The interaction of derma collagen with mineral and polymer compounds

Authors

DOI:

https://doi.org/10.15587/2312-8372.2016.65494

Keywords:

filling composition, interaction, IR spectroscopy, active groups, chemical bond, collagen, derma

Abstract

Analysis of the existing research aimed at expanding the range of filling and retanning materials and increasing environmental leather industry showed that the actual trend is the use of compositions based on bentonite clay.

To assess the effectiveness of the developed polymer-mineral compositions is expedient to establish the nature of the interaction between the surface of the material and collagen to predict the effectiveness of structuring the derma and rational use of chemical compounds created in the leather production.

IR spectroscopy was chosen for the experiment. The object of this article is the infrared spectroscopic study of the interaction of the derma collagen with modified montmorillonite and acrylic emulsion.

As a result of analysis of the infrared spectra it was concluded that mineral and polymer compounds can significantly change the structure of semi-finished chrome through the formation of bonds of various nature: coordination, electrovalent, hydrogen bonds and van der Waals forces. The most likely is the formation of new types of hydrogen bonds Si-O....H-N and Si-O....H-C between the active centers of modified montmorillonite and NH- and CH- protein groups. Interact with chrome gelatin in the case of use of acrylic polymers is involving carboxyl and carbonyl groups of MBM-3 and amino, ester, peptide groups ionized groups СOO- and NH3 + of chrome gelatin.

Such interaction will promote the efficient structuring of the collagen structure of the derma in the following manufacturing processes and improve operational properties of the leather.

Author Biographies

Валентина Анатоліївна Отрошко, Chernihiv National University of Technology, 95 Shevchenka Str., 14027, Chernihiv

PhD student

Department of Commodity, expertise, customs businessand trade

Ніна Василівна Мережко, Kyiv National University of Trade and Economics, Kyoto 19, Kyiv, Ukraine, 02156

Doctor of Technical Sciences, Professor, Head of Department

Department of Commodity and examination of consumer goods

Олена Романівна Мокроусова, Kyiv National University of Trade and Economics, Kyoto 19, Kyiv, Ukraine, 02156

Doctor of Technical Sciences, Professor

Department of Commodity and examination of consumer goods

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Published

2016-03-29

How to Cite

Отрошко, В. А., Мережко, Н. В., & Мокроусова, О. Р. (2016). The interaction of derma collagen with mineral and polymer compounds. Technology Audit and Production Reserves, 2(4(28), 48–54. https://doi.org/10.15587/2312-8372.2016.65494

Issue

Vol. 2 No. 4(28) (2016): Technologies of food, light and chemical industry

Section

Technologies of food, light and chemical industry

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Copyright (c) 2016 Валентина Анатоліївна Отрошко, Ніна Василівна Мережко, Олена Романівна Мокроусова

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