Investigation of thermal decomposition process of finely divided carbonate raw materials and some properties of the roasting product
DOI:
https://doi.org/10.15587/2312-8372.2015.51776Keywords:
roasting, carbonate raw materials, particle size distribution, thermal dissociationAbstract
The problems of the roasting of finely divided carbonate raw material are considered in the article. The aim of the research is to determine the physical and chemical laws, by which we can manage the process and roasting product quality. Some results of a comprehensive study of the physical and chemical properties of several kinds of finely divided carbonate raw materials and the laws of its thermal dissociation are given, physical and chemical properties of the dissociation products are defined. They are allowed to establish in each case the kinetic and technological parameters of thermal dissociation process of raw materials, at which the maximum conversion rate of CaCO3 into CaO is observed, whereby the product has the highest activity. The practical application of the principle of the results will reduce investment in the creation of the unit, improve the furnace performance for the final product. This process organization on the basis of the research results provides the optimal regimes of carbonate waste preparation and their firing to obtain highly active lime and production effectiveness.
References
- Tkach, G. A., Shaporev, V. P., Titov, V. M. (1998). Proizvodstvo sody po maloothodnoi tehnologii. Kharkov: KhGPU, 430.
- Tovazhnianskyi, L. L., Loboiko, O. Ya., Hryn, H. I. et al. (2007). Tekhnolohiia zviazanoho azotu. Kharkiv: NTU «KhPI», 535.
- Bobylev, V. P. (1999). Razrabotka tehnologii proizvodstva shlamosoderzhashchih bezobzhigovyh okatyshei i ih ispol'zovanie v staleplavil'nom proizvodstve. Metallurgiia i gornorudnaia promyshlennost', 1, 96–100.
- Sapronov, A. R. et al. (1990). Obshchaia tehnologiia sahara i saharnyh veshchestv. Moscow: Agropromizdat, 356.
- Pereskokov, A. I. (2007). Retsikling aktivnoi izvesti, ispol'zuemoi v tselliulozno-bumazhnoi promyshlennosti. Materialy mezhdunarodnoi konferentsii «Sotrudnichestvo dlia resheniia problemy othodov». Sektsiia «Promyshlennye othody tehnologii i oborudovaniia dlia pererabotki». Kharkov, 143–146.
- Tret'iakov, Yu. D. (2006). Mikro- i nanomir sovremennyh materialov. Moscow: MGU, 69.
- Saifulin, R. S. (1983). Neorganicheskie kompozitsionnye materialy. Moscow: Himiia, 36.
- Pech' kiniashchego sloia dlia obzhiga materialov. (1974). Copyright certificate the USSR № 425033 kl F 276 15/021 S 22v 43/00. Filed 12.10.1972, Publ. 25.04.1974. Otkr. Izobretenie, prom. obraz. tovar. znaki, № 15, 122.
- Reaktor s vibriruiushchim psevdoozhizhennym sloem. (1985). Application EPV № 0126191 MKI V 01 I8/40 //F23C 11/02, F 23 C 5/00, C 21B 13/00. Filed 16.05.1983. Publ. 28.11.1984; № 48. Izobretenie stran mira, Vol. 16, № 15, 29.
- Ustroistvo dlia teplovoi obrabotki melkozernistyh materialov. (1985). Application FRG (DE) № 053325670 MKI V 01I 6/00, F27 B 7/00, F27 D 13/00. Publ. 24.01.1985; № 4. Izobretenie stran mira, Vol. 16, № 15, 38.
- Meshkova, L. V. (1985). Izuchenie svoistv shlama vtoroi stadii rassoloochistki kak syr'ia dlia proizvodstva gidroksida kal'tsiia na Krymskom sodovom zavode. Trudy NIOHIM "Intensifikatsiia tehnologicheskih protsessov i apparatov sodovogo i smezhnyh proizvodstv", Vol. LX, 87–97.
- Kanso, V. A., Raiko, V. F., Shaporev, V. P. (2006). Matematicheskoe modelirovanie protsessa obzhiga vo vrashchaiushchihsia pechah. Vestnik NTU «KhPI», 10, 118–133.
- Kanso, V. A. (2008). Modelirovanie i intensifikatsiia protsessov termicheskogo razlozheniia dispersnogo karbonata kal'tsiia vo vrashchaiushchihsia pechah. Kharkov, 133.
- Gorelik, S. S., Rastorguev, A. N. (1970). Rentgenograficheskii i elektronograficheskii analiz. Moscow: Fizmatgiz, 140.
- Grin'e, A. (1961). Rentgenografiia kristallov. Teoriia i praktika. Translated from French. Moscow: Fizmatgiz, 604.
- Kouzov, P. A. (1971). Osnovy analiza dispersnogo sostava promyshlennyh pechei i izmel'chennyh materialov. Leningrad: Himiia, 280.
- Klassen, P. V., Grishaev, I. G. (1982). Osnovy tehniki granulirovaniia. Moscow: Himiia, 272.
- Beliaev, E. K., Annapol'skii, V. F. (1976). Vychislenie kineticheskih parametrov po dannym derivatograficheskih izmerenii. Zhurnal fizicheskoi himii, Vol. 50, № 3, 790–793.
- Shaporev, V. P. (1995). Tehnologіia neorganіchnih armuiuchi napovniuvachіv. Kharkov, 365.
- Drago, R.; Translated from English: Reutov, O. A. (1981). Physical Methods for Chemists. Part 2. Moscow: Mir, 456.
- Shaporev, V. P., Dolkart, A. V., Ostroushko, V. I., Vedeneeva, Z. I. (1985). Rentgenograficheskoe izuchenie struktury i gidratatsionnoi aktivnosti oksida kal'tsiia v zavisimosti ot prirody karbonatnogo syr'ia i temperatury obzhiga. Dep. v NIITEHIM 25.05.85 № 696 hp. 182. Kharkov, 10.
- Shaporev, V. P., Hitrova, I. V., Darmanian, A. V. (1993). Issledovanie reaktsionnoi sposobnosti oksida kal'tsiia, poduchennogo termicheskim razlozheniem izvestniaka. Vestnik KhGPU. Himicheskaia tehnologiia, 2, 22–25.
- Pleva, M. (1981). Einflub des Schnelbrandes aud die Eigenschalten des Branntkalkes. Baustof-findustrie, Vol. 24, № 1, 10–12.
- Gal'perin, A. (1960). Bystryi raschet energii aktivatsii pri pomoshchi termograficheskih metodov. Phys. Rev., Vol. 117, 416.
- Fotiev, A., Molchanov, V. (1968). Otsenka velichiny kazhushcheisia energii aktivatsii s pomoshch'iu differentsial'noi termografii. Zhurnal neorganicheskoi himii, 13, 1374–1379.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2016 Инна Вячеславовна Питак, Валерий Павлович Шапорев, Михаил Ильич Васильев
This work is licensed under a Creative Commons Attribution 4.0 International License.
The consolidation and conditions for the transfer of copyright (identification of authorship) is carried out in the License Agreement. In particular, the authors reserve the right to the authorship of their manuscript and transfer the first publication of this work to the journal under the terms of the Creative Commons CC BY license. At the same time, they have the right to conclude on their own additional agreements concerning the non-exclusive distribution of the work in the form in which it was published by this journal, but provided that the link to the first publication of the article in this journal is preserved.