Synthesis and investigation dark polymer hydrocarbon resins in the bitumen composites

Authors

DOI:

https://doi.org/10.15587/2312-8372.2016.65573

Keywords:

dark polymer hydrocarbons resins, oil bitumen, hydrocarbons fraction, heavy pyrolysis pitch, modification, petroleum bitumen composition

Abstract

Thermal gas-phase pyrolysis of hydrocarbon raw materials in pipe furnaces remains to be the main strategic process of ethylene and propylene production. Nowadays, the possibility of the pyrolysis process intensification to increase the target product yield draws attention of scientists. But besides the olefins (target products) the pyrolysis process is the source of heavy pyrolysis pitch. Considerable development of petrochemical industry requires finding new applications of the by-products from pyrolysis gas and liquid pyrolysis products. Methods of polymer hydrocarbons resin synthesis from the liquid wasters of ethylene and propylene production have been considered. Regularities of modification of polymer  hydrocarbons resins (PHRs) insulating oil bitumen have been worked. The influence of the main factors on the physical and chemical properties of this process has been determined. The mechanism of influence petroleum polymer resins (cooligomer products) components to the complex technical and performance properties of the petroleum bitumen compositions have been regarded. Found that based on bitumen insulation compositions of the physical and mechanical parameters, electrical insulation and corrosion characteristics meet the requirements for insulation of underground pipelines have been defined. Polymer petroleum resins as modifiers significantly increase the inhibitory properties of bitumen matrix. 

Author Biographies

Ірена Євгенівна Никулишин, Lviv Polytechnic National University, 12 S. Bandery str., Lviv, Ukraine, 79013

Doctor of Technical Sciences, Associate Professor

Department of Organic Products Technology

Зорян Григорович Піх, Lviv Polytechnic National University, 12 S. Bandery str., Lviv, Ukraine, 79013

Doctor of Chemical Sciences, Professor, Head of Department

Department of Organic Products Technology

Лілія Іванівна Шевчук, Lviv Polytechnic National University, 12 S. Bandery str., Lviv, Ukraine, 79013

Doctor of Technical Sciences, Associate Professor

Department of Department of Organic Products Technology

Анна Мирославівна Рипка, Lviv Polytechnic National University, 12 S. Bandery str., Lviv, Ukraine, 79013

Candidate of Technical Sciences, Research Assistant

Department of Organic Products Technology

Руслана Тарасівна Чайківська, Lviv Polytechnic National University, 12 S. Bandery str., Lviv, Ukraine, 79013

