Obtaining oxide compounds of metals from water solution by contact non-equilibrium plasma treatment

Authors

DOI:

https://doi.org/10.15587/2312-8372.2016.65419

Keywords:

contact non-equilibrium plasma, solution, nano-sized particles, oxygen compounds of cobalt, copper

Abstract

The data obtained as the authors themselves with the assistance of laboratory equipment as well as data obtained from the literature, are used in the article. This study examined obtaining superfine powders of oxygen-containing compounds of cobalt and copper in the water solutions. The necessity of these studies due to the fact that the characteristics of the particles greatly depends on the production method, and, therefore, further studies were necessary for particles obtained by the treatment of water solutions by contact non-equilibrium plasma. When using the plasma chemical processing method for the Co(OH)2 in water and CuSO4 solution, sediments with dimensional characteristics in the range from 8 to 110 nm were obtained. Larger particles are shown in the form of agglomerates 0,5-5 microns. Sediments of cobalt compounds are presented in the form of β-form of cobalt hydroxide (II), CoO, Co3O4, and copper compounds in the form of Cu2O, CuO and Cu, which is confirmed by X-ray diffraction data. The possibility to control the process of synthesis of particles by adjusting its parameters was proved that thanks to its constructive design is straightforward and is advantage of this method along with the possibility of using very dilute solutions. These studies point to the prospect of using the particles with desired characteristics for the development of catalysts for chemical processes in the production of ceramics, and dyes, as well as industries, including the development of chemical current sources.

Author Biographies

Ольга Вячеславовна Сергеева, Ukrainian State University of Chemical Technology, Gagarin ave. 8, Dnepropetrovsk, 49005

Candidate of Technical Sciences, Associate Professor

Department of Technology Inorganic Substances and Ecology

Александр Андреевич Пивоваров, Ukrainian State University of Chemical Technology, Gagarin ave. 8, Dnepropetrovsk, 49005

Doctor of Technical Sciences, Professor

Department of Technology Inorganic Substances and Ecology

References

  1. Ershov, B. G. (2001). Nanochastitsy metallov v vodnyh rastvorah: elektronnye, opticheskie i kataliticheskie svoistva. Rossiiskii himicheskii zhurnal, Vol. XLV, № 3, 20–30.
  2. Dhas, N. A., Raj, C. P., Gedanken, A. (1998, May). Synthesis, сharacterization, and properties of metallic copper nanoparticles. Chemistry of Materials, Vol. 10, № 5, 1446–1452. doi:10.1021/cm9708269
  3. Kear, В. H., Strutt, P. R. (1995, January). Chemical processing and applications for nanostructured materials. NanoStructured Materials, Vol. 6, № 1-4, 227–236. doi:10.1016/0965-9773(95)00046-1
  4. Hе, W., Duan, X., Zhu, L. (2009, October). Characterization of ultrafine copper powder prepared by novel electrodeposition method. Journal of Central South University of Technology, Vol. 16, № 5, 708–712. doi:10.1007/s11771-009-0117-0
  5. Lee, W. M. (1991). Metal/Water chemical reaction coupled pulsed electrical discharge. Journal of Applied Physics, Vol. 69, № 10, 6945–6951. doi:10.1063/1.348931
  6. Rahman, M. M., Wang, J.-Z., Deng, X.-L., Li, Y., Liu, H.-K. (2009, December). Hydrothermal synthesis of nanostructured Co3O4 materials under pulsed magnetic field and with an aging technique, and their electrochemical performance as anode for lithium-ion battery. Electrochimica Acta, Vol. 55, № 2, 504–510. doi:10.1016/j.electacta.2009.08.068
  7. Lepeshev, A. A., Ushakov, A. V., Karpov, I. V. (2012). Plazmohimicheskii sintez nanodispersnyh poroshkov i polimernyh nanokompozitov. Krasnoiarsk: Sib. feder. un-t, 328.
  8. Samukawa, S., Hori, M., Rauf, S., Tachibana, K., Bruggeman, P., Kroesen, G. et al. (2012, June 7). The 2012 Plasma Roadmap. Journal of Physics D: Applied Physics, Vol. 45, № 25, 253001. doi:10.1088/0022-3727/45/25/253001
  9. Lurie, Y. Y. (1989). Handbook of Analytical Chemistry. Ed. 6. Moscow: Chemistry, 448.
  10. Ruzinov, L. A., Gulyanitsky, B. S. (1975). Equilibrium conversion of metallurgical reactions. Moscow: Metallurgy, 416.
  11. Kislenko, L. V., Oleinik, L. P. (2008). The formation of the copper oxide particles in an aqueous solution polivinilpirrolidona. Ukrainian Chemical Journal, Vol. 74, № 4, 67–70.
  12. Teslyuk, D. A., Vasyoha, M. V. (2013). Theoretical analysis sulphite precursor for the synthesis of fine powders of cobalt oxide (II), nickel (II) and copper (II). Proceedings of the Kurnakovskoe X International Meeting on the physical and chemical analysis. Samara: Samara State Technical University, 74–79.
  13. Baes, C. F., Mesmer, R. E. (1976). The hydrolysis of cations. New York: Wiley, 489.
  14. Sergeyeva, O. V. (2014). Obtaining of micro- and nanoscale copper compounds by plasma-chemical treatment of solutions. Technology Audit And Production Reserves, 5(3(19)), 19–22. doi:10.15587/2312-8372.2014.27943
  15. Sergeyeva, O., Pivovarov, A. (2015). Theoretical analysis of the fine powder of the copper oxides by received of plasmachemical by treatment of solution CuSO4. Bulletin of NTU «KhPI». Series: New solutions in modern technologies, 62 (1171), 155–159.

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Published

2016-03-29

How to Cite

Сергеева, О. В., & Пивоваров, А. А. (2016). Obtaining oxide compounds of metals from water solution by contact non-equilibrium plasma treatment. Technology Audit and Production Reserves, 2(4(28), 60–63. https://doi.org/10.15587/2312-8372.2016.65419

Issue

Vol. 2 No. 4(28) (2016): Technologies of food, light and chemical industry

Section

Technologies of food, light and chemical industry

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Copyright (c) 2016 Ольга Вячеславовна Сергеева, Александр Андреевич Пивоваров

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