Chemical composition of underground waters of Kharkiv region as a health risk factor of the population

Authors

  • В. М. Прибилова V.N. Karazin Kharkiv National University, Ukraine https://orcid.org/0000-0001-8603-2350
  • А. М. Качан V.N. Karazin Kharkiv National University, Ukraine

DOI:

https://doi.org/10.26565/2410-7360-2017-46-04

Keywords:

Chemical composition, groundwater, Kharkiv region, public health, risk assessment, hazard ratio

Abstract

The article discusses the results of public health risk assessment caused by the groundwater use without preliminary water treatment for residents of Kharkiv region. Within Kharkiv region the main aquifer used for centralized water supply is Palaeogene (usually Buchatskiy-Kanev, less Mezhygirska-Obukhiv), aquifer-loamy chalk strata of the Upper Cretaceous and Cenomanian-Inferior Cretaceous aquifer.Water quality has a direct impact on the incidence of local residents. Most of the rural population routinely uses water from their own wells or boreholes. In most of them water is low quality. Increased concentrations of Tl, Hg, Cd, Pb, As, Al, Ba, Sr, Fe, Mn have been found in untreated natural water sources in different parts of the region. As a rule, levels of most of the trace elements listed above are not reduced before drinking water reaches a consumer. The analysis of macro- and microcomponent composition of drinking underground waters of Kharkiv region has been carried out. Based on the chemical composition of groundwater in the main aquifers used for water supply purposes averaged over a large number of samples over a long period of observation, the main substances for assessing the health risk of the population were identified. Subject to applicable laws of chemical elements distribution in groundwater were received average concentrations of substances in each aquifer complex. All analyzes were carried out using modern water standard techniques quite widely used today to assess the quality of drinking water. The average daily doses of elements in the human body with consumed groundwater and the indices of non-carcinogenic effects for human health are calculated. Priority substances contained in groundwater and having a health hazard index of more than 0.05 are related to thallium, mercury, cadmium, lead, arsenic, barium, strontium, iron, and manganese. By the value of the total hazard ratio, a comparative analysis of the water quality of various aquifers has been carried out and a conclusion has been reached on the acceptability of the level of risk to human health.

Author Biographies

В. М. Прибилова, V.N. Karazin Kharkiv National University

PhD (Geology), Associate Professor

А. М. Качан, V.N. Karazin Kharkiv National University

MSc (Geology)

References

Kopylevych, V. A., Voytenko, L. V., Balakyreva, A. D. et al. (2009). Aktual'nie problemi kachestva pyt'evoy vodi v Ukrayne. Voda i vodoochysni tekhnolohiyi, 10. 7–12.

Vasylevskaya, L. S., Orlova, S. V. (2004). Mykroelementi v medytsyne, 5, 4, 25-26.

Vstup do medychnoyi heolohiyi, T. 1. (2010). Za redaktsiyeyu H. I. Rud'ka, O. M. Adamenka. K., «Akadempres», 736.

Prokopov, V. O., Zorina, O. V., Hulenko, S. V. et al. (2012). Hihiyenichnyy analiz stanu vykorystannya system doochyshchennya pytnoyi vody v Ukrayini. Hihiyenichna nauka ta praktyka: suchasni realiyi: Materialy KhV z"yizdu hihiyenistiv Ukrayiny. 20-21 veresnya 2012 roku (L'viv). L'viv, Drukarnya LNMU imeni Danyla Halyts'koho, 299-302.

Honcharuk, V. (2009). Khimiya vody i problemy pytnoho vodopostachannya. Svitohlyad, 4, 18–27.

Hryshchenko, S. V., Nahornyy, I. M., Svestun, R. S. (2009). Terytorial'ni zakonomirnosti tekhno-hennoho zabrudnennya navkolyshn'oho seredovyshcha v Ukrayini. Vestnyk hyhyeni y epydemyolohyy, 13, 2, 243–248.

Kobylyans'kyy, V. Ya. (2009). Kontrol' yakosti pytnoyi vody v XXI stolitti: (prosto i tochno). Vodopostachannya ta vodovidvedennya, 2, 19–21.

Kopylevych, V. A., Voytenko, L. V. (2010). K voprosu normyrovanyya kachestva vodi dlya raznikh vydov vodopotreblenyya. Voda i vodoochysni tekhnolohiyi, 5–6, 17–20.

Novykov, S. M. (1998). Problemi otsenky kantserohennoho ryska vozdeystvyya khymycheskykh zahryaznyteley okruzhayushchey sredi. Gigiena i sanitariya, 1.

Onyshchenko, H. H., Novykov, S. M., Rakhmanyn, Yu. A. (2002). Osnovi otsenky ryska dlya zdorov'ya naselenyya pry vozdeystvyy khymycheskykh veshchestv, zahryaznyayushchykh okruzhayushchuyu sredu. M., NYY EChyHOS, 408.

Onyshchenko, H. H., Rakhmanyn, Yu. A., Karmazynov, F. V. (2010). Benchmarkynh kachestva pyt'evoy vodi. SPb., Noviy zhurnal, 432.

Prybylova, V. M. (2016). Porivnyal'na kharakterystyka normatyviv yakosti pytnoyi vody, shcho zastosovuyut'sya v okremykh krayinakh svitu. Visnyk KhNU imeni V.N. Karazina, seriya «Geolohiya-Geohrafiya-Ekolohiya», 44, 55-62.

Prybylova, V. M. (2016). Osoblyvosti formuvannya yakosti pytnoyi vody ta faktory, shcho na neyi vplyvayut'. «Hidroheolohiya: nauka, osvita, praktyka», 3, KhNU imeni V.N. Karazina, Kharkiv, 2-4 lystopada 2016 r. Kharkiv, 125-128.

Prybylova, V. M. (2016). Stratehiya vykorystannya pidzemnykh vodnykh resursiv Kharkivs'koyi oblasti. Rehion – 2016: Stratehiya optymal'noho rozvytku: mizhnarodna naukovo-praktychna konferentsiya. Kharkiv, 2-4 lystopada 2016 r. Kharkiv, 297-300.

Stratehiya vykorystannya resursiv pytnykh pidzemnykh vod dlya vodopostachannya: u 2t. (2011). Za red. E. A. Stavyts'koho, H. I. Rud'ka, Ye. O. Yakovlyeva. Chernivtsi, Bukrek, 1, 348.

Stratehiya vykorystannya resursiv pytnykh pidzemnykh vod dlya vodopostachannya: u 2t. (2011). Za red. E. A. Stavyts'koho, H. I. Rud'ka, Ye.O. Yakovlyeva. Chernivtsi, Bukrek, 2, 500.

Shestopalov, V. M., Ovchynnykova, N. B. (2003). Podzemnie vodi y zdorov'e. Ekolohiya dovkillya ta bezpeka zhyttyediyal'nosti, 1, 19-32.

Yakist' pytnoyi vody ta yiyi vplyv na zdorov"ya naselennya (2015). Dopovid' pro stan navkolyshn'oho pryrodnoho seredovyshcha v Kharkivs'kiy oblasti v 2015 rotsi. Min-vo okhor. navkol. pryr. sered. Ukrayiny, Derzh. upr. okhor. navkol. pryr. sered. v Khark. obl. Kh., 68-67.

Guidelines for Drinking-Water Quality (2008). Third Edition Incorporating the 1-st and 2-nd Addenda, 1. Recommendations. WHO, Geneva, Switzerland.

Published

2017-10-23

Issue

Section

Geology