriamky udoskonalennia pereeeteryfikatsii olii ta zhyriv. Intehrovani tekhnolohii ta enerhozberezhennia, 2, 90–95.
- Demydov, I. M., Sytnik, N. S., Gusak, V. A. (27.07.2015). Sposib pereeteryfikatsii olii ta zhyriv. Patent of Ukraine № 100531, MPK A23D 9/02, C11C 3/10. Appl. № u 201501842. Filed 02.03.2015. Bull. № 14. Available: http://uapatents.com/4-100531-sposib-pereeterifikaci-olijj-ta-zhiriv.html
- Ukrainian Research Institute of Oils and Fats NAAS. (2013). Metodychne zabezpechennia identyfikatsii pereeteryfikovanykh olii. Research report (final) № 012U005479. Kharkiv, 155.
- Liu, L. (2004, April). How is chemical interesterification initiated: Nucleophilic substitution or α-proton abstraction? Journal of the American Oil Chemists’ Society, Vol. 81, № 4, 331–337. doi:10.1007/s11746-004-0903-x
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