Department of Organic Products Technology

References

  1. Bratychak, M. M., Hetmanchuk, Yu. P. (2009). Khimichna tekhnolohiia syntezu vysokomolekuliarnykh spoluk. Lviv: Vyd-vo NU «Lvivska politekhnika», 409.
  2. Lesniak, V. P., Gaponik, L. V., Shiman, D. I., Kostiuk, S. V., Kaputskii, F. N. (2008). Sintez, modifikatsiia i primenenie neftepolimernyh smol na osnove monomersoderzhashchih piroliznyh fraktsii. Himicheskie problemy sozdaniia novyh materialov i tehnologii. Minsk, 204–245.
  3. Manankova, A. A., Bondaletov, V. G. (2007). Kvalifitsirovannoe ispol'zovanie pobochnyh produktov neftehimicheskih proizvodstv. Izvestiia Samarskogo nauchnogo tsentra RAN. Spetsial'nyi vypusk. Bezopasnost'. Tehnologii. Upravlenie, Vol. 1, 68–70.
  4. Lebedeva, I. P., Lubinskii, M. I., Doshlov, O. I. (2007). K voprosu ispol'zovaniia tiazheloi smoly piroliza dlia polucheniia uglegrafitovyh materialov. Tezisy dokladov V respublikanskoi nauchno-tehnicheskoi konferentsii molodyh uchenyh i spetsialistov aliuminievoi i elektrodnoi promyshlennosti. Irkutsk, 77–78.
  5. Lebedeva, I. P., Lazarev, D. G., Doshlov, O. I., Lubinskii, M. I., Lebedeva, N. P. (2009). Perspektivnye tehnologii pererabotki tiazheloi smoly proliza. V mire nauchnyh otkrytii, 5, 25–29.
  6. Kapustin, V. M., Chernysheva, E. A. (2010). Problemy i tendentsii razvitiia sovremennogo neftepererabatyvaiushchego i neftehimicheskogo kompleksa. Materialy Mezhdunarodnoi nauchno-prakticheskoi konferentsii «Neftegazopererabotka-2010». Ufa, 18–19.
  7. Muhamedzianova, A. A., Abdullin, M. I., Muhamedzianov, A. T., Gimaev, R. N. (2012). Kinetika obrazovaniia mezofazy pri termopolikondensatsii vysokoaromatizirovannyh neftianyh ostatkov. Vestnik Bashkirskogo universiteta, Vol. 17, № 4, 1721–1725.
  8. Kopytov, M. A., Bondaletov, V. G., Prozorova, I. V., Loskutova, Yu. V., Yudina, N. V. (2004). Prisadki kompleksnogo deistviia na osnove neftepolimernyh smol. Materialy III Vserossiiskoi nauchno-prakticheskoi konferentsii «Dobycha, podgotovka, transport nefti i gaza». Tomsk, 83–86.
  9. Bratychak, М., Grynyshyn, O., Astakhova, O., Shyshchak, O., Waclawek, W. (2010). Functional petroleum resins based on pyrolysis by-products and their application for bitumen modification. Ecological chemistry and engineering, Vol. 17, № 3, 309–315.
  10. Pyshiev, S., Hrytsenko, Yu., Khlibyshyn, Yu., Strap, H., Koval, T. (2014). Influence of the nature of polymer on properties of modified bitumen. Eastern-European Journal Of Enterprise Technologies, 2(11(68)), 4–8. doi:10.15587/1729-4061.2014.21862
  11. Grynyshyn, О., Bratychak, M., Krynytskiy, V., Donchak, V. (2008). Petroleum resins for bitumens modification. Chemistry & Chemical Technology, Vol. 2, № 1, 47–53.
  12. Bratychak, M., Grynyshyn, O., Shyshchak, O., Romashko, I., Waclawek, W. (2007). Obtaining of petroleum resins using pyrolysis by-products. Petroleum resins with hydroxyl groups. Ecological Chemistry and Engineering. S, Vol. 14, № 2, 225–234.
  13. Bratychak, М., Grynyshyn, O., Astakhova, O., Shyshchak, O., Waclawek, W. (2008). Petroleum resins with hydroxyl groups modified with styrene. Ecological Chemistry and Engineering. S, Vol. 15, № 3, 387–396.
  14. Fiterer, E. P., Bondaletov, V. G., Anikanova, L. A., Grigor'eva, M. A., Slavgorodskaia, O. I. (2011). Poluchenie gidroizoliatsionnyh mastik na osnove neftianyh bitumov, modifitsirovannyh neftepolimernymi smolami. Lakokrasochnye materialy i ih primenenie, 1-2, 85–89.
  15. Hrudz, V. Ya., Tymkiv, D. F., Kostiv, V. V. (2009). Obsluhovuvannia i remont truboprovodiv. Ivano-Frankivsk: Lileia-NV, 711.
  16. Oliinyk, I. Ya., Kychma, A. O., Danylo, Ya. Ya. (2009). Suchasni pidkhody do zabezpechennia roboty hazotransportnoi systemy tryvaloi ekspluatatsii. 9-y Mizhnarodnyi sympozium ukrainskykh inzheneriv-mekhanikiv. Lviv, 221–223.
