Analysis of environmental, legislative and technological aspects of the choice of non-aqueous working bodies for power plants
DOI:
https://doi.org/10.15587/2312-8372.2017.119336Keywords:
power plant, working bodies of energy cycles, stability of substances, sulfur hexafluorideAbstract
In the conducted researches there is a task of a choice of a working body for a heat power circuit of power plants on non-aqueous working substances with possibility of considerable increase of power efficiency of a cycle and safety of operation of plants in view of restrictions of the Montreal and Kyoto protocols. In an experimental study of the possibility of using fluorocarbon working bodies and SF6 as working bodies of energy cycles, positive results have been obtained both in terms of increasing the safety of operation of power plants and increasing their reliability, and in terms of energy efficiency. However, their use as working bodies was delayed by the extremely long lifetime in the atmosphere by the Lifetime criterion.
When calculating material balances of fluorocarbons and SF6 gas in the atmosphere based on the new IPCC-2013 data, a discrepancy of four orders of magnitude of the Lifetime criterion is found with the initial data given by IPCC-94. Based on these data, restrictions are introduced on the use of these substances within the framework of the commitment of the countries participating in the Kyoto Protocol to the UNFCCC. This gives grounds for the use of fluorocarbons and SF6 gas without restrictions on the basis of the greenhouse hazard, since the lifetime of these substances in the atmosphere does not exceed 2 years.
The use of fluorocarbons and SF6 gas as working bodies of energy cycles will significantly reduce energy consumption in the refrigeration industry and will significantly increase the efficiency in generating electricity at TPPs and NPPs, while reducing energy consumption by 20–25 %.
References
- Gohshtein, D. P., Smirnov, G. F., Kirov, V. S. (1964). Nekotorye osobennosti parogazovyh shem s nevodianymi parami. Energetika, 11, 20–24.
- Moisan et Lebeau, C. R. (1900). Sur un nouveaucorps gazeux: leperfluorure de soufre SF6. Paris: Academie des sciences, 130.
- Morkin, M. S., Lemehov, V. V., Cherepnin, Yu. S. (2014). Fizicheskaia model' radioliza gazoobraznogo ftoruglerodnogo rabochego tela. Doklady tret'ei mezhdunarodnoi nauchno-tehnicheskoi konferentsii «Innovatsionnye proekty i tehnologii iadernoi energetiki». Vol. 1. OAO «NIKIET», 462–466.
- Maksimov, B. N., Barabanov, V. G., Serushkin, I. L. et al. (1996). Promyshlennye ftororganicheskie produkty. Ed. 2. St. Petersburg: Himiia, 544.
- Brown, T. E., LeMay, H. E., Bursten, B. E., Murphy, C., Woodward, P. (2011). Chemistry: The Central Science. Ed. 11. Prentice Hall, 1232.
- Intergovernmental Panel on Climate Change. (2014). Summary for Policymakers. Climate Change 2013 – The Physical Science Basis. Cambridge University Press, 1–30. doi:10.1017/cbo9781107415324.004
- Tapscott, R. E., Mather, J. D. (2000). Tropodegradable fluorocarbon replacements for ozone-depleting and global-warming chemicals. Journal of Fluorine Chemistry, 101 (2), 209–213. doi:10.1016/s0022-1139(99)00161-x
- Haywood, R. W. (1980). Analysis of Engineering Cycles. Elsevier, 348. doi:10.1016/c2013-0-03329-4
- Perelshtein, I. I., Parushin, E. B. (1984). Termodinamicheskie i teplofizicheskie svoistva rabochih veshchestv holodil'nyh mashin i teplovyh nasosov. Moscow: Liogkaia i pishchevaia promyshlennost', 232.
- Syvorotkin, V. L. (2002). Glubinnaia degazatsiia Zemli i global'nye katastrofy. Moscow: Geoinformtsentr, 250.
- Molina, M. J., Rowland, F. S. (1974). Stratospheric sink for chlorofluoromethanes: chlorine atom-catalysed destruction of ozone. Nature, 249 (5460), 810–812. doi:10.1038/249810a0
- Houghton, J. T., Meira Filho, L. G., Bruce, J., Hoesung Lee, Callander, B. A., Haites, E., Harris, N., Maskell, K. (1995). Climate Change 1994. Radiative Forcing of Climate Change and An Evaluation of the IPCCIS92 Emission Scenarios. Cambridge University Press, 340. Available at: https://www.ipcc.ch/pdf/special-reports/cc1994/climate_change_1994.pdf
- SF6 recycling guide. Re-use of SF6 gas in electrical power equipment and final disposal. (1997). ELECTRA, ELT_173_3, 29. Available at: https://e-cigre.org/publication/ELT_173_3-sf6-recycling-guide-re-use-of-sf6-gas-in-electrical-power-equipment-and-final-disposal
- Stekolnikov, I. S. (1960). Priroda dlinnoi iskry. Moscow: AN SSSR, 272.
- Stekolnikov, I. S., Bagirov, M. A. (1953). Issledovanie prirody dlinnoi iskry. Izvestiia AN SSSR. OTN, 2, 12–16.
- Toepler, M. (1906). Zur Kenntnis der Gesetze der Gleitfunkenbildung. Annalen Der Physik, 326 (12), 193–222. doi:10.1002/andp.19063261202
- Schonland, B. F. J. (1953). The Pilot Streamer in Lightning and the Long Spark. Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, 220 (1140), 25–38. doi:10.1098/rspa.1953.0169
- Isidorov, V. A. (1985). Organicheskaia himiia atmosfery. Leningrad: Himiia, 264.
- Doronin, A., Mazurin, I., Stoljarevski, A. (1995). The new cooling agents. Proceedings of the 19th International congress of refrigeration, Hague, Netherlands, August 20–25, 1995. Paris: Institut international du froid, 914.
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