Determination of precipitation regularities for nanoparticles of hydrated metal oxides in the anion exchange resin

Authors

  • Константин Сергеевич Супруненко National Technical University of Ukraine «Kyiv Polytechnic Institute», 37 Peremogy ave. Kyiv, Ukraine, 03056, Ukraine https://orcid.org/0000-0002-0559-9054
  • Александр Александрович Kвитка National Technical University of Ukraine «Kyiv Polytechnic Institute», 37 Peremogy ave. Kyiv, Ukraine, 03056, Ukraine https://orcid.org/0000-0003-4034-7052
  • Екатерина Олеговна Куделко V. I. Vernadsky Institute of General and Inorganic Chemistry of the Ukrainian National Academy of Sciences, Pr. Vernadsky 32/34, 03680, Kyiv, Ukraine https://orcid.org/0000-0002-7319-8797
  • Юлия Сергеевна Дзязько V. I. Vernadsky Institute of General and Inorganic Chemistry of the Ukrainian National Academy of Sciences, Pr. Vernadsky 32/34, 03680, Kyiv, Ukraine https://orcid.org/0000-0003-3599-9558
  • Александра Станиславовна Руденко V. I. Vernadsky Institute of General and Inorganic Chemistry of the Ukrainian National Academy of Sciences, Pr. Vernadsky 32/34, 03680, Kyiv, Ukraine https://orcid.org/0000-0003-2327-5106

DOI:

https://doi.org/10.15587/2312-8372.2016.70634

Keywords:

organic and inorganic ionites, hydrated metal oxides, nanoparticles, fractals

Abstract

Organic and inorganic ion-exchange materials containing incorporated inorganic particles of ion exchangers are characterized by enhanced selectivity for ions of toxic metals and resistant to poisoning by organic substances. An important task for achieve the necessary kinetic parameters of ion exchange is to reduce the size of the incorporated particles that is particularly important for hydrated oxides containing functional groups, mainly, on the outer surface of the particles. Regularities of forming Zr(IV), Fe(III), Al(III) oxide particles in a polymeric anion exchange matrix are considered in the article. The aim of research is establishing and experimental confirmation of deposition mechanism for inorganic ionite in the polymer for directional control of size and state of the particles.

Using computer analysis of TEM images it was revealed that the fractal dimension of the aggregate particles is 2,38-2,72. Nature of modifier also determines the state of the polymer particles. The effect of these factors was analyzed using the Ostwald-Freundlich equation. It was established that the primary nanoparticle size is determined by reprecipitation. Accordingly, the formation mechanism of aggregates is association of nanoparticles with a small cluster, and the limiting step is the diffusion of the polymer nanoparticles. The equation for the diffusion flux of nanoparticles was obtained and it was shown that flux slowing leads to formation of dendritic multilevel structures.

The results can be used to develop technologies for ionite synthesis, ion-exchange membranes and materials for baromembrane separation. The proposed approach allows to obtain materials with a given particle size and, consequently, with certain functional properties.

Author Biographies

Константин Сергеевич Супруненко, National Technical University of Ukraine «Kyiv Polytechnic Institute», 37 Peremogy ave. Kyiv, Ukraine, 03056

Department of Cybernetics of Chemical Technology Processes

Александр Александрович Kвитка, National Technical University of Ukraine «Kyiv Polytechnic Institute», 37 Peremogy ave. Kyiv, Ukraine, 03056

Candidate of Chemical Sciences, Associate Professor

Department of Cybernetics of Chemical Technology Processes

Екатерина Олеговна Куделко, V. I. Vernadsky Institute of General and Inorganic Chemistry of the Ukrainian National Academy of Sciences, Pr. Vernadsky 32/34, 03680, Kyiv

Candidate of Chemical Sciences

Department of sorption & membrane technologies and materials

Юлия Сергеевна Дзязько, V. I. Vernadsky Institute of General and Inorganic Chemistry of the Ukrainian National Academy of Sciences, Pr. Vernadsky 32/34, 03680, Kyiv

Doctor of Chemical Sciences

Department of sorption & membrane technologies and materials

Александра Станиславовна Руденко, V. I. Vernadsky Institute of General and Inorganic Chemistry of the Ukrainian National Academy of Sciences, Pr. Vernadsky 32/34, 03680, Kyiv

Department of sorption & membrane technologies and materials

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Published

2016-05-26

How to Cite

Супруненко, К. С., Kвитка А. А., Куделко, Е. О., Дзязько, Ю. С., & Руденко, А. С. (2016). Determination of precipitation regularities for nanoparticles of hydrated metal oxides in the anion exchange resin. Technology Audit and Production Reserves, 3(3(29), 42–47. https://doi.org/10.15587/2312-8372.2016.70634

Issue

Vol. 3 No. 3(29) (2016): Technologies of food, light and chemical industry

Section

Technologies of food, light and chemical industry

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Copyright (c) 2016 Константин Сергеевич Супруненко, Александр Александрович Kвитка, Екатерина Олеговна Куделко, Юлия Сергеевна Дзязько, Александра Станиславовна Руденко

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