  17. Ahmatnurov, A. M., Demin, Yu. N. (2008). Opyt vypolneniia rabot po pereizoliatsii gazoprovoda bez ostanovki transporta gaza. Gazovaia promyshlennost', 9, 106–108.
  18. Itkin, O. F., Derkach, M. P., Banakhevych, Yu. V. (2009). Dosvid vykonannia robit iz kapitalnoho remontu hazoprovodiv bez zupynky transportu hazu. Naftova i hazova promyslovist, 4, 51–53.
  19. Kryzhanivskyi, Ye. I., Fedorovych, Ya. T., Polutrenko, M. S. et al. (2011). Pidvyshchennia protykoroziinykh kharakterystyk ta nadannia biostiikosti zakhysnym izoliatsiinym pokryttiam na bitumno polimernii osnovi. Rozvidka ta rozrobka naftovykh i hazovykh rodovyshch, 3 (40), 100–105.
  20. Kryzhanivskyi, Ye. I., Polutrenko, M. S., Fedorovych, Ya. T. (2011). Pidvyshchennia efektyvnosti vykorystannia suchasnykh izoliatsiinykh pokryttiv dlia zakhystu pidzemnykh sporud vid korozii. Mizhnarodna naukovo-tekhnichna konferentsiia «Nafto-hazova enerhetyka – 2011», 10-14 zhovtnia 2011 r. Ivano-Frankivsk, 91.
  21. Kryzhanivskyi, Ye. I., Polutrenko, M. S., Fedorovych, Ya. T. et al. (2011). Vidnovlennia protykoroziinoho zakhystu pidzemnykh hazonaftoprovodiv v sylno mineralizovanykh hruntakh. Naftohazova enerhetyka, 1 (41), 34–38.
  22. Kryzhanivskyi, Ye. I., Polutrenko, M. S. (2012). Pidvyshchennia efektyvnosti pasyvnoho zakhystu pidzemnykh sporud vid korozii. Naukovyi visnyk IFTUNH, 1 (31), 32–41.
  23. Purish, L. M., Asaulenko, L. H., Abdulina, D. R., Yutynska, H. O. (2010). Kharakterystyka sulfatvidnovliuvalnykh bakterii, vydilenykh u teplovykh merezhakh. Dopovidi Natsionalnoi akademii nauk Ukrainy, 4, 169–173.
  24. Shmarov, V. M., Labunets, V. F., Bielievtsev, R. Ya., Kozlova, I. O., Prysiazhniuk, V. V. (2015). Utvorennia antyfryktsiinykh mineralnykh sirkovmisnykh biopokryttiv na konstruktsiinykh materialakh. Visnyk Vinnytskoho politekhnichnoho instytutu, 1, 162–167.
  25. Nykulyshyn, I. (2009). Catalytic Complexes In The Petroleum Resins Synthesis Processes. Using. Properties. V naukovo-tekhnichna konferentsiia «Postup u naftohazopererobnii ta naftokhimichnii promyslovosti», 9-12 chervnia 2009 r. Lviv, 68–69.
  26. Urbaniak, W., Nykulyszyn, I., Pich, Z., Rypka, A., Woronchak, T. (2010). Homogeneous Catalytic Complexes in the Petroleum Resins Synthesis Processes. 17th International Symposium on Homogeneous Catalysis, July 4-9, 2010. Poznan, Poland, 321.
  27. Rypka, H. M., Serednytskyi, Ya. A., Nykulyshyn, I. Ye., Pikh, Z. H., Voronchak, T. O. (2013). Modyfikatsiia naftobitumnykh mastykovykh pokryttiv naftopolimernymy smolamy. Voprosy himii i himicheskoi tehnologii, 5, 107–109.
  28. Nykułyszyn, I., Pich, Z., Urbaniak, W. (2009). Sposoby zagospodarowania odpadów przemysłu naftowego na Ukrainie. Rekultywacja i rewitalizacja terenów zdegradowanych, 1, 261–270.
  29. Hnativ, Z. Ya., Nykulyshyn, I. Ye., Pikh, Z. H., Rypka, A. M., Voronchak, T. O. (2012). Oderzhannia temnykh naftopolimernykh smol katalitychnoiu spivpolimeryzatsiieiu vazhkoi smoly pirolizu z fraktsiieiu S9 produktiv pirolizu dyzelnoho palyva. Visnyk Natsionalnoho tekhnichnoho universytetu «KhPI», 68 (974), 176–179.
  30. Gnativ, Z., Nykulyshyn, I., Rypka, A., Voronchak, T., Pikh, Z. (2014). Study of aromatic and terpenic hydrocarbons catalytic cooligomerization regularities. Chemistry & Chemical Technology, 4, 401–410.

Published

2016-03-29

How to Cite

Никулишин, І. Є., Піх, З. Г., Шевчук, Л. І., Рипка, А. М., & Чайківська, Р. Т. (2016). Synthesis and investigation dark polymer hydrocarbon resins in the bitumen composites. Technology Audit and Production Reserves, 2(4(28), 80–87. https://doi.org/10.15587/2312-8372.2016.65573

Issue

Section

Technologies of food, light and chemical